Spinodal Decomposition in Fe-Cr Alloys

Article Preview

Abstract:

The hardening behavior of precipitation was studied during aging of Fe-Cr alloys. This mechanical behavior is associated with the nanometric modulation structure of the coherent decomposed Fe-rich and Cr-rich phases formed by the spinodal decomposition of the supersaturated solid solution. The growth kinetics of spinodal decomposition was very slow and it increased during coarsening stage. The morphology of decomposed phases consisted of an interconnected irregular shape with no preferential alignment for short aging times and a further aging caused the change to a plate shape of the decomposed Cr-rich phase aligned in the <110> directions of the Fe-rich matrix. The rapid increase in hardness and embrittlement seem to be associated with the coherency and nanometer size of the spinodally-decomposed phases in the aged alloys.

You might also be interested in these eBooks

Info:

Periodical:

Solid State Phenomena (Volumes 172-174)

Pages:

443-448

Citation:

Online since:

June 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] P. Marshal: Austenitic Stainless Steels Microstructure and Properties (Elsevier Applied Science Publisher, London 1984).

Google Scholar

[2] M.K. Miller, R.E. Stoller and K.F. Russell: J Nuc. Mater. Vol. 230 (1996) p.219.

Google Scholar

[3] J.C. LaSalle and L.H. Schwartz: Acta Metall. Vol. 34 (1986) p.989.

Google Scholar

[4] J.W. Cahn and J.E. Hilliard: Acta Metall. Vol. 19 (1971) p.151.

Google Scholar

[5] M. Honjo and Y. Saito: ISIJ International. Vol. 40 (2000) p.914.

Google Scholar

[6] H. Bakker, H.P. Bonzel, C.M. Bruff, M.A. Dayananda, W. Gust, J. Horvath, I. Kaur, G.V. Kidson, A.D. LeClaire, H. Mehrer, G.E. Murch, G. Neumann, N. Stolica and N.A. Stolwijk: Diffusion in Solid Metals and Alloys (Springer-Verlag. Berlin 1990).

Google Scholar

[7] G.E. Dieter: Mechanical Metallurgy (McGraw-Hill, London 1988).

Google Scholar

[8] T. Kuwajima, Y. Saito and Y. Suwa: Intermetallics Vol. 11 (2003) p.1279.

Google Scholar

[9] J. W. Cahn: Acta Metall. Vol. 10 (1962) p.179.

Google Scholar

[10] Y. Ustinovshikov, B. Pushkarev and I. Igumnov: J. Mater. Sci. Vol. 37 (2002) p. (2031).

Google Scholar