Effect of the Pulse Laser Radiation on the Stabilization of the ZrO2 and HFO2 High-Temperature Phases

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Abstract:

The conditions of formation of the ZrO2 and HfO2 high-temperature (tetragonal and cubic) phases in the ablated nanoparticles were investigated. X-ray diffraction and transmission electron microscopy data demonstrate that laser intensities above 109 W/m2 ensure the formation of the ZrO2 high-temperature phases, while intensities above 5·109 W/m2 do the formation of the HfO2 high-temperature phases. Quantitative content of the high-temperature phases in layers of the ablated nanoparticles increases with raising the intensity. The obtained nanoparticles exhibit good thermal stability.

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Solid State Phenomena (Volume 245)

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200-203

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October 2015

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© 2016 Trans Tech Publications Ltd. All Rights Reserved

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[1] J. Wang, H.P. Li, R. Stevens, Hafnia and hafnia-toughened ceramics. Review, J. Mater. Sci. 27 (1992) 5397-5430.

DOI: 10.1007/bf00541601

Google Scholar

[2] B. Matovica, D. Bucevaca, M. Prekajskia, V. Maksimovic, D. Gautam, K. Yoshida, T. Yano, Synthesis and characterization of nanometric yttrium-doped hafnia solid solutions, J. Eur. Ceram. Soc. 32 (2012) 1971-(1976).

DOI: 10.1016/j.jeurceramsoc.2011.10.029

Google Scholar

[3] M.A. Pugachevskii, V.I. Panfilov, Optical properties of HfO2 nanoparticles produced by laser ablated, Journal of appl. spectr. 81 (2014) 640-643.

DOI: 10.1007/s10812-014-9982-x

Google Scholar

[4] M.A. Pugachevskii, Morphology and phase changes in laser ablated TiO2 particles during thermal annealing, Technical Physics Letters 38 (2012) 328-331.

DOI: 10.1134/s1063785012040128

Google Scholar

[5] M.A. Pugachevskii, Effect of annealing on photoluminescent properties of titanium dioxide nanoparticles, Journal of appl. spectr. 79 (2012) 834-837.

Google Scholar