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HomeSolid State PhenomenaSolid State Phenomena Vol. 316Hydrogenation of Nitro Compounds over Catalytic...

Hydrogenation of Nitro Compounds over Catalytic Systems Containing Rare-Earth Oxides

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Abstract:

The paper studies the activity of 1 % palladium catalysts containing rare earth oxides (REOs) and alumina as a carrier in the hydrogenation of nitro compounds exemplified by nitrobenzene and o-nitro anisole. Under the liquid-phase hydrogenation conditions, these catalytic systems provide high selectivity of the process and a quantitative yield. It has been found that the partial replacement of Al₂O₃ with REO allows increasing the hydrogenation rate by 5–6 times, as compared with the reference catalyst and by 1.2–1.7 times as compared with the individual carrier. The oxide mixtures (REO and Al₂O₃) containing 20–40 % REO allow reaching the same hydrogenation rate with that over an REO-containing 1 % Pd catalyst.

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Materials Engineering and Technologies for Production and Processing VI

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Periodical:

Solid State Phenomena (Volume 316)

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684-688

DOI:

https://doi.org/10.4028/www.scientific.net/SSP.316.684

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Online since:

April 2021

Authors:

G. M. Kurunina*, O.M. Ivankina, Gennady M. Butov

Keywords:

Aromatic Nitro Compounds, Catalysis, Catalyst, Hydrogenation, Palladium, Rare Earth Oxides

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© 2021 Trans Tech Publications Ltd. All Rights Reserved

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