Influence of the Mole Ratio of Salt to Alkali on the Surface Structure of SnO2 Thin Film

Article Preview

Abstract:

This work investigated the effects of molar ratio of salt to alkali on the properties of tin oxide nanofilms to provide reference for optimizing its photoelectric conversion efficiency. The tin oxide film grown by hydrothermal method exhibited poor film-forming property. The macroscopic analysis revealed the formation of a thick film. The bonding force to the FTO substrate was poor, its brittle, and easy to fall off. When the molar ratio of salt to alkali was 1:8, the tin oxide film exhibited improved microstructure and large specific surface area, which could benefit electron transport. Moreover, the film showed excellent photoelectric conversion performance. However, mechanical properties, such as adhesion between the tin oxide film and the conductive glass FTO, remain to be improved.

You might also be interested in these eBooks

Info:

Periodical:

Solid State Phenomena (Volume 279)

Pages:

192-196

Citation:

Online since:

August 2018

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2018 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] X. Ma, X. Y. Ni, Using upconversion nanoparticles to improve photovoltaic properties of poly(3-hexylthiophene)-TiO2 heterojunction solar cell, J. Nanopart. Res. 15 (2013) 1547-1553.

DOI: 10.1007/s11051-013-1547-z

Google Scholar

[2] J.G. Song, L. Hua, Q. Shen, Effect of pH value on the properties of SnO2 nano-cystalline for dye sensitized solar cells, Key Eng. Mater. 633 (2015) 273-276.

DOI: 10.4028/www.scientific.net/kem.633.273

Google Scholar

[3] W.Y. Shi, B.S. Peng, Y.Y. Guo, Synthesis of asymmetric zinc phthalocyanine with bulky diphenylthiophenol substituents and its photovoltaic performance for dye-sensitized solar cells, J. Photochem. Photobiol. A: Chem. 321 (2016) 248-256.

DOI: 10.1016/j.jphotochem.2016.02.009

Google Scholar

[4] L.J. Li, C.L. Wang, J.Y. Liao, Arumugam manthiram dual-template synthesis of N-doped macro/mesoporous carbon with an open-pore structure as a metal-free catalyst for dye-sensitized solar cells, J. Power Sourc. 300 (2015) 254-260.

DOI: 10.1016/j.jpowsour.2015.09.076

Google Scholar

[5] R. Li, Y. Zhao, R.E. Hou, Enhancement of power conversion efficiency of dye sensitized solar cells by modifying mesoporous TiO2 photoanode with Al-doped TiO2 layer, J. Photochem. Photobiol. A: Chem. 319 (2016) 62-69.

DOI: 10.1016/j.jphotochem.2016.01.002

Google Scholar

[6] J. Du, F. Bittner, D.S. Hecht, A carbon nanotube-based transparent conductive substrate for flexible ZnO dye-sensitized solar cells, Thin Solid Film. 531 (2013) 391-397.

DOI: 10.1016/j.tsf.2012.12.051

Google Scholar

[7] S.A. Mozaffari, M. Ranjbar, E. Kouhestanian, An investigation on the effect of electrodeposited nanostructured ZnO on the electron transfer process efficiency of TiO2 based DSSC, Mater. Sci. Semicond. Process. 40 (2015) 285-292.

DOI: 10.1016/j.mssp.2015.06.081

Google Scholar

[8] J.T Park, C.S Lee, J.H. Kim, High performance electrocatalyst consisting of CoS nanoparticles on an organized mesoporous SnO2 film: its use as a counter electrode for Pt-free, dye-sensitized solar cells, Nanoscale. 7 (2015) 670-678.

DOI: 10.1039/c4nr05779a

Google Scholar

[9] A. Abdelkrim, S. Rahmane, O. Abdelouahab, Effect of solution concentration on the structural, optical and electrical properties of SnO2 thin films prepared by spray pyrolysis, Int. J. Light Elect. Optic. 127 (2016) 2653-2658.

DOI: 10.1016/j.ijleo.2015.11.232

Google Scholar