Amorphous Porous Phase of Nitinol Generated by Ultrafast Isobaric Cooling

Article Preview

Abstract:

Titanium nickelide (nitinol) is of great applied interest in various industries due to unique combination of its physical and mechanical characteristics. In the present work, we consider the possibility of obtaining nitinol with mesoporous structure by rapidly cooling the molten sample to room temperature. Based on molecular dynamics simulation data, it was shown that the rapid cooling of the nitinol melt leads to formation of a porous structure. It was shown that the inner pore wall is formed mainly by titanium atoms, which provide biocompatibility of nitinol. It was found that the porosity of nitinol weakly depends on the cooling rate, while the porosity increases linearly with decreasing melt density.

You might also be interested in these eBooks

Info:

Periodical:

Solid State Phenomena (Volume 310)

Pages:

150-155

Citation:

Online since:

September 2020

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2020 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] S.A. Shabalovskaya, Surface, corrosion and biocompatibility aspects of Nitinol as an implant material. Bio-Medical Materials and Engineering. 12 (2002) 69-109.

Google Scholar

[2] C. Wen, Metallic Foam Bone: Processing, Modification and Characterization and Properties, Woodhead Publishing, (2016).

Google Scholar

[3] P.S. Liu, G.F. Chen, Porous Materials Processing and Applications. 1st ed. Elsevier Ltd., Oxford, UK, (2014).

Google Scholar

[4] M.H. Elahinia, M. Hashemi, M. Tabesh, S.B. Bhaduri, Manufacturing and processing of NiTi implants: A review. Progress in Materials Science. 57 (2012) 911-946.

DOI: 10.1016/j.pmatsci.2011.11.001

Google Scholar

[5] D. Kapoor, Nitinol for Medical Applications: A Brief Introduction to the Properties and Processing of Nickel Titanium Shape Memory Alloys and their Use in Stents. Johnson Matthey Technol. Rev. 61 (2017) 66-76.

DOI: 10.1595/205651317x694524

Google Scholar

[6] T.J. Jeon, T.W. Hwang, H.J. Yun, C.J. VanTyne and Y.H. Moon, Control of Porosity in Parts Produced by a Direct Laser Melting Process. Appl. Sci. 8 (2018) 2573(1)-2573(16).

DOI: 10.3390/app8122573

Google Scholar

[7] J.C. Chekotu, R. Groarke, K. O'Toole, D. Brabazon, Advances in Selective Laser Melting of Nitinol Shape Memory Alloy Part Production. Materials. 12 (2019) 809(1)-809(20).

DOI: 10.3390/ma12050809

Google Scholar

[8] R.M. Khusnutdinoff, A.V. Mokshin, Electrocrystallization of supercooled water confined by graphene walls, J. Cryst. Growth. 524 (2019) 125182(1)- 125182(4).

DOI: 10.1016/j.jcrysgro.2019.125182

Google Scholar

[9] R.M. Khusnutdinoff, A.V. Mokshin, Electrocrystallization of supercooled water confined between graphene layers, JETP Letters. 110 (2019) 557-561.

DOI: 10.1134/s0021364019200050

Google Scholar

[10] J.M. Rodriques-Parra, R. Moreno, M.I. Nieto, Effect of cooling rate on the microstructure and porosity of alumina produced by freeze casting, J. Serb. Chem. Soc. 77 (2012) 1775-1785.

DOI: 10.2298/jsc121018132r

Google Scholar

[11] W.-S. Ko, B. Grabowski and J. Neugebauer, Development and application of a Ni-Ti interatomic potential with high predictive accuracy of the martensitic phase transition, Phys. Rev. B 92 (2015) 134107 1-22.

DOI: 10.1103/physrevb.92.134107

Google Scholar

[12] C. Braga, K.P. Travis, A configurational temperature Nose-Hoover thermostat. J. Chem. Phys. 123 (2005) 134101(1)-134101(15).

DOI: 10.1063/1.2013227

Google Scholar

[13] F.A.L. Dullien, Porous Media. Fluid Transport and Pore Structure, Academic Press, (1992).

Google Scholar

[14] L. Zhong, J. Wang, H. Sheng, Z. Zhang, and S.X. Mao, Formation of monatomic metallic glasses through ultrafast liquid quenching, Nature 512 (2014) 177-180.

DOI: 10.1038/nature13617

Google Scholar

[15] A.V. Mokshin, B.N. Galimzyanov, D.T. Yarullin, Scaling relations for temperature dependences of the surface self-diffusion coefficient in crystallized molecular glasses, JETP Letters. 110 (2019) 511-516.

DOI: 10.1134/s002136401919010x

Google Scholar

[16] B.N. Galimzyanov, V.I. Ladyanov, A.V. Mokshin, Remarkable nuances of crystallization: from ordinary crystal nucleation to rival mechanisms of crystallite coalescence. J. Cryst. Growth. 526 (2019) 125214(1)-125214(4).

DOI: 10.1016/j.jcrysgro.2019.125214

Google Scholar

[17] Y. Li, C. Yang, H. Zhao, S. Qu, X. Li, Y. Li, New Developments of Ti-Based Alloys for Biomedical Applications. Materials. 7 (2014) 1709-1800.

DOI: 10.3390/ma7031709

Google Scholar

[18] K. Prasad, O. Bazaka, M. Chua, M. Rochford, L. Fedrick, J. Spoor, R. Symes, M. Tieppo, C. Collins, A. Cao, D. Markwell, K. Ostrikov, K. Bazaka, Metallic Biomaterials: Current Challenges and Opportunities. Materials. 10 (2017) 884(1)-884(33).

DOI: 10.3390/ma10080884

Google Scholar

[19] I.V. Shishkovsky, M.V. Kuznetsov, Yu.G. Morozov, Porous Titanium and Nitinol Implants Synthesized by SHS/SLS: Microstructural and Histomorphological Analyses of Tissue Reactions. International Journal of Self-Propagating High-Temperature Synthesis. 19 (2010) 157-167.

DOI: 10.3103/s1061386210020123

Google Scholar