For Libraries For Publication Open Access Downloads About Us Contact Us
Paper Titles
Investigation of the Mechanical Properties of Urethane Dimethacrylate (UDMA) Reinforced with Abaca Cellulose for Vat Photopolymerization (VP)
p.35
TiO2- Polyurethane Cocopol Blend Nanocomposites as an Anticorrosion Coating for Mild Steel
p.43
Effect of Gadolinium Content on the Microstructures and Corrosion Properties of Mg-4Zn-3Gd Alloy
p.51
Corrosion Inhibitive Effects of Orange Juice for Brass in Acidic Medium 5M H2SO4
p.59
Investigation of the Adsorption Characteristics of Theobroma cacao Peels Biomass Inhibitors on Mild Steel Surfaces by EIS, SEM-EDX, XPS, and Chemical Studies in Acidic Media
p.69
Effects of Sn on Corrosion Resistance of Rare-Earth-Free Mg-2Zn Alloy
p.83
Mitigation of Erosion Wear Produced by Fly-Ash Slurry on 900 Elbow by Changing the Cross-Section Shape and Area Ratio
p.93
Integrated Phase Field and Machine Learning Study of Microstructure Evolution during Interface-Controlled Spinodal Decomposition
p.101
Exploring Sintering, Densification, and Mechanical Behaviour of Invar Alloys through Molecular Dynamics Simulations
p.107

Investigation of the Adsorption Characteristics of Theobroma cacao Peels Biomass Inhibitors on Mild Steel Surfaces by EIS, SEM-EDX, XPS, and Chemical Studies in Acidic Media

Article Preview

Abstract:

Investigators used Potentiodynamic Polarization, Spectroscopy of Electrochemical Impedance (EIS), Scanning Electron Microscope-Energy Dispersive X-Ray (SEM-EDX), Spectroscopy of X-Ray Photoelectron (XPS), and chemical studies to examine the inhibitory effect of Theobroma cacao peel extract (TCPE) on mild steel (MS) corrosion in 1.5M HCl. Studies of electrochemical data indicate that, TCPE reduces MS corrosion through adsorption using a mixed inhibition mechanism. As the inhibitor concentration grows and temperatures lowers, TCPE becomes more protective. The adsorption of TCPE molecules on the MS surface is controlled by the Langmuir adsorption isotherm. To determine the correlation between the hampers effect and the structure of TCPE molecular, a number of chemical characteristics were computed.

You might also be interested in these eBooks
The 3rd International Conference on Advances in Materials Science (ICAMS) View Preview
Advanced Materials Research and Corrosion Protection View Preview

Info:

Periodical:

Solid State Phenomena (Volume 357)

Pages:

69-82

DOI:

https://doi.org/10.4028/p-qz0pLd

Citation:

Cite this paper

Online since:

June 2024

Authors:

Yuli Yetri*, Gunawarman Gunawarman, Rakiman Rakiman, Adri Yanti Rivai, Ichlas Nur

Keywords:

Adsorpsi, Adsorption, Chemical Studies, Molecules, Theobroma Cacao

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2024 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

References

[1] M. Faiz, A. Zahari, K. Awang, H. Hussin, Corrosion Inhibition on Mild Steel in 1 M HCl Solution by Cryptocarya nigra Extracts and three of its Constituents (alkaloids), RSC Adv., 10(11) (2020) 6547–6562

DOI: 10.1039/c9ra05654h

Google Scholar

[2] Chaitra, T. K., Mohana, K. N., Tandon, H. C., Evaluation of newly synthesized hydrazones as mild steel corrosion inhibitors by adsorption, electrochemical, quantum chemical and morphological studies. Arab Journal of Basic and Applied Sciences. 25(2) (2020) 45-55.

DOI: 10.1080/25765299.2018.1449347

Google Scholar

[3] Aejitha S, Kasthuri PK, Geethamani P., Comparative Study of Corrosion Inhibition of Commiphora caudata and Digera muricata for Mild Steel in 1 M HCl Solution, Asian Journal of Chemistry. 28(2) (2016) 307-311.

DOI: 10.14233/ajchem.2016.19283

Google Scholar

[4] Reham El-Bindary, A. M. El-Shamy, Medhat Elhadek, Ahmed Nassef, Statistical Analysis of the Inhibition of Carbon Steel Corrosion in 3.5 wt.% NaCl Solution Using Lawsonia Extract, Port-Said Engineering Research Journal. 25(1) (2021) 101-113.

DOI: 10.21608/pserj.2020.35020.1050

Google Scholar

[5] Mo, H.-Q. Luo, N.-B. Li, Plant Extracts as Green Corrosion Inhibitors for Steel in Sulphuric Acid, Chem. Pap., 70 (2016) 1131–1143.

DOI: 10.1515/chempap-2016-0055

Google Scholar

[6] Ji, G., Anjum, S., Sundaram, S., Prakash, R., Musaparadisica peel extract as green corrosion inhibitor for mild steel in HCl solution, Corrossion Science. 90 (2015) 107–117.

DOI: 10.1016/j.corsci.2014.10.002

Google Scholar

[7] Saxena, A., Prasad, D., Haldhar, R., Investigation of corrosion inhibition effect and adsorption activities of Cuscuta reflexa extract for mild steel in 0.5 M H2SO4, Bioelectrochemistry. 124 (2018) 156–164.

DOI: 10.1016/j.bioelechem.2018.07.006

Google Scholar

[8] A. Miralrio, A. Espinoza Vázquez, Plant Extracts as Green Corrosion Inhibitors for Different Metal Surfaces and Corrosive Media: A Review, Processes. 8 (2020) 942.

DOI: 10.3390/pr8080942

Google Scholar

[9] Anaei, Z., Ramezanzadeh, M., Bahlakeh, G., Ramezanzadeh, B., Use of Rosa canina fruit extract as a green corrosion inhibitor for mild steel in 1 M HCl solution: A complementary experimental, molecular dynamics and quantum mechanics investigation, J. Ind.Eng. Chem., 69 (2019) 18–31.

DOI: 10.1016/j.jiec.2018.09.013

Google Scholar

[10] Saxena, A., Prasad, D., Haldhar, R., Singh, G., Kumar, A., Use of Sida cordifolia extract as green corrosion inhibitor for mild steel in 05 M H2SO4, Journal Environment Chemistry Engineering. 6 (2018) 694–700.

DOI: 10.1016/j.jece.2017.12.064

Google Scholar

[11] Alvarez, P. E., Fiori-Bimbi, M. V., Neske, A., Brandán S. A., Gervasi, C. A., Rollinia occidentalis extract as green corrosion inhibitor for carbon steel in HCl solution, J. Ind. Eng. Chem., 58 (2018) 92–99.

DOI: 10.1016/j.jiec.2017.09.012

Google Scholar

[12] Bahlakeh, G., Ramezanzadeh, B., Dehghani, A., Ramezanzadeh, M., Novel cost-effective and highperformance green inhibitor based on aqueous Peganum harmala (Esfand) seed extract for mild steel corrosion in HCl solution: Detailed experimental and electronic/atomic level computational explorations, J. Mol. Liq., 283 (2019) 174–195.

DOI: 10.1016/j.molliq.2019.03.086

Google Scholar

[13] Idouhli, Y. Koumya, M. Khadiri, A. Aityoub, A. Abouelfida, A. Benyaich, Inhibitory Effect of Senecio anteuphorbium as Green Corrosion Inhibitor for S300 Steel, Int. J. Integrated Care 10(2) (2019) 133–143.

DOI: 10.1007/s40090-019-0179-2

Google Scholar

[14] Yuli Yetri, Emriadi, Novesar J., Gunawarman, Corrosion Inhibitor of Mild Steel By Polar Extract of Theobroma cacao Peels in Hydrochloric Acid Solution, Asian Journal of Chemistry. 27(3) (2015) 875-881.

DOI: 10.14233/ajchem.2015.17173

Google Scholar

[15] F. Zulkifli, 'Nora'aini Ali, M. Sukeri M. Yusof, M.I.N. Isa, Henna Leaves Extract as a Corrosion Inhibitor in Acrylic Resin Coating, Progress in Organic Coatings. 105 (2017) 310-319.

DOI: 10.1016/j.porgcoat.2017.01.017

Google Scholar

[16] Jiyaul Haque, Chandrabhan Verma, Vandana Srivastava, W.B. Wan Nik, Corrosion Inhibition of Mild Steel in 1M HCl Using Environmentally Benign Thevetia peruviana Flower Extracts, Sustainable Chemistry and Pharmacy. V19, 100354 (2021) 1-13.

DOI: 10.1016/j.scp.2020.100354

Google Scholar

[17] W.M.K.W.M. Ikhmal, M.F.M. Maria, W.A.W. Rafizah, W.N.W.M. Norsani, M.G.M. Sabri, Corrosion Inhibition of Mild Steel in Seawater Through Green Approach Using Leucaena leucocephala Leaves Extract, International Journal of Corrosion and Scale Inhibition. 8(3) (2019) 628-643.

DOI: 10.17675/2305-6894-2019-8-3-12

Google Scholar

[18] Nishant Bhardwaj, Pooja Sharma, Vineet Kuma, Triticum aestivum Extract as Corrosion Inhibitor for Stainless Steel (SS-410) in Acidic Media: Experimental and Theoretical Study, Current Research in Green and Sustainable Chemistry. 4 (2021) 100189

DOI: 10.1016/j.crgsc.2021.100189

Google Scholar

[19] Haldhar, R., Prasad, D., Bhardwaj, N., Extraction and Experimental Studies of Citrus aurantifolia as an Economical and Green Corrosion Inhibitor for Mild Steel in Acidic Media. Journal of Adhesion Science and Technology. 33(11) (2019) 1169-1183.

DOI: 10.1080/01694243.2019.1585030

Google Scholar

[20] K.K. Alaneme, S.J. Olusegun, O.T. Adelowo, Corrosion Inhibition and Adsorption Mechanism Studies of Hunteria umbellata Seed Husk Extracts on Mild Steel Immersed in Acidic Solutions, Alexandria Engineering Journal. 55 (1) (2016) 673-681.

DOI: 10.1016/j.aej.2015.10.009

Google Scholar

[21] B. Hafez, M. Mokhtarі, H. Elmsellem, H. Steli, Environmentally Friendly Inhibitor of The Corrosion of mild Steel: Commercial oil of Eucalyptus, Int. J. Corros. Scale Inhib., 8(3) (2019) 573-585.

DOI: 10.17675/2305-6894-2019-8-3-8

Google Scholar

[22] Yuli Yetri, Sukatik, Green Inhibitor for Mild Steel in Acidic Solution by Using Crude Extract and Polar Extract of Theobroma cacao Peels, Oriental Journal of Chemistry. 33(4) (2017) 2071-2079.

DOI: 10.13005/ojc/330456

Google Scholar

[23] Okuda T., H. Ito, Tannin of Constant Structure in Medical and Food Plant, Hydrolyzable Tannins and Polyphenol Related to Tannins, Journal of Moleculer Structure. 16 (2011) 2191-2217.

DOI: 10.3390/molecules16032191

Google Scholar

[24] Hii C.L., Law, S., Suzannah, Misnawi, M. Cloke1, Polyphenols in Cocoa (Theobroma cacao L), Asian Journal of Food Agriculture Industry. 2(4) (2009) 702-722.

Google Scholar

[25] Yuli Yetri, Emriadi, Novesar Jamarun, Gunawarman, Inhibitory Action of Theobroma cacao Peels Extract on Corrosion of Mild Steel in Different Media, Rasayan Journal of Chemistry. 9(4) (2016) 716-727.

DOI: 10.5772/intechopen.73263

Google Scholar

[26] Nurry Putri Tissos, Dahyunir Dahlan, Yuli Yetri, Synthesis of Cuprum (Cu) Layer by Electrodeposition Method with Theobroma cacao Peels as Corrosion Protectector of Steel, International Journal on Advanced Science Engineering Information Technology (IJASEIT). 8(4) (2018) 1290-1295.

DOI: 10.18517/ijaseit.8.4.4104

Google Scholar

[27] Yuli Yetri , R. Hidayati, R. Sumiati, N. P. Tissos, Adsorption Corrosion Inhibitive Behavior of Peels Extract of Theobroma cacao on Mild Steel as a Corrosion Inhibitor in HCl Media, Rasayan Journal of Chemistry. 13(1) (2020) 405-416.

DOI: 10.31788/rjc.2020.1315550

Google Scholar

[28] Satapathy A.K, G. Gunasekaran, S.C. Sahoo, Kumar Amit, P.W. Rodrigues, Corrosion Inhibition by Justicia gendarussa Plant Extract in Hydrochloric Acid Solution, Corrosion Science. 51(12) (2009) 2848-2856.

DOI: 10.1016/j.corsci.2009.08.016

Google Scholar

[29] Vatshala, MK. Pawethra, K.O Nayana, TV. Vermetesha, Synergetic Effect of Halide Ions on Improving Corrosion Inhibitor Behavior of benzi so thio zole-3–piperizim hydrochloride on Mild Steel in 0.5M H2SO4 Medium, Corrosion Science. 32(11) (2010) 3811-3819.

DOI: 10.1016/j.corsci.2010.07.034

Google Scholar

[30] Znini M, G. Cristofari, L. Majidi, A. Ansari, A. Bauyanzer, J. Paolini, J.Costa, B. Hammouti, 2012, Green Approach to Corrosion Inhibition of Mild Steel by Essential Oil Leaves of Astericus Graveolus (Forsk.) in Sulphuric Acid Medium, Corrosion Science. 7 (2012) 3959-3981.

DOI: 10.1016/s1452-3981(23)19513-7

Google Scholar

[31] Mashuga, M.E., Olasunkanmi, L.O., Adekunle, A.S., Yesudass, S., Kabanda, M.M., Ebenso, E.E., Adsorption, Thermodynamics and Quantum Chemical Studies of 1-hexyl-3-methylimidazolium Based Ionic Liquids as Corrosion Inhibitors for Mild Steel in HCl. Materials. 8 (2015) 3607–3632.

DOI: 10.3390/ma8063607

Google Scholar

[32] Mohanty. U. S., K.L Lin, Potentiodynamic Polarization Measurement of Sn–8.5Zn–XAl–0.5Ga Alloy in 3.5% NaCl Solution, Journal of Electrochemical Science. 153(8) (2006) B319-B324.

DOI: 10.1149/1.2209569

Google Scholar

[33] O.S. Yadav, S. Kumar, G. Kaur, G. Singh, Synthesis, Characterization and Investigation of Schiff Base as a Corrosion Inhibitor for Mild Steel in HCl Medium, Heterolett. 4 (2014) 287– 293.

Google Scholar

[34] Vishnu Devan. M., Mitigation of Mild steel Corrosion in Acidic Solution Using Inhibitor, E-Journal of Chemistry. 8(1) (2011) 53-60.

Google Scholar

[35] Ostovari A, Hoseinieh S.M, Peikari, M, Shadizadeh, S.R, Hashemi S.J., Corrosion Inhibitor of Mild Steel in 1 M HCl Solution by Henna Extract: A Comparative Study of Inhibition by Henna and Its Constituents (Lawsone, Gallic acid, Glucose and Tannic Acid). Corrosion Science. 51 (2009) 1935-1949.

DOI: 10.1016/j.corsci.2009.05.024

Google Scholar

[36] Cang H, Fei Z, Shao J, Shi W., Xu Q., Corrosion Inhibition of Mild Steel by Aloes Extract in HCl Solution Medium, International Journal Electrochemical Science. 8 (2013) 720-743.

DOI: 10.1016/s1452-3981(23)14053-3

Google Scholar

[37] Perez, Nestor, Electrochemistry and Corrosion Science, Boston, Kluwe Academic Publisher. 2004 124-160.

Google Scholar

[38] Gerengi H., Halil Ibrahim Sahin, Shinopsis lorentzii Extract as a Green Corrosion Inhibitor for low Carbon Steel in 1 M HCl Solution, Industrial Engineering Chemical Research. 51 (2011) 780-787.

DOI: 10.1021/ie201776q

Google Scholar

[39] Guo L, Qi C, Zheng X, Zhang R, Shen X, Kaya S., Toward Understanding the Adsorption Mechanism of Large Size Organic Corrosion Inhibitors on an Fe (110) Surface Using the DFTB method. RSC Advances. 7(46) (2017) 29042-29050.

DOI: 10.1039/c7ra04120a

Google Scholar

[40] Lebrini M. Robert, F. Ross C., Alkoloids Extract from Palicourea guianensis Plant as Corrosion of C38 Steel in 1 M Hydrochloric Acid Medium, International Journal of Electrochemical Science. 6 (2011) 5357-5371.

DOI: 10.1016/s1452-3981(23)15039-5

Google Scholar

[41] Khan G., Basirun WJ., Kazi SN., Ahmed P., Magaji L., Ahmed SM., Electrochemical Investigation on The Corrosion Inhibition of Mild Steel by Quinazoline Schiff Base Compounds in Hydrochloric Acid Solution. Journal of Colloid and Interface Science. 502 (2017) 134-145.

DOI: 10.1016/j.jcis.2017.04.061

Google Scholar

[42] De Souza F.S., Reinaldo S., Goncalves, Almir Spinelli, Assessment of Caffeine Adsorption onto Mild Steel Surfaces as an Eco-Friendly Corrosion Inhibitor, Journal Brazil Chemistry Society. 25(1) (2014) 81-90.

DOI: 10.5935/0103-5053.20130270

Google Scholar

[43] Raja, P.B., Fadaeinasab, M., Qureshi, A.K., Rahim, A.A., Osman, H., Litaudon, M., Awang, K., Evaluation of Green Corrosion Inhibition by Alkaloid Extracts of Ochrosia oppositifolia and Isoreserpiline Against Mild Steel in 1 M HCl Medium. Ind. Eng. Chem. Res. 52 (2013) 10582–10593.

DOI: 10.1021/ie401387s

Google Scholar

[44] Cruz J., Martinez R., Genesca J., Garc J., Experimental and Theorical Study of 1-(2-ethylamino)-2-methylimidazoline as an Inhibitor of Carbon Steel in Acid Media, Journal Electroanalytical Chemistry. 566 (2011) 111-121.

DOI: 10.1016/j.jelechem.2003.11.018

Google Scholar

[45] Nahle A., Abu-Abdoun I., Abdel-Rahman I., Al-Khayat M., UAE Neem Extract as Corrosion Inhibitor for Carbon Steel in HCl Solution, International Journal of Corrosion. 10 (2010) 1-9.

DOI: 10.1155/2010/460154

Google Scholar

[46] Dang Nam N, Motilal Mathesh, Bruce Hinton, Mike J.Y. Tan, Rare Earth 4-Hydrocin namate Compounds as Carbon Dioxide Corrosion Inhibitors for Steel in Sodium Chloride Solution, Journal of Electrochemical Science. 161(12) (2014) C527-C534.

DOI: 10.1149/2.0231412jes

Google Scholar

[47] P. Udhayakala, T.V. Rajendiran, S. Gunasekaran, A theoretical Study of Some Barbiturates as Corrosion Inhibitors for Mild Steel, J. Chem. Pharm. Res. 6 (2014) 1027– 1039.

Google Scholar

© 2025 Trans Tech Publications Ltd. All rights are reserved, including those for text and data mining, AI training, and similar technologies. For open access content, terms of the Creative Commons licensing CC-BY are applied.
Scientific.Net is a registered trademark of Trans Tech Publications Ltd.