A Series of [Ln(NO3)3(4’-(4-Bromophenyl)-2,2’:6’,2’’-Terpyridine)] Lanthanide Derivatives

Piedraescrita Gallardo; Elisa Abas; Alicia Buceta; Francisco Merchán; Asunción Luquin; Saif A. Haque; Mariano Laguna

doi:10.4028/www.scientific.net/SSP.257.160

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A Series of [Ln(NO₃)₃(4’-(4-Bromophenyl)-2,2’:6’,2’’-Terpyridine)] Lanthanide Derivatives

Abstract:

Lanthanide complexes [Ln (NO₃)₃(4’-(4-bromophenyl)-2,2’:6’,2’’-terpyridine)]; being Ln all the non radiative lanthanide elements (1 – 14), have been synthesized and characterized by IR, ¹H NMR, MALDI-MS and the X-ray structures of the La, Nd, Sm, Eu and Dy complexes, showing a linear comparison of the average M-O and M-N distances with the ionic radius or the number of f electrons of the lanthanides. The luminescence properties of complexes 4 (Nd), 5 (Sm), 6 (Eu), 8 (Tb), 9 (Dy) in the solid state and in the acetonitrile solutions of 5 (Sm) and 6 (Eu) are reported.

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Solid State Phenomena (Volume 257)

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160-164

DOI:

https://doi.org/10.4028/www.scientific.net/SSP.257.160

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October 2016

Authors:

Piedraescrita Gallardo, Elisa Abas, Alicia Buceta, Francisco Merchán, Asunción Luquin, Saif A. Haque, Mariano Laguna*

Keywords:

Coordination Complexes, Lanthanide, Luminiscence, Terpyridine, X-Ray

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