Paper Titles

In Situ Mueller-Matrix Magneto-Ellipsometry
p.55

Modeling of Structures Nanocrystalline and Amorphous Alloys
p.60

Nanocomposites Based on CdS Quantum Dots for Laser Control Devices
p.67

Formation of Bulk and Nanocrystallite Layers of GaSb on Silicon
p.72

Synthesis of Mesoporous CaMoO₄ in Aqueous Solution
p.80

Inhibitor-Containing Composite Coatings on Mg Alloys: Corrosion Mechanism and Self-Healing Protection
p.89

Electrophoretic Composite Coatings on Magnesium Alloys
p.97

Formation of Composite Coatings Using Fluoropolymer Materials
p.103

Nanostructured Composite FeOF-FeF₃ as Anode Material for Li-Ion Battery: The Original Method of Pulsed High-Voltage Discharge
p.109

HomeSolid State PhenomenaSolid State Phenomena Vol. 245Synthesis of Mesoporous CaMoO4 in Aqueous Solution

Synthesis of Mesoporous CaMoO₄ in Aqueous Solution

Article Preview

Abstract:

The mesoporous CaMoO₄ microcrystals have been prepared by precipitation in an aqueous solution. The scheelite-type structure in space group I4₁/a has been verified by the XRD analysis of the final powder product. The CaMoO₄ powder is composed of the almost size-uniform erythrocyte-like microspheroids with a diameter of ~5 μm. Every particle is formed by plate-like crystals with the characteristic thickness at a few-nanometer level and a diameter of ~1-2 μm.

You might also be interested in these eBooks

Physics and Technology of Nanostructured Materials III

Info:

Periodical:

Solid State Phenomena (Volume 245)

Pages:

80-85

DOI:

https://doi.org/10.4028/www.scientific.net/SSP.245.80

Citation:

Cite this paper

Online since:

October 2015

Authors:

V.V. Atuchin*, O.P. Andreeva, T.A. Gavrilova, N.A. Kalyzhnyi, I.V. Korolkov, E.A. Maximovskiy

Keywords:

Calcium Molybdate, Nanocrystal, Precipitation, SEM, XRD

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2016 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] V.V. Atuchin, B.I. Kidyarov, Classification and search for novel binary acentric molybdate and wolframate crystals, J. Korean Cryst. Growth Cryst. Technol. 12 (6) (2002) 323-328.

[2] V.V. Atuchin, B.I. Kidyarov, N.V. Pervukhina. Phenomenological modeling and design of new acentric crystals for optoelectronics, Comput. Mater. Sci. 30 (2004) 411-418.

DOI: 10.1016/j.commatsci.2004.03.013

[3] O. Yu. Khyzhun, T. Strunskus, Yu.M. Solonin, XES, XPS and NEXAFS studies of the electronic structure of cubic MoO1. 9 and H1. 63MoO3 thick films, J. Alloys Compd. 366 (2004) 54-60.

DOI: 10.1016/s0925-8388(03)00736-9

[4] C.V. Ramana, V.V. Atuchin, V.G. Kesler, V.A. Kochubey, L.D. Pokrovsky, V. Shutthanandan, U. Becker, R.C. Ewing, Growth and surface characterization of sputter-deposited molybdenum oxide thin films, Appl. Surf. Sci, 253 (2007) 5368-5374.

DOI: 10.1016/j.apsusc.2006.12.012

[5] V.V. Atuchin, T.A. Gavrilova, V.G. Kostrovsky, L.D. Pokrovsky, I.B. Troitskaia, Morphology and structure of hexagonal MoO3 nanorods, Inorg. Mater. 44 (6) (2008) 622-627.

DOI: 10.1134/s0020168508060149

[6] V.V. Atuchin, O.D. Chimitova, T.A. Gavrilova, M.S. Molokeev, Sung-Jin Kim, N.V. Surovtsev, B.G. Bazarov, Synthesis, structural and vibrational properties of microcrystalline RbNd(MoO4)2, J. Cryst. Growth 318 (2011) 683-686.

DOI: 10.1016/j.jcrysgro.2010.09.076

[7] Chang Sung Lim, Solid-state metathetic synthesis of BaMO4 (M = W, Mo) assisted by microwave irradiation, J. Ceram. Pross. Res. 12 (5) (2011) 544-548.

[8] V.V. Atuchin, T.A. Gavrilova, T.I. Grigorieva, N.V. Kuratieva, K.A. Okotrub, N.V. Pervukhina, N.V. Surovtsev, Sublimation growth and vibrational microspectrometry of a-MoO3 single crystals, J. Cryst. Growth 318 (2011) 987-990.

DOI: 10.1016/j.jcrysgro.2010.10.149

[9] S. Rajagopal, D. Nataraj, O. Yu. Khyzhun, Yahia Djaoued, Jacques Robichaud, K. Senthil, D. Mangalaraj, Systematic synthesis and analysis of change in morphology, electronic structure and photoluminescence properties of pyrazine intercalated MoO3 hybrid nanostructures, Cryst. EngComm 13 (2011).

DOI: 10.1039/c0ce00303d

[10] V.V. Atuchin, V.G. Grossman, S.V. Adichtchev, N.V. Surovtsev, T.A. Gavrilova, B.G. Bazarov, Structural and vibrational properties of microcrystalline TlM(MoO4)2 (M = Nd, Pr) molybdates, Opt. Mater. 34 (5) (2012) 812-816.

DOI: 10.1016/j.optmat.2011.11.016

[11] V.V. Atuchin, M.S. Molokeev, G. Yu. Yurkin, T.A. Gavrilova, V.G. Kesler, N.M. Laptash, I.N. Flerov, G.S. Patrin, Synthesis, structural, magnetic, and electronic properties of cubic CsMnMoO3F3 oxyfluoride, J. Phys. Chem. C 116 (2012) 10162-10170.

DOI: 10.1021/jp302020f

[12] V.V. Atuchin, O.D. Chimitova, S.V. Adichtchev, B.G. Bazarov, T.A. Gavrilova, M.S. Molokeev, N.V. Surovtsev, Zh.G. Bazarova, Syhtnesis, structural and vibrational properties of microcrystalline b-RbSm(MoO4)2, Mater. Lett. 106 (2013) 26-29.

DOI: 10.1016/j.matlet.2013.04.039

[13] Chang Sung Lim, Upconversion photoluminescence properties of SrY2(MoO4)4: Er3+/Yb3+ phosphors synthesized by a cyclic microwave-modified sol-gel method, Infrared Phys. Techn. 67 (2014) 371-376.

DOI: 10.1016/j.infrared.2014.08.018

[14] V.V. Atuchin, A.S. Aleksandrovsky, O.D. Chimitova, T.A. Gavrilova, A.S. Krylov, M.S. Molokeev, A.S. Oreshonkov, B.G. Bazarov, J.G. Bazarova, Synthesis and spectroscopic properties of monoclinic a-Eu2(MoO4)3, J. Phys. Chem. C 118 (28) (2014).

DOI: 10.1021/jp5040739

[15] D.A. Spassky, V.N. Shlegel, N.V. Ivannikova, A.P. Yelisseyev, A.N. Belsky, Luminescent properties of Pb2MoO5 single crystals, Opt. Mater. 42 (2015) 430-434.

DOI: 10.1016/j.optmat.2015.01.041

[16] Jun Ho Chung, Jeong Ho Ryu, Sung Wook Mhin, Kang Min Kim and Kwang Bo Shim, Controllable white upconversion luminescence in Ho3+/Tm3+/Yb3+ co-doped CaMoO4, J. Mater. Chem. 2012, 22, 3997-4002.

DOI: 10.1039/c2jm15332g

[17] A.K. Parchur, A.I. Prasad, A.A. Ansari, S.B. Rai, R.S. Ningthoujam, Luminescence properties of Tb3+-doped CaMoO4 nanoparticles: annealing effect, polar medium dispersible, polymer film and core–shell formation , Dalton Trans. 2012, 41, 11032-11045.

DOI: 10.1039/c2dt31257c

[18] N. Sharma, K. M. Shaju, G. V. Subba Rao, B. V. R. Chowdari, Z. L. Dong, T. J. White, Carbon-coated nanophase CaMoO4 as anode material for Li ion batteries, Chem. Mater. 16 (3) (2004) 504-512.

DOI: 10.1002/chin.200415017

[19] V.V. Atuchin, T.A. Gavrilova, S.A. Gromilov, V.G. Kostrovsky, L.D. Pokrovsky, I.B. Troitskaia, R.S. Vemuri, G. Carbajal-Franco, C.V. Ramana, Low-temperature chemical synthesis and microstructure analysis of GeO2 crystals with a-quartz structure, Cryst. Growth Des. 9 (4) (2009).

DOI: 10.1021/cg8010037

[20] V.V. Atuchin, T.A. Gavrilova, V.G. Kesler, M.S. Molokeev, K.S. Aleksandrov, Low-temperature synthesis and structural properties of ferroelectric K3WO3F3, Chem. Phys. Lett. 493 (2010) 83-86.

DOI: 10.1016/j.cplett.2010.05.023

[21] V.V. Atuchin, I.B. Troitskaia, O. Yu. Khyzhun, V.L. Bekenev, Yu.M. Solonin, Electronic structure of h-WO3 and CuWO4 nanocrystals, harvesting materials for renewable energy systems and functional devices, Appl. Mech. Mater. 110-116 (2012).

DOI: 10.4028/www.scientific.net/amm.110-116.2188

[22] L.I. Gongorova, B.G. Bazarov, O.D. Chimitova, A.G. Anshits, T.A. Vereschagina, R.F. Klevtsova, L.A. Glinskaya, Z.G. Bazarova, Crystal structure of a new ternary molybdate Rb5CeZr(MoO4)6, J. Struct. Chem. 53 (2) (2012) 329-333.

DOI: 10.1134/s0022476612020175

[23] V.V. Atuchin, A.S. Aleksandrovsky, O.D. Chimitova, A.S. Krylov, M.S. Molokeev, B.G. Bazarov, J.G. Bazarova, Zhiguo Xia, Synthesis and spectroscopic properties of multiferroic b¢-Tb2(MoO4)3, Opt. Mater. 36 (2014) 1631-1635.

DOI: 10.1016/j.optmat.2013.12.008

[24] C.V. Ramana, V.V. Atuchin, I.B. Troitskaia, S.A. Gromilov, V.G. Kostrovsky, G.B. Saupe, Low-temperature synthesis of morphology controlled metastable hexagonal molybdenum trioxide (MoO3), Solid State Commun. 149 (2009) 6-9.

DOI: 10.1016/j.ssc.2008.10.036

[25] T.A. Gavrilova, O.P. Andreeva, V.V. Atuchin, I.V. Korolkov, I.S. Soldatenkov, Synthesis and micromorphology transformation of monoclinic a-Gd2(MoO4)3, Solid State Phenom. 213 (2014) 165-169.

DOI: 10.4028/www.scientific.net/ssp.213.165

[26] V.V. Atuchin, Lei Zhu, Soo Hyun Lee, Dae Hyun Kim, Chang Sung Lim, Preparation and optical properties of Sr3V2O8 nanoparticles via microwave-assisted solvothermal route, Asian J. Chem. 26 (5) (2014) 1290-1292.

DOI: 10.14233/ajchem.2014.17211

[27] V.V. Atuchin, O.P. Andreeva, I.V. Korolkov, E.A. Maximovskiy, C.S. Lim, Low-temperature synthesis and structural properties of PbMoO4 nanocrystals, Asian J. Chem. 26 (5) (2014) 1287-1289.

DOI: 10.14233/ajchem.2014.17210

[28] V.V. Atuchin, V.V. Kaichev, I.V. Korolkov, A.A. Saraev, I.B. Troitskaia, T.V. Perevalov, V.A. Gritsenko, Electronic structure of noncentrosymmetric a-GeO2 with oxygen vacancy: ab initio calculations and comparison with experiment, J. Phys. Chem. C 118 (7) (2014).

DOI: 10.1021/jp411751c

[29] G. Ahmad, M.B. Dickenson, B.C. Church, Ye Cai, S.E. Jones, R.R. Naik, J.S. King, C.J. Summers, N. Kröger, K.H. Sandhage, Rapid, room-temperature formation of crystalline calcium molybdate phosphor microparticles via peptide-induced precipitation, Adv. Mater. 18 (2006).

DOI: 10.1002/adma.200600243

[30] Yong-Song Luo, Xiao-Jun Dai, Wie-Dong Zhang, Yang Yang, Chang Q. Sun, Shao-Yun Fu, Controlable synthesis and luminescent properties of novel erythrocyte-like CaMoO4 hierarchical nanostructures via a simple surfactant-free hydrothermal route, Dalton Trans. 39 (2010).

DOI: 10.1039/b915099d

[30] Mi Yan, Huang Zai-Yin, Jiang Jun-Ying, Li Yan-Fen, In situ microcalorimetry insight into the CaMoO4 microcrystallites, Acta Phys. – Chim. Sin. 25 (12) (2009) 2422-2426.

DOI: 10.3866/pku.whxb20091215

[31] S.P. Culver, F.A. Rabuffetti, Shiliang Zhou, M. Macklenburg, Yan Song, B.C. Melot, R.I. Brutchey, Low-temperature synthesis of AMoO4 (A = Ca, Sr, Ba) scheelite nanocrystals, Chem. Mater. 25 (2013) 4129-4134.

DOI: 10.1021/cm402867y

[32] R.M. Hansen, L.W. Finger, J.W.E. Mariathasan, High-pressure crystal chemistry of scheelite-type tungstates and molybdates, J. Phys. Chem. Solids 46 (2) (1985) 253-263.

DOI: 10.1016/0022-3697(85)90039-3