Removal of Manganese from Aqueous Solution Using Indonesian Peat

Article Preview

Abstract:

Peat can be used as a natural adsorbent due to its humic acid content having various active functional groups such as carboxylates and hydroxyl groups. Peat soil samples obtained from Pelalawan district, Riau province of Indonesia were selected and their adsorption capacities were investigated using Mn(II) solution as a model solution. The raw peat samples were first prepared by drying at 110°C for 12 h. The adsorption experiment was conducted in batch test using Mn(II) solutions for 360 mins at pH of 5.2 as optimum conditions. The peat samples were analyzed using the Fourier Transform Infrared Spectroscopy, Surface Area Analysis and Scanning Electron Microscopy- Energy Dispersive Spectroscopy. The obtained adsorption data were fitted using Langmuir, Freundlich and BET isotherm models. It was found that the adsorption data followed the Langmuir isotherm model with correlation coefficients (R2) ranging between 0.9866-0.9997 and the adsorption capacities were between 11.99-22.94 mg/g.

You might also be interested in these eBooks

Info:

Periodical:

Solid State Phenomena (Volume 302)

Pages:

141-147

Citation:

Online since:

April 2020

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2020 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Xiong, J.B. and Q. Mahmood, Adsorptive removal of phosphate from aqueous media by peat. Desalin, 2010. 259(1-3): pp.59-64.

DOI: 10.1016/j.desal.2010.04.035

Google Scholar

[2] Abat, M., et al., Adsorption and desorption of copper and zinc in tropical peat soils of Sarawak, Malaysia. Geo, 2012. 175-176: pp.58-63.

DOI: 10.1016/j.geoderma.2012.01.024

Google Scholar

[3] Chieng, H.I., L.B.L. Lim, and N. Priyantha, Sorption characteristics of peat from Brunei Darussalam for the removal of rhodamine B dye from aqueous solution: adsorption isotherms, thermodynamics, kinetics and regeneration studies. Desalin Wat Treat, 2015. 55(3): pp.664-677.

DOI: 10.1080/19443994.2014.919609

Google Scholar

[4] Zehra, T., et al., Sorption characteristics of peat of Brunei Darussalam V: removal of Congo red dye from aqueous solution by peat. Desalin Wat Treat, 2015. 54(9): pp.2592-2600.

DOI: 10.1080/19443994.2014.899929

Google Scholar

[5] Brown, P.A., S.A. Gill, and S.J. Allen, Metal removal from wastewater using peat. Wat Res, 2000. 34(16): pp.3907-3916.

DOI: 10.1016/s0043-1354(00)00152-4

Google Scholar

[6] Liu, Z.-r., et al., Competitive adsorption of heavy metal ions on peat. J China Univ Min Technol, 2008. 18(2): pp.255-260.

Google Scholar

[7] Dawodu, F.A. and K.G. Akpomie, Simultaneous adsorption of Ni(II) and Mn(II) ions from aqueous solution unto a Nigerian kaolinite clay. J Mat Res Technol, 2014. 3(2): pp.129-141.

DOI: 10.1016/j.jmrt.2014.03.002

Google Scholar

[8] Belviso, C., et al., Removal of Mn from aqueous solution using fly ash and its hydrothermal synthetic zeolite. J Environ Manag, 2014. 137: pp.16-22.

DOI: 10.1016/j.jenvman.2014.01.040

Google Scholar

[9] Inglezakis, V., et al., Removal of iron and manganese from underground water by use of natural minerals in batch mode treatment. Desalin Wat Treat, 2010. 18: pp.341-346.

DOI: 10.5004/dwt.2010.1102

Google Scholar

[10] Bartczak, P., et al., Removal of nickel(II) and lead(II) ions from aqueous solution using peat as a low-cost adsorbent: A kinetic and equilibrium study. Arab J Chem, 2018. 11(8): pp.1209-1222.

DOI: 10.1016/j.arabjc.2015.07.018

Google Scholar

[11] Hei Ing, C., et al., Sorption characteristics of peat of Brunei Darussalam IV: equilibrium, thermodynamics and kinetics of adsorption of methylene blue and malachite green dyes from aqueous solution. Environ Earth Sci, 2014. 72(7): pp.2263-2277.

DOI: 10.1007/s12665-014-3135-7

Google Scholar

[12] Khadiran, T., et al., Textural and Chemical Properties of Activated Carbon Prepared from Tropical Peat Soil by Chemical Activation Method. Biores, 2014. 10(1): p.22.

DOI: 10.15376/biores.10.1.986-1007

Google Scholar

[13] Lim, L., et al., Sorption characteristics of peat of Brunei Darussalam I: characterization of peat and adsorption equilibrium studies of methylene blue-peat interactions. Cey. J. Sci., 2013. 17: pp.41-51.

DOI: 10.1007/s12665-014-3135-7

Google Scholar

[14] Batista, A.P., et al., Biosorption of Cr(III) using in natura and chemically treated tropical peats. J Hazard Mat, 2008. 163: pp.517-23.

DOI: 10.1016/j.jhazmat.2008.06.129

Google Scholar

[15] Yuliani, G., G. Garnier, and A.L. Chaffee, Utilization of raw and dried Victorian brown coal in the adsorption of model dyes from solution. J Wat Process Eng, 2017. 15: pp.43-48.

DOI: 10.1016/j.jwpe.2016.06.004

Google Scholar

[16] Yuliani, G., I. Noviyana, and A. Setiabudi, Enrichment of Indonesian Low Rank Coal's Surface (SOCs) using hidrogen peroxides and its adsortive properties. Adv Mat Res, 2014. 869: p.159.

DOI: 10.4028/www.scientific.net/amr.896.159

Google Scholar

[17] Mahajan, O.P., CO2 surface area of coals: The 25-year paradox. Carbon, 1991. 29(6): pp.735-742.

DOI: 10.1016/0008-6223(91)90010-g

Google Scholar

[18] Woskoboenko, F., W.O. Stacy, and D. Raisbeck, Physical structure and properties of brown coal, in The science of Victorian brown coal: structure, properties and consequences for utilization, R.A. Durie, Editor. 1991, Butterworth-Heinemann: Oxford. pp.152-246.

DOI: 10.1016/b978-0-7506-0420-8.50009-9

Google Scholar

[19] Kan, C.-C., et al., Adsorption of Mn2+ from aqueous solution using Fe and Mn oxide-coated sand. J Enviro Sci, 2013. 25(7): pp.1483-1491.

DOI: 10.1016/s1001-0742(12)60188-0

Google Scholar

[20] Moreno-Piraján, J., G. Rigoberto, and G. Liliana, Removal of Mn, Fe, Ni and Cu Ions from Wastewater Using Cow Bone Charcoal. Materials, 2010. 3: pp.452-466.

DOI: 10.3390/ma3010452

Google Scholar

[21] Taba, P., P. Budi, and A. Y Puspitasari, Adsorption of heavy metals on amine-functionalized MCM-48. IOP Conf Ser: Mat Sci Eng, 2017. 188: pp.1-9.

DOI: 10.1088/1757-899x/188/1/012015

Google Scholar