The Effect of Fiber Surface Treatment on the Water Absorption and Morphological Properties of Linear Low Density Polyethylene/Poly(Vinyl Alcohol)/Kenaf Composites

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The effect of untreated and treated (chromium sulfate and sodium bicarbonate) kenaf (KNF) on the water uptake and morphological properties of linear low density polyethylene/poly(vinyl alcohol)/kenaf (LLDPE/PVOH/KNF) composites was studied. The composites were prepared by using an internal mixer (Haake Polydrive) at 150 °C and 50 rpm for 10 min. The results showed that the untreated composites tend to absorb greater amount of water compared to the treated composites. This shows that the chromium sulfate and sodium bicarbonate treatment on KNF had improved the interfacial adhesion between KNF and LLDPE/PVOH matrices. Consequently, the capability of water absorption by the treated composites was reduced. Scanning electron microscope (SEM) result shows that lesser traces of filler pull-out and better filler-matrix interfacial adhesion were observed in the tensile fractured surfaces of treated composites.

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Solid State Phenomena (Volume 264)

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1-4

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September 2017

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© 2017 Trans Tech Publications Ltd. All Rights Reserved

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[1] H.M. Akil, M.F. Omar, A.A.M. Mazuki, S. Safiee, Z.A.M. Ishak, A.A. Bakar, Kenaf fiber reinforced composites: A review, Mater. Des. 32 (2011) 4107-4121.

DOI: 10.1016/j.matdes.2011.04.008

Google Scholar

[2] A.L. Pang, and H. Ismail, Studies on the properties of polypropylene/(waste tire dust)/kenaf (PP/WTD/KNF) composites with addition of phthalic anhydride (PA) as a function of KNF loading, J. Vinyl. Add. Tecnhol. 20 (2014) 193-200.

DOI: 10.1002/vnl.21365

Google Scholar

[3] M. George, P.G. Mussone, D.C. Bressler, Modification of the cellulosic component of hemp fibers using sulfonic acid derivatives: Surface and thermal characterization, Carbohyd. Polym. 134 (2015) 230-239.

DOI: 10.1016/j.carbpol.2015.07.096

Google Scholar

[4] R. Malkapuram, V. Kumar, Y. S. Negi, Recent development in natural fiber reinforced polypropylene composites, J. Reinf. Plast. Compos. 28 (2009) 1169-1189.

DOI: 10.1177/0731684407087759

Google Scholar

[5] A.L. Pang, H. Ismail, A.A. Bakar, Effects of kenaf loading on processability and properties of linear low-density polyethylene/poly (vinyl alcohol)/kenaf composites, Biores. 10 (2015) 7302-7314.

DOI: 10.15376/biores.10.4.7302-7314

Google Scholar

[6] N.S. Balakrishna, H. Ismail, N. Othman, The effects of rattan filler loadings on properties of rattan powder-filled polypropylene composites, Biores. 7 (2012) 5677-5690.

DOI: 10.4028/www.scientific.net/amr.626.1010

Google Scholar

[7] M. Farsi, Thermoplastic matrix reinforced with natural fibers: A study on interfacial behavior, in: J. Wang (Ed. ), Some critical issues for injection molding, In Tech Publisher, Croatia, 2012, pp.225-250.

DOI: 10.5772/34527

Google Scholar

[8] N.F. Zaaba, H. Ismail, M. Jaafar, The effects of modifying peanut shell powder with polyvinyl alcohol on the properties of recycled polypropylene and peanut shell powder composites, Biores. 9 (2014) 2128-2142.

DOI: 10.15376/biores.9.2.2128-2142

Google Scholar

[9] M.M. Kabir, H. Wang, K.T. Lau, F. Cardona, Chemical treatments on plant-based natural fiber reinforced polymer composites: An overview, Compos. Part B, 43 (2012) 2883-2892.

DOI: 10.1016/j.compositesb.2012.04.053

Google Scholar

[10] A.L. Pang, H. Ismail, A.A. Bakar, Tensile properties, water resistance, and thermal properties of linear low-density polyethylene/polyvinyl alcohol/kenaf composites: Effect of 3-(trimethoxysilyl)propyl methacrylate (TMS) as a silane coupling agent, Biores. 11 (2016).

DOI: 10.15376/biores.11.3.5889-5904

Google Scholar

[11] B.K. Tan, Y.C. Ching, S.N. Gan, S. Ramesh, M.R. Rahman, Water absorption properties of kenaf fibre-poly (vinyl alcohol) composites, Mater. Research. Inno. 18 (2014) 144-146.

DOI: 10.1179/1432891714z.000000000946

Google Scholar