Novel Method for Comprehensive Processing of Low-Grade Copper Concentrate

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Abstract:

Low grade copper concentrate, composed mainly of plagioclase, quartz, pyrite, chlorite, chalcopyrite, glauconite, is a promising source for the future recovery of copper and other valuable components which processing by existing methods is not economical. An alkali fusion-leaching method followed by acid leaching for extraction of copper, aluminum, silica, iron and silver from such low-grade copper concentrate was explored in this research. The samples were characterized by using wet chemical analysis and X-ray diffraction. An alkali-fusing-leaching method for processing of low-grade copper concentrate allows to extract in a solution of 62% Si, 70% Fe, 95% Ag, 97% Al and 98% of Cu with the following optimal parameters: NaOH/concentrate mass ratio = 175%, fusion temperature = 375 °C, the fusion time = 90 min. The proposed method is suitable for the comprehensive processing of the low-grade copper concentrate.

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Solid State Phenomena (Volume 284)

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856-862

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October 2018

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© 2018 Trans Tech Publications Ltd. All Rights Reserved

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[1] L. Sinclair, J. Thompson, In situ leaching of copper: challenges and future prospects, Hydrometallurgy. 157 (2015) 306-324.

DOI: 10.1016/j.hydromet.2015.08.022

Google Scholar

[2] D. A. Singer, Future copper resources, Ore Geology Reviews. 86 (2017) 271-279.

DOI: 10.1016/j.oregeorev.2017.02.022

Google Scholar

[3] M. Misra, M.C. Fuerstenau, Chalcopyrite leaching at moderate temperature and ambient pressure in the presence of nanosize silica, Minerals Engineering. 18 (2005) 293-297.

DOI: 10.1016/j.mineng.2004.06.014

Google Scholar

[4] T. Khonthu, J. Wiese, C.T. O'Connor, A comparative study of the flotation performance of ores treated in an IsaMill and a ball mill, IMPC 2012. 26 (2012) 2421-2428.

Google Scholar

[5] X. Ye, S. Gredelj, W. Skinner, S.R. Grano, Regrinding sulphide minerals - Breakage mechanisms in milling and their influence on surface properties and flotation behavior, Powder Technology. 203 (2010) 133-147.

DOI: 10.1016/j.powtec.2010.05.002

Google Scholar

[6] S. Palaniandy, Impact of mechanochemical effect on chalcopyrite leaching, Int. J. Miner. Process. 136 (2015) 56-65.

Google Scholar

[7] E. Jorjani, A. Ghahreman, Challenges with elemental sulfur removal during the leaching of copper and zinc sulfides, and from the residues; a review, Hydrometallurgy. 171 (2017) 333-343.

DOI: 10.1016/j.hydromet.2017.06.011

Google Scholar

[8] R.G. McDonald, D.M. Muir, Pressure oxidation leaching of chalcopyrite 1. Comparison of high and low temperature reaction kinetics and products, Hydrometallurgy. 86 (2007) 191-205.

DOI: 10.1016/j.hydromet.2006.11.015

Google Scholar

[9] I.V. Ukraintsev, G.V. Petrov, B.S. Ivanov, A.Ya. Boduen, Autoclave conditioning of a low-grade sulphide copper concentrate, Tsvetnye Metally. 10 (2016) 43-48.

DOI: 10.17580/tsm.2016.10.06

Google Scholar

[10] D.A. Rogozhnikov, B.V. Kolmachikhin, Polymetallic ore concentration middlings Nitric Acid leaching kinetics, Solid State Phenomena. 265 (2017) 1065-1070.

DOI: 10.4028/www.scientific.net/ssp.265.1065

Google Scholar

[11] D.A. Rogozhnikov, S.V. Mamyachenkov, O.S. Anisimova, Nitric Acid Leaching of Copper-Zinc Sulfide Middlings, Metallurgist. 60 (2016) 229-233.

DOI: 10.1007/s11015-016-0278-7

Google Scholar

[12] C.G. Anderson, The Optimization, Design and Economics of Industrial NSC Oxidative Pressure Leaching Of Complex Sulfide Concentrates, Inter. J. of Eng. and Science. 2 (2013) 01-16.

Google Scholar

[13] Y. Dong, H. Lin, X. Xu, S. Zhou, Bioleaching of different copper sulfides by Acidithiobacillus ferrooxidans and its adsorption on minerals, Hydrometallurgy. 140 (2013) 42-47.

DOI: 10.1016/j.hydromet.2013.05.009

Google Scholar

[14] Z. Manafi, H. Abdollahi, O.H. Tuovinen, Shake flask and column bioleaching of a pyritic porphyry copper sulphide ore, Int. J. Miner. Process. 119 (2013) 16-20.

DOI: 10.1016/j.minpro.2012.12.010

Google Scholar

[15] A.G. Bulaev, M.I. Muravyov, T.A. Pivovarova, N.V. Fomchenko, T.F. Kondrat'eva, Bioprocessing of mining and metallurgical wastes containing nonferrous and precious metals, Advanced Materials Research. 825 (2013) 301-304.

DOI: 10.4028/www.scientific.net/amr.825.301

Google Scholar

[16] X. Ma, J. Yang, H. Ma, C. Liu, Hydrothermal extraction of potassium from potassic quartz syenite and preparation of aluminum hydroxide, Int. J. Miner. Process. 147 (2016) 10-17.

DOI: 10.1016/j.minpro.2015.12.007

Google Scholar

[17] I.V. Loginova, A.V. Kyrchikov, V.A. Lebedev, S.F. Ordon, Investigation into the Question of Complex Processing of Bauxites of the Srednetimanskoe Deposit, Russian Journal of Non-Ferrous Metals. 54 (2013) 143-147.

DOI: 10.3103/s1067821213020089

Google Scholar

[18] I.V. Loginova, A.A. Shoppert, L.I. Chaikin, Extraction of Rare-Earth Metals During the Systematic Processing of Diaspore Boehmite Bauxites, Metallurgist. 60 (2016) 198-203.

DOI: 10.1007/s11015-016-0273-z

Google Scholar

[19] A.А. Shoppert, I. V. Loginova, L. I. Chaikin, and D. A. Rogozhnikov, Alkali fusion-leaching method for comprehensive processing of fly ash, Technogen Conference Proceedings, KnE Materials Science. 1 (2017) 89-96.

DOI: 10.18502/kms.v2i2.952

Google Scholar

[20] D. Li, X. Guo, Z. Xu, Q. Tian, Q. Feng, Leaching behavior of metals from copper anode slime using an alkali fusion-leaching process, Hydrometallurgy. 157 (2015) 9-12.

DOI: 10.1016/j.hydromet.2015.07.008

Google Scholar

[21] X. Guo, J. Liu, H. Qin, Y. Liu, Q. Tian, D. Li, Recovery of metal values from waste printed circuit boards using an alkali fusion–leaching–separation process, Hydrometallurgy. 156 (2015) 199-205.

DOI: 10.1016/j.hydromet.2015.06.011

Google Scholar