Influence of Nano-Modification on Structural, Mechanical and Physico-Chemical Characteristics of Bentonite

Article Preview

Abstract:

The paper studies the influence of nanodispersed aluminum and silicon oxides on the structural, physico-chemical and mechanical characteristics of calcium-magnesium bentonite deposits of the Republic of Tatarstan, in order to determine the optimal concentrations of the nanomodifier, and to improve the performance of respective materials. It was found that nanomodification of bentonite increases the strength of samples after firing by more than 1,5 times, the adsorption index by 20–25 %. The optimal concentration of nanoparticles was determined by changing the properties. The methods of Brunauer-Emmett-Teller (BET), x-ray phase analysis and infrared spectroscopy show an increase in the specific surface area, a change in the phase composition of the annealed samples, the intensity and position of the characteristic absorption bands, as well as the chemical bond silicon-oxygen in bentonite, modified by nanoparticles of aluminum and silicon oxides of similar nature.

You might also be interested in these eBooks

Info:

Periodical:

Solid State Phenomena (Volume 316)

Pages:

34-39

Citation:

Online since:

April 2021

Authors:

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2021 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] F. Bergaya, B.K.G. Theng, G. Lagaly, Handbook of Clay Science, Elsevier Science, Amsterdam, (2006).

Google Scholar

[2] V.M. Goldberg, N.P. Skvortsov, Permeability and filtration in clays, Nedra, Moscow, (1986).

Google Scholar

[3] J. Wei, R. Zhu, J. Zhu et al, Simultaneous sorption of crystal violet and 2-naphthol to bentonite with different CECs, J. of Hazard. Mat. 166 (2009) 195–199.

DOI: 10.1016/j.jhazmat.2008.11.004

Google Scholar

[4] V.V. Krupskaya, S.V. Zakusina, E.A. Tyurina et al, Transformation of the structure and adsorption properties of montmorillonite under thermochemical action, Geochemistry. 64 (2019) 300–319.

Google Scholar

[5] A.A. Sabitov, Deposits of bentonites of the Republic of Tatarstan: Geology and Genesis, directions of use of raw materials, Georesursy. 1 (2015) 38–43.

DOI: 10.18599/grs.63.4.6

Google Scholar

[6] I.V. Dobrynin, Mechanical alloying methods in the field of efficient production of bentonite powders for drilling, Oil. Gas. Innovations 10 (2009) 23–28.

Google Scholar

[7] D. Manikandan, R.V. Mangalaraja, S. Ananthakumar, T. Sivakumar, Synthesis of metal intercalated clay catalysts for selective hydrogenation reactions, Catalysis in Industry. 4 (2012) 215–230.

DOI: 10.1134/s2070050412040125

Google Scholar

[8] S. Morfis, C. Philippopoulos, N. Papayannakos, Application of Al-pillared clay minerals as catalytic carriers for the reaction of NO with CO, Appl. Clay Sci. 13 (1998) 203–212.

DOI: 10.1016/s0169-1317(98)00022-2

Google Scholar

[9] M.N. Timofeeva, V.N. Panchenko, V.V. Krupskayaet al, Effect of nitric acid modification of montmorillonite clay on synthesis of sotketal from glycerol and acetone, Catal. Commun. 90 (2017) 65–69.

DOI: 10.1016/j.catcom.2016.11.020

Google Scholar

[10] M. Eloussaief, M. Benzina, Efficiency of natural and acid-activated clays in the removal of Pb(II) from aqueous solutions, J. of Hazard. Mat. 178 (2010) 753–757.

DOI: 10.1016/j.jhazmat.2010.02.004

Google Scholar

[11] A.M. Akimbaeva, E.E. Ergozhin, Estimation of structural and sorption characteristics of activated bentonite, Colloid J. 69 (2007) 437–443.

DOI: 10.1134/s1061933x07040011

Google Scholar

[12] Р. Komadel, Chemically modified smectites, Clay Miner. 38 (2003) 127–138.

DOI: 10.1180/0009855033810083

Google Scholar

[13] Р. Komadel, Acid activated clays: Materials in continuous demand, Appl. Clay Sci. 131 (2016) 84–99.

DOI: 10.1016/j.clay.2016.05.001

Google Scholar

[14] I.A. Zhenzhurist, A.E. Buntin, Influence of additives of hydrosols of oxides of aluminum and silicon on properties of molding mixture, Foundry production. 8 (2011) 36–40.

Google Scholar

[15] A.E. Buntin, I.A. Zhenzhurist, O.S. Sirotkin, R.H. Khuziakhmetov, Technology of modification of natural aluminosilicates by nanosols of aluminum and silicon oxides,Herald of Technological University. 21 (2018) 66–70.

Google Scholar

[16] O.S. Sirotkin, R.O. Sirotkin, A.M. Trubacheva, On the necessity and procedure of taking into account the metallic component of a heteronuclear bond, Russ. J. Inorg. Chem. 50 (2005) 67–71.

Google Scholar

[17] O.S. Sirotkin, R.O. Sirotkin, Chemistry (Fundamentals of unified chemistry), KNORUS, Moscow, (2017).

Google Scholar

[18] V.V. Tarasov, Problems of physics of glass, Stroizdat, Moscow, (1979).

Google Scholar

[19] N.A. Medvedeva, O.S. Sitewe, V.V. Seredin, Sorption capacity of clays subjected to compression, Heraldof PNRPU. 18 (2018) 118–128.

Google Scholar

[20] P. Larkin, Infrared and raman spectroscopy: principles and spectral interpretation, Elsevier, (2011).

Google Scholar