Thermodynamic Properties of RZnSn2 (R = Y, Er, Lu) Compounds with HfCuSi2 Structure Type

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Abstract:

The results of magnetic and specific heat studies are reviewed and discussed for the series of RZnSn2 (R = Y, Er and Lu) compounds crystallizing in the same tetragonal HfCuSi2 - type of structure. A sharp peak in the specific heat of ErZnSn2 compound is indicative for magnetic ordering of Er moments at 5.0 K, being in agreement with its established antiferromagnetic nature. The estimated magnetic entropy Smagn contribution is less than that expected for the ground state J = 15/2 multiplet of Er3+.

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Solid State Phenomena (Volume 194)

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67-70

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November 2012

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] Yu. Verbovytskyy, K. Łątka, J. Przewoźnik, N. Leal, A.P. Gonçalves, On the new ternary RZnSn2 compounds with HfCuSi2 structure type, Intermetallics 20 (2012) 176-182.

DOI: 10.1016/j.intermet.2011.08.024

Google Scholar

[2] J. Rodriguez-Carvajal, T. Roisnel, FullProf.98 and WinPLOTR: New Windows 95/NT Applications for Diffraction Commission For Powder Diffraction, International Union for Crystallography, Newsletter №20 (May-August) Summer, 1998.

Google Scholar

[3] G. Czjzek, V. Oestreich, H. Schmidt, K. Łątka, K. Tomala, A study of compounds GdT2Si2 by Mössbauer spectroscopy and by bulk magnetization measurements, J. Magn. Magn. Mat. 79 (1989) 42-56.

DOI: 10.1016/0304-8853(89)90290-4

Google Scholar

[4] K. Łątka, R. Kmieć, A.W. Pacyna, R Mishra, R. Pöttgen, Magnetism and hyperfine interactions in Gd2Ni2Mg, Solid State Sci. 3 (2001) 545-558.

DOI: 10.1016/s1293-2558(01)01172-4

Google Scholar

[5] R.-D. Hoffmann, T. Fickenscher, R. Pöttgen, C. Felser, K. Łątka, R. Kmieć, Ferromagnetic ordering in GdPdCd, Solid State Sci. 4 (2002) 609-617.

DOI: 10.1016/s1293-2558(02)01304-3

Google Scholar

[6] K. Łątka, Z. Tomkowicz, R. Kmieć, A.W. Pacyna, R. Mishra, T. Fickenscher, R.-D. Hoffmann, R. Pöttgen, H. Piotrowski, Structure and properties of GdTMg (T = Pd, Ag, Pt), J. Solid State Chem. 168 (2002) 331-342.

DOI: 10.1006/jssc.2002.9718

Google Scholar

[7] K. Łątka, R. Kmieć, A.W. Pacyna, T. Fickenscher, R.-D. Hoffmann, R. Pöttgen, Magnetism and 155Gd Mössbauer spectroscopy of GdAuMg, Solid State Sci. 6 (2004) 301-309.

DOI: 10.1016/j.solidstatesciences.2004.01.006

Google Scholar

[8] K. Łątka, R. Kmieć, A.W. Pacyna, T. Fickenscher, R.-D. Hoffmann, R. Pöttgen, Magnetic ordering in GdAuCd, J. Magn. Magn. Mat. 280/1 (2004) 90-100.

DOI: 10.1016/j.jmmm.2004.02.025

Google Scholar

[9] K. Łątka, R. Kmieć, M. Rams, A.W. Pacyna, V.I. Zaremba, R. Pöttgen, Antiferromagnetic ordering in GdRhIn5, Z. Naturforsch. 59b, (2004) 947-957.

DOI: 10.1515/znb-2004-0901

Google Scholar

[10] K. Łątka, M. Rams, R. Kmieć, A.W. Pacyna, V.I. Zaremba, U.Ch. Rodewald, R. Pöttgen, Structure and properties of Gd4Pd10In21, Solid State Sci. 9 (2007) 173-184.

DOI: 10.1016/j.solidstatesciences.2006.10.005

Google Scholar

[11] K. Łątka, A. W. Pacyna, R. Pöttgen, F. M. Schappacher, Puzzling magnetism of Gd3Cu4Sn4, Acta Physica Polonica A, 114 (2008) 1501-1508.

DOI: 10.12693/aphyspola.114.1501

Google Scholar

[12] Yu. Verbovytskyy, K. Łątka, J. Przewoźnik, A.P. Gonçalves, Crystal structure and magnetic properties of GdZn2Ga2, Intermetallics 22 (2012) 106-109.

DOI: 10.1016/j.intermet.2011.10.012

Google Scholar

[13] C. Kittel, Introduction to Solid State Physics, seventh ed., Chapter 5, John Wiley&Sons, Inc., New York, Chichester, Brisbane, Toronto, Singapore, 1996, pp.115-142.

Google Scholar