Enhanced Photocatalytic Activity of Cu1.8Se/CuAgSe for Organic Pollutants under Visible and Near-Infrared Light

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The Cu1.8Se/CuAgSe nanostructure was synthesized by a simple two-step process. Starting with the template of cubic Cu1.8Se nanoplate by precipitation method, Cu1.8Se/CuAgSe nanostructure and ternary CuAgSe were prepared through a rapid ion exchange reaction using various amount of AgNO3 at room temperature. The as-prepared samples were analyzed by XRD, SEM and DRS. It was found that Cu1.8Se/CuAgSe heterostructure and the pure CuAgSe phase were formed without changing the morphology, and these samples had efficient light absorption from UV light to near-infrared light region. Photocatalytic properties of these samples were evaluated by the degradation of Congo red under visible and near-infrared light. The Cu1.8Se/CuAgSe nanostructure showed enhanced photocatalytic activity due to the lower recombination of charge-carrier in the photodegradation process.

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Solid State Phenomena (Volume 281)

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825-829

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August 2018

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© 2018 Trans Tech Publications Ltd. All Rights Reserved

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[1] Mi, L.; Wei, W.; Zheng, Z.; et al., Ag+ insertion into 3D hierarchical rose-like Cu 1.8 Se nanocrystals with tunable band gap and morphology genetic. Nanoscale. 6 (2) (2014) 1124-1133.

DOI: 10.1039/c3nr04923j

Google Scholar

[2] Zhao, Y.; Burda, C., Development of plasmonic semiconductor nanomaterials with copper chalcogenides for a future with sustainable energy materials. Energy & Environmental Science. 5 (2) (2012) 5564-5576.

DOI: 10.1039/c1ee02734d

Google Scholar

[3] Chen, W. S.; Stewart, J.; Mickelsen, R., Polycrystalline thin‐film Cu2− x Se/CdS solar cell. Applied Physics Letters. 46 (11) (1985) 1095-1097.

DOI: 10.1063/1.95773

Google Scholar

[4] Qiao, L.-N.; Wang, H.-C.; Shen, Y.; Lin, Y.-H.; Nan, C.-W., Enhanced Photocatalytic Performance under Visible and Near-Infrared Irradiation of Cu1. 8Se/Cu3Se2 Composite via a Phase Junction. Nanomaterials. 7 (1) (2017) 19.

DOI: 10.3390/nano7010019

Google Scholar

[5] Moroz, N.; Olvera, A.; Willis, G.; Poudeu, P., Rapid direct conversion of Cu 2− x Se to CuAgSe nanoplatelets via ion exchange reactions at room temperature. Nanoscale. 7 (21) (2015) 9452-9456.

DOI: 10.1039/c5nr01451d

Google Scholar

[6] Li, H.; Zanella, M.; Genovese, A.; Povia, M.; et al., Sequential cation exchange in nanocrystals: preservation of crystal phase and formation of metastable phases. Nano letters. 11 (11) (2011) 4964-4970.

DOI: 10.1021/nl202927a

Google Scholar

[7] Beberwyck, B. J.; Alivisatos, A. P., Ion exchange synthesis of III–V nanocrystals. Journal of the American Chemical Society. 134 (49) (2012) 19977-19980.

DOI: 10.1021/ja309416c

Google Scholar

[8] Miyatani, S.-y.; Miura, Y.; Ando, H., Mixed conduction in AgCuSe. Journal of the Physical Society of Japan. 46 (6) (1979) 1825-1832.

DOI: 10.1143/jpsj.46.1825

Google Scholar

[9] Ishiwata, S.; Shiomi, Y.; Lee, J.; et al., Extremely high electron mobility in a phonon-glass semimetal. Nature materials. 12 (6) (2013) 512-517.

DOI: 10.1038/nmat3621

Google Scholar

[10] Han, C.; Sun, Q.; Cheng, Z. X.; et al., Ambient scalable synthesis of surfactant-free thermoelectric CuAgSe nanoparticles with reversible metallic-np conductivity transition. Journal of the American Chemical Society. 136 (50) (2014) 17626-17633.

DOI: 10.1021/ja510433j

Google Scholar

[11] Hong, A.; Li, L.; Zhu, H.; et al., Anomalous transport and thermoelectric performances of CuAgSe compounds. Solid State Ionics. 261 (2014) 21-25.

DOI: 10.1016/j.ssi.2014.03.025

Google Scholar

[12] Butler, M., Photoelectrolysis and physical properties of the semiconducting electrode WO2. Journal of Applied Physics. 48 (5) (1977) 1914-(1920).

DOI: 10.1063/1.323948

Google Scholar

[13] Xu, C.; Liu, Y.; Huang, B.; Li, H.; Qin, X.; Zhang, X.; Dai, Y., Preparation, characterization, and photocatalytic properties of silver carbonate. Applied Surface Science. 257 (20) (2011) 8732-8736.

DOI: 10.1016/j.apsusc.2011.05.060

Google Scholar

[14] Butler, M.; Ginley, D., Prediction of flatband potentials at semiconductor‐electrolyte interfaces from atomic electronegativities. Journal of the Electrochemical Society. 125 (2) (1978) 228-232.

DOI: 10.1149/1.2131419

Google Scholar

[15] Lv, J.; Kako, T.; Zou, Z.; Ye, J., Band structure design and photocatalytic activity of In 2 O 3/N–InNbO 4 composite. Applied Physics Letters. 95 (3) (2009) 032107.

DOI: 10.1063/1.3183507

Google Scholar

[16] Xu, Y.; Schoonen, M. A., The absolute energy positions of conduction and valence bands of selected semiconducting minerals. American Mineralogist. 85 (3-4) (2000) 543-556.

DOI: 10.2138/am-2000-0416

Google Scholar

[17] Wang, H.; Zhang, L.; Chen, Z.; et al., Semiconductor heterojunction photocatalysts: design, construction, and photocatalytic performances. Chem. Soc. Rev. 43 (15) (2014) 5234-5244.

DOI: 10.1039/c4cs00126e

Google Scholar