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HomeSolid State PhenomenaSolid State Phenomena Vol. 231Influence of Sr-Doping on the Structure of LaCoO3...

Influence of Sr-Doping on the Structure of LaCoO₃ Thin Films Prepared by Pulsed Laser Deposition

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Abstract:

The aim of the research was to investigate the influence of strontium on the structure thin films La1-x SrxCoO3 (x=0; 0.1, 0.2). The LaCoO3 and LaCoO3 doped by Sr films were grown by pulsed laser deposition (PLD) on Si [100] substrate using an Excimer KrF (= 248 nm). To characterize the structure and morphology of the thin films were used the SEM, AFM and XRD methods. X-Ray Diffraction analysis showed only LaCoO3 phase in the thin film not doped andLa0.1Sr0.9CoO3 and La0.2Sr0.8CoO3 phases in thin films doped by Sr. The crystallites size, calculated by Williamson-Hall plots, was smaller for films doped by Sr. The surface of the thin films was free from the drops. SEM analysis showed change of the shape of thin films as a result of doping by Sr. Highly developed layer surface was observed using the AFM microscope for thin films doped by Sr.

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XV International Conference on Electron Microscopy

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Periodical:

Solid State Phenomena (Volume 231)

Pages:

19-24

DOI:

https://doi.org/10.4028/www.scientific.net/SSP.231.19

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Online since:

June 2015

Authors:

Agnieszka Kopia*, Łukasz Cieniek, Kazimierz Kowalski, Jan Kusiński

Keywords:

Perovskite LaCoO3, Pulsed Laser Deposition, Thin Films

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] A. Kopia, Semi-conducting thin films with catalytic properties, AGH University of Science and Technology Press, Kraków, 2011 (in Polish).

[2] J. Wu, C. Leighton, Glassy ferromagnetism and magnetic phase separation in La1-xSrxCoO3, Phys. Rev. B 67 (2003) 174408-174408-16.

[3] X. Yang, D.W. Park, M. Il Kim, Selective oxidation of hydrogen sulfide over LaCoO3 and LaSrCoO4 mixed oxides, Korea J. Chem. Eng. 24 (4) (2007) 592-595.

DOI: 10.1007/s11814-007-0008-8

[4] P.R.N. Silva1, A.B. Soares, Lanthanum based high surface area perovskite-type oxide and application in CO and propane combustion, Eclet. Quím. 34 (2009) 31-38.

DOI: 10.1590/s0100-46702009000100005

[5] Y. Xiao Mao, Structures and catalytic activities of LaSrCoO4 and LaSrCoO3. 6F0. 4 mixed oxides, Appl. Mech. Mater. 55-57 (2011) 1957-(1961).

[6] Y.J. Yoo, K.K. Yu, Y.P. Lee, J.Y. Kim, Ch.J. Yu, K.W. Kim, Magnetic phase study of Sr-doped LaCoO alloys by using neutron diffraction, J. Korean Phys. Soc. 49 (2006) 2397-2401.

[7] K.H. Wong, W. Wu, P.W. Chan. J.T. Cheung, Low temperature growth of epitaxial La0. 5Sr0. 5CoO3 films on (100) SrTiO3 by pulsed laser deposition, Thin Solid Films 312 (1998) 7-10.

DOI: 10.1016/s0040-6090(97)00224-1

[8] K.S. Hwang, H.M. Lee, S. S Min, B. O Kang, Epitaxially grown LaSrCoO3 thin films on various substrates by the sol-gel method, J. Sol-Gel Sci. Tech. 18 (2000) 175-180.

[9] A.V. Kadu, S.V. Jagtap, H2S gas sensing behavior of modified LaCoO3thick film, Sci. Revs. Chem. Commun. 2(3) (2012) 172-178.

[10] Ł. Cieniek, J. Kusiński, Structure and low temperature electrical properties of LaCoO3 perovskite thin film produced by PLD technique, Inżynieria Materiałowa 4 (2013) 253-256 (in Polish).

[11] J. Szelc, A. Kopia, Ł. Cieniek, Thin films based on perovskite LaCoO3 deposited by pulsed laser deposition, Inżynieria Materiałowa 6 (2013) 903-906 (in Polish).

[12] S. Sun, L. Yang, G. Pang, S. Feng, Surface properties of Mg doped LaCoO3 particles with large surface areas and their enhanced catalytic activity for CO oxidation, Appl. Catal. A 401 (2011) 199-203.

DOI: 10.1016/j.apcata.2011.05.015

[13] M. Lv, X. Xiu, Z. Pang, Y. Dai, L. Ye, Ch. Cheng, Sh. Han, Structural, electrical and optical properties of zirconium-doped zinc oxide films prepared by radio frequency magnetron sputtering Thin Solid Films 516 (2008) 2017-(2021).

DOI: 10.1016/j.tsf.2007.06.173

[14] M. Kumar, S. Srikanth, B. Ravikumar, T.C. Alex, S.K. Das, Synthesis of pure and Sr-doped LaGaO3, LaFeO3 and LaCoO3 and Sr, Mg-doped LaGaO3 for ITSOFC application using different wet chemical routes, Mater. Chem. Phys. 113 (2009) 803-815.

DOI: 10.1016/j.matchemphys.2008.08.047

[15] M. Chmielowska, S. Villain, A. Kopia, J.P. Dallas, J. Kusinski, J.R. Gavarri, Ch. Leroux, Ce1−xNdxO2−δ/Si thin films obtained by pulsed laser deposition: Microstructure and conduction properties, Thin Solid Films 516 (2008) 3747-3754.

DOI: 10.1016/j.tsf.2007.06.224