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HomeSolid State PhenomenaSolid State Phenomena Vol. 337Selective Copper Extraction from Spent Lithium-Ion...

Selective Copper Extraction from Spent Lithium-Ion Batteries

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Abstract:

This paper is dedicated to the investigation of selective copper extraction from the black mass of lithium-ion batteries (LIBs) using ammonium sulfate. Thermodynamic analysis performed with the use of Pourbaix diagrams allowed to compare and predict the area of stable copper and cobalt ammine complexes, determine operating pH range (8.7-9.7) for solutions. Concentrations of sodium hydroxide and ammonium sulfate were defined experimentally allowing to achieve high copper extraction (82-87 %) at low cobalt recovery into solutions (0.25-0.52 %). By variation of main leaching parameters optimal process conditions were determined: (NH₄)₂SO₄ 45 g/dm³, NaOH 9 g/dm³, 25 С, l : s = 5 : 1, 120 minutes.

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Solid State Technologies and Modern Production

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Periodical:

Solid State Phenomena (Volume 337)

Pages:

45-51

DOI:

https://doi.org/10.4028/p-0bcko6

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Online since:

October 2022

Authors:

Elvira B. Kolmachikhina*, Konstantin D. Naumov, Dana I. Bludova

Keywords:

Ammonium Leaching, Cobalt, Copper, Lithium-Ion Batteries

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© 2022 Trans Tech Publications Ltd. All Rights Reserved

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* - Corresponding Author

[1] J. Chen, Q. Li, J. Song, D. Song, L. Zhang, X. Shi, Environmentally friendly recycling and effective repairing of cathode powders from spent LiFePO4 batteries, Green Chem. 18(8) (2016) 2500-2506.

DOI: 10.1039/c5gc02650d

[2] Information on: https://evreporter.com/lithium-ion-battery-reuse-and-recycling/.

[3] M. R. Palacin, A. deGuibert, Why do batteries fail?, Science. 351 (2016) 1253292.

[4] X. Zhang, Y. Bian, S. Xu, E. Fan, Q. Xue, Y. Guan, F. Wu, L. Li, R. Chen, Innovative application of acid leaching to regenerate Li(Ni1/3Co1/3Mn1/3)O2 cathodes from spent lithium-ion batteries, ACS Sustain. Chem. Eng. 6 (2018) 5959-5968.

DOI: 10.1021/acssuschemeng.7b04373.s001

[5] R. Sattar, S. Ilyas, H. N. Bhatti, A. Ghaffar, Resource recovery of critically-rare metals by hydrometallurgical recycling of spent lithium ion batteries, Purif. Technol. 209 (2019) 725-733.

DOI: 10.1016/j.seppur.2018.09.019

[6] X. Chen, Y. Chen, T. Zhou, D. Liu, H. Hu, S. Fan, Hydrometallurgical recovery of metal values from sulfuric acid leaching liquor of spent lithium-ion batteries, Waste Management. 38 (2015) 349-356.

DOI: 10.1016/j.wasman.2014.12.023

[7] C. Peng, J. Hamuyuni, B.P. Wilson, M. Lundström, Selective reductive leaching of cobalt and lithium from industrially crushed waste Li-ion batteries in sulfuric acid system, Waste Management. 76 (2018) 582-590.

DOI: 10.1016/j.wasman.2018.02.052

[8] Y. Guo, F. Li, H. Zhu, G. Li, J. Huang, W. He, Leaching lithium from the anode electrode materials of spent lithium-ion batteries by hydrochloric acid (HCl), Waste Management. 51 (2016) 227-233.

DOI: 10.1016/j.wasman.2015.11.036

[9] K. Shuva, M. A. Hossaini, Dissolution kinetics of cathode of spent lithium ion battery in hydrochloric acid solutions, Journal of The Institution of Engineers (India): Series D: Metallurgical & Materials and Mining Engineering. 94(1) (2013) 13-16.

DOI: 10.1007/s40033-013-0018-0

[10] H. Chen, S. Gu, Y. Guo, X. Dai, L. Zeng, K. Wang, C. He, G. Dodbiba, Y. Wei, T. Fujita, Leaching of cathode materials from spent lithium-ion batteries by using a mixture of ascorbic acid and HNO3, Hydrometallurgy. 205 (2021) 105746.

DOI: 10.1016/j.hydromet.2021.105746

[11] Y.R. Fajaryanto, N.S. Annisaa, Acid leaching and kinetics study of cobalt recovery from spent lithium-ion batteries with nitric acid, E3S Web of Conferences, EDP Sciences. 67 (2018) 03025.

DOI: 10.1051/e3sconf/20186703025

[12] X. Chen, H. Ma, C. Luo, T. Zhou, Recovery of valuable metals from waste cathode materials of spent lithium-ion batteries using mild phosphoric acid, J. of Hazard. Mat. 326 (2017) 77-86.

DOI: 10.1016/j.jhazmat.2016.12.021

[13] Y. Fu, Y. He, H. Chen, C. Ye, Q. Lu, R. Li, W. Xie, J. Wang, Effective leaching and extraction of valuable metals from electrode material of spent lithium-ion batteries using mixed organic acids leachant, J. Ind. Eng. Chem. 79 (2019) 154-162.

DOI: 10.1016/j.jiec.2019.06.023

[14] P. Meshram, A. Mishra, R. Sahu, Environmental impact of spent lithium ion batteries and green recycling perspectives by organic acids: A review, Chemosphere. (2020) 125291.

DOI: 10.1016/j.chemosphere.2019.125291

[15] N. Vieceli, C.A. Nogueira, C. Guimaraes, M.C. Pereira, F.O. Durao, F. Margarido, Hydrometallurgical recycling of lithium-ion batteries by reductive leaching with sodium metabisulphite, Waste Management. 71 (2018) 350-361.

DOI: 10.1016/j.wasman.2017.09.032

[16] G.P. Nayaka, Y. Zhang, P. Dong, D. Wang, K.V. Pai, J. Manjanna, G. Santhosh, J. Duan, Z. Zhou, J. Xiao, Effective and environmentally friendly recycling process designed for LiCoO2 cathode powders of spent Li-ion batteries using mixture of mild organic acids, Waste Management. 78 (2018) 51-57.

DOI: 10.1016/j.wasman.2018.05.030

[17] F. Meng, Q. Liu, R. Kim, J. Wang, G. Liu, A. Ghahreman, Selective recovery of valuable metals from industrial waste lithium-ion batteries using citric acid under reductive conditions: Leaching optimization and kinetic analysis, Hydrometallurgy. 191 (2020) 105160.

DOI: 10.1016/j.hydromet.2019.105160

[18] B. Musariri, G. Akdogan, C. Dorfling, S. Bradshaw, Evaluating organic acids as alternative leaching reagents for metal recovery from lithium ion batteries, Miner. Eng. 137 (2019) 108-117.

DOI: 10.1016/j.mineng.2019.03.027

[19] J.R. Almeida, M.N. Moura, R.V. Barrada, E.M.S, Barbieri, M.T.W.D. Carneiro, S.A.D. Ferreira, M.F.F. Lelis, M.B.J.G. Freitas, G.P. Brandão, Composition analysis of the cathode active material of spent Li- ion batteries leached in citric acid solution: a study to monitor and assist recycling processes, Sci. Total Environ. 685 (2019) 589-595.

DOI: 10.1016/j.scitotenv.2019.05.243

[20] R. Golmohammadzadeh, F. Faraji, F. Rashchi, Recovery of lithium and cobalt from spent lithium ion batteries (LIBs) using organic acids as leaching reagents: A review, Resour. Conserv. Recycl. 136 (2018) 418-435.

DOI: 10.1016/j.resconrec.2018.04.024

[21] R. Golmohammadzadeh, F. Rashchi, E. Vahidi, Recovery of lithium and cobalt from spent lithium-ion batteries using organic acids: Process optimization and kinetic aspects, Waste Management. 64 (2017) 244-254.

DOI: 10.1016/j.wasman.2017.03.037

[22] C. Wu, B. Li, C. Yuan, S. Ni, L. Li, Recycling valuable metals from spent lithium-ion batteries by ammonium sulfite-reduction ammonia leaching, Waste Management. 93 (2019) 153-161.

DOI: 10.1016/j.wasman.2019.04.039

[23] M. Tanaka, M. Tabata, Stability constants of Metal(II) complexes with amines and aminocarboxylates with special reference to chelation, Bulletin of the Chemical Society of Japan. 82 (2009) 1258-1265.

DOI: 10.1246/bcsj.82.1258