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Online since: February 2013
Authors: Ye Xin Chen, Hai Yan Qian, Tao Chen
Intermatallics compound Ni3Fe has L12 crystal structure.
The Ni3Fe alloy has a disordered structure above the critical temperature Tc and an ordered structure below Tc.
It was suggested that alloy stoichiometry strongly influences grain-boundary chemistry which in turn, affects the grain-boundary cohesion [10].
Therefore, we can deduct that the structure defect—vacancy is formed in rich Fe alloy and anti-site defect is formed in rich Ni alloy.
George, Effect of boron on the fracture behavior and grain boundary chemistry of Ni3Fe, Scripta Mater. 64 (2011) 303-306
The Ni3Fe alloy has a disordered structure above the critical temperature Tc and an ordered structure below Tc.
It was suggested that alloy stoichiometry strongly influences grain-boundary chemistry which in turn, affects the grain-boundary cohesion [10].
Therefore, we can deduct that the structure defect—vacancy is formed in rich Fe alloy and anti-site defect is formed in rich Ni alloy.
George, Effect of boron on the fracture behavior and grain boundary chemistry of Ni3Fe, Scripta Mater. 64 (2011) 303-306
Online since: March 2017
Authors: Ibrahim Siti Aida, Muhamad Nazim Ahmid
Results and Discussion
The XRD analysis was used in order to investigate the phase structure of TiO2 and Fe-TiO2 nanoparticles.
This suggests that some pertubation takes place in the anatase structure after the introduction of Fe (III) ions [11].
Hoffmann, Effects of Single Metal-Ion Doping on the Visible-Light Photoreactivity of TiO2, The Journal of Physical Chemistry C, 114 (2010) 783-792
Zhang, Preparation, photocatalytic performance and electronic structures of visible-light-driven Fe–N-codoped TiO2 nanoparticles, Mater.
Scherer, Sol-gel science: The physics and chemistry of sol-gel processing, Academic Press, New York, 1990
This suggests that some pertubation takes place in the anatase structure after the introduction of Fe (III) ions [11].
Hoffmann, Effects of Single Metal-Ion Doping on the Visible-Light Photoreactivity of TiO2, The Journal of Physical Chemistry C, 114 (2010) 783-792
Zhang, Preparation, photocatalytic performance and electronic structures of visible-light-driven Fe–N-codoped TiO2 nanoparticles, Mater.
Scherer, Sol-gel science: The physics and chemistry of sol-gel processing, Academic Press, New York, 1990
Online since: March 2020
Authors: Xian Zhi Ye
Most probe designs for small molecule molecular imaging typically begin with drugs that modify known structures.
This usually requires structure-activity relationships (SAR) to determine the optimal probe position.
MS analysis showed that residues Arg251 and Trp249 were labeled by probes, and from the crystal structure of MFE2.
Analytical Chemistry 2017, 89 (3), 1427-1432
Chemistry Letters 2012, 41 (7), 658-666
This usually requires structure-activity relationships (SAR) to determine the optimal probe position.
MS analysis showed that residues Arg251 and Trp249 were labeled by probes, and from the crystal structure of MFE2.
Analytical Chemistry 2017, 89 (3), 1427-1432
Chemistry Letters 2012, 41 (7), 658-666
Online since: September 2021
Authors: A.Kh. Salamov, Arsen Kharaev, Rima Bazheva, A.Z. Bazhev, Asker Kongapshev
Researches showed that the nature of a surface of composition depends on structure and on length of oligoester.
Particle size of the modifier depends on structure of composites and makes from 0.3-3 microns.
Development of research in the field of chemistry and technology of aromatic polysulfones // Plastics. 2003.
Block-copolysulfonarilates of Polycondensational Type // Modern Tendencies in Organic and Bioorganic Chemistry: Today and Tomorrow.
Molecular and topological structures in polyester block copolymers.
Particle size of the modifier depends on structure of composites and makes from 0.3-3 microns.
Development of research in the field of chemistry and technology of aromatic polysulfones // Plastics. 2003.
Block-copolysulfonarilates of Polycondensational Type // Modern Tendencies in Organic and Bioorganic Chemistry: Today and Tomorrow.
Molecular and topological structures in polyester block copolymers.
Online since: May 2020
Authors: R.I. Gulyaeva, E.N. Selivanov, K.V. Pikulin, L.I. Galkova
Using X-ray phase and X-ray structure microanalysis, it was established that the initial single crystal wolfram consists of Fe0.5Mn0.5WO4 and Fe0.3Mn0.7WO4.
Conducting the model experiments on sintering with the subsequent removal of water-soluble compounds (alkalization) made it possible to follow the change in the structure of wolframite.
A large amount of information on the process of tungsten-containing raw materials sintering with alkali metal carbonates is presented in the literature [5–9], but data on the kinetics and chemistry of the interaction in FexMn1–xWO4–Na(K)2CO3 mixtures during heating is very limited.
According to the results of thermal analysis, during the heating (20 °C/min) of initial wolframite to 1000 °C in the air flow, no transformations in the mineral structure were detected.
Encyclopedia of Industrial chemistry, H.U.
Conducting the model experiments on sintering with the subsequent removal of water-soluble compounds (alkalization) made it possible to follow the change in the structure of wolframite.
A large amount of information on the process of tungsten-containing raw materials sintering with alkali metal carbonates is presented in the literature [5–9], but data on the kinetics and chemistry of the interaction in FexMn1–xWO4–Na(K)2CO3 mixtures during heating is very limited.
According to the results of thermal analysis, during the heating (20 °C/min) of initial wolframite to 1000 °C in the air flow, no transformations in the mineral structure were detected.
Encyclopedia of Industrial chemistry, H.U.
Online since: June 2011
Authors: Dong Xu Li, Jing Lu, Dong Li Yu
Different kinds of silicon structures were found in the coatings.
As known, there exist many different structures of silicon, like cubic, tetragonal and hexagonal.
In the deposition experiments, different structures of silicon appeared by different deposition methods and conditions.
Following the experiments, two different structures [11-12] were selected for the coating original models.
Kaiser: Journal of Physics and Chemistry of Solids, Vol. 16 (1960), p.44 [12] H.
As known, there exist many different structures of silicon, like cubic, tetragonal and hexagonal.
In the deposition experiments, different structures of silicon appeared by different deposition methods and conditions.
Following the experiments, two different structures [11-12] were selected for the coating original models.
Kaiser: Journal of Physics and Chemistry of Solids, Vol. 16 (1960), p.44 [12] H.
Online since: August 2014
Authors: Xiu Feng Xiao, Hua Hong Wu, Shan Li, Guo Jie Xu
Pore structure HA microspheres with diameter of 2μm and uniform distribution can be obtained when the concentration of Rutin was 0.01wt%.
HA microspheres self-assemble by short rod, and the pore structure are formed by rods.
The structure of Rutin has plane double benzene ring similar to 17-β-E2 and DES.
HA nuclei priority growth along the c-surface into rod-like structure.
As a result, nucleation from the surface of the spherical micelle, and finally generate pore structure HA microspheres.
HA microspheres self-assemble by short rod, and the pore structure are formed by rods.
The structure of Rutin has plane double benzene ring similar to 17-β-E2 and DES.
HA nuclei priority growth along the c-surface into rod-like structure.
As a result, nucleation from the surface of the spherical micelle, and finally generate pore structure HA microspheres.
Online since: January 2010
Authors: M. Phiriyawirut, Natnapa Chotirat, Sirikul Phromsiri, Ingorn Lohapaisarn
The interconnected structure of
cellulose microfibril having a diameter of 27 nm was observed by TEM.
The properties of NR can be tailored by the addition of fillers of varying surface chemistry and aggregate size/aspect ratio to suit the application concerned.
In this work, as-prepared CMF, which is mainly nanosized fibrils with web-like structures, was used for preparing NR nanocomposite films.
The increasing in toughness of the composite film is the effect of long fibril characteristic and interconnected web-like structure of the CMF.
The CMF, prepared by acid hydrolysis of cellulose from banana peel, consisted of interconnected web-like structure with an average diameter around 27 nm.
The properties of NR can be tailored by the addition of fillers of varying surface chemistry and aggregate size/aspect ratio to suit the application concerned.
In this work, as-prepared CMF, which is mainly nanosized fibrils with web-like structures, was used for preparing NR nanocomposite films.
The increasing in toughness of the composite film is the effect of long fibril characteristic and interconnected web-like structure of the CMF.
The CMF, prepared by acid hydrolysis of cellulose from banana peel, consisted of interconnected web-like structure with an average diameter around 27 nm.
Online since: April 2013
Authors: Shu Ren Zhang, Bin Tang, Jian Liang, Zhe Liu, Wen Chen Hu
Various studies have shown that most X7R dielectric materials exhibit core-shell structures in the grains.
In addition to these additives, rare earth oxides doping into BaTiO3 ceramics could greatly change the microstructure, phase composition, density and properties of mechanics, physics, chemistry and sintering[11-16].
For chemical characteristics, there are the core-shell structure caused by non-uniform doping and homogeneous structure caused by uniform doping.
In the BT- Nb2O5-ZnO system, that Nb5+ diffuses difficultly in BT grains results in the appearance of the core-shell structure[25].
The type III REO(Nd, Ce and Pr) doping could destroy the original core-shell structure and form a new core-shell structure[29, 30], in which the shell region was decreased and the core region was increased, so the dielectric constant peak at 40ºC were depressed, the peak at 127ºC were raised.
In addition to these additives, rare earth oxides doping into BaTiO3 ceramics could greatly change the microstructure, phase composition, density and properties of mechanics, physics, chemistry and sintering[11-16].
For chemical characteristics, there are the core-shell structure caused by non-uniform doping and homogeneous structure caused by uniform doping.
In the BT- Nb2O5-ZnO system, that Nb5+ diffuses difficultly in BT grains results in the appearance of the core-shell structure[25].
The type III REO(Nd, Ce and Pr) doping could destroy the original core-shell structure and form a new core-shell structure[29, 30], in which the shell region was decreased and the core region was increased, so the dielectric constant peak at 40ºC were depressed, the peak at 127ºC were raised.
Online since: May 2022
Preface to “Engineered Materials for Sustainable Structures”
Roberto Frassine1, Andrea Nobili2, Giuseppe Saccomandi3,
Cesare Signorini2,4,a
1Department of Chemistry, Materials and Chemical Engineering ”Giulio Natta”, Politecnico di Milano, Piazza L.
In this collection of papers, we present the last advances in the field of sustainable materials and structures as they appear in the proceedings of the 2021 edition of the international workshop ”Engineering Materials for Sustainable Structures” (EM4SS’21) organised by the University of Modena and Reggio Emilia under the auspices of the Italian Industry Association for composite materials (Assocompositi).
The symposium gathered researchers alongside industrial partners active in the field of sustainable technologies and mechanics of complex materials and structures.
Again, long-term performance of novel construction materials plays a crucial role in determining resilience and reliability of modern structures.
Mechanics of Solids and Structures The Session reports on state-of-the-art and new concepts in the mechanics of solids and structures, includingmultiscaleandasymptoticmodels,homogenizationandinstability,nonlinearelasticity,wave propagation and reflection, plasticity, fracture mechanics.
In this collection of papers, we present the last advances in the field of sustainable materials and structures as they appear in the proceedings of the 2021 edition of the international workshop ”Engineering Materials for Sustainable Structures” (EM4SS’21) organised by the University of Modena and Reggio Emilia under the auspices of the Italian Industry Association for composite materials (Assocompositi).
The symposium gathered researchers alongside industrial partners active in the field of sustainable technologies and mechanics of complex materials and structures.
Again, long-term performance of novel construction materials plays a crucial role in determining resilience and reliability of modern structures.
Mechanics of Solids and Structures The Session reports on state-of-the-art and new concepts in the mechanics of solids and structures, includingmultiscaleandasymptoticmodels,homogenizationandinstability,nonlinearelasticity,wave propagation and reflection, plasticity, fracture mechanics.