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Online since: December 2012
Authors: M.N. Berhan, Nor Diyana Md Sin, Samsiah Ahmad, Mohamad Rusop
All films exhibit the (002) plane which correspond to hexagonal wurtzite structure with the highest peak at 150 Watt.
Fig. 2 (a) shows that the sphere particles did not form the nanocolumnar structure.
Fig. 2 (b) shows that the samples start to grow a nanocolumnar structure.
Fig. 2 (c) to Fig 2(e) show almost the same structures which are homogenous columnar structure, however with increasing Rms value.
Liu, and J.S.Yang:Materials Chemistry and Physics, vol. 72, pp. 269-272, 2001
Fig. 2 (a) shows that the sphere particles did not form the nanocolumnar structure.
Fig. 2 (b) shows that the samples start to grow a nanocolumnar structure.
Fig. 2 (c) to Fig 2(e) show almost the same structures which are homogenous columnar structure, however with increasing Rms value.
Liu, and J.S.Yang:Materials Chemistry and Physics, vol. 72, pp. 269-272, 2001
Online since: September 2018
Authors: Yurii F. Ivanov, Oleg S. Tolkachev, Pavel Moskvin, Olga V. Krysina, Elizaveta A. Petrikova, Olga V. Ivanova
Figure 5 shows a typical TEM image of the multilayer gradient structure identified in the material.
The transition layer has a polycrystalline structure formed by crystallites of size 150–700 nm.
TEM image of the Al surface structure after electron beam alloying with Ti.
Teer, Structure and mechanical properties of co-deposited TiAl thin films, Thin Solid Films 420-421 (2002) 386-391
Krysina, V.V.Denisov, Generation of low-temperature gas discharge plasma in large vacuum volumes for plasma chemical processes, Russian Journal of General Chemistry 85(5) (2015) 1326-1338, doi: 10.1134/S1070363215050485 [8] Yu.F.
The transition layer has a polycrystalline structure formed by crystallites of size 150–700 nm.
TEM image of the Al surface structure after electron beam alloying with Ti.
Teer, Structure and mechanical properties of co-deposited TiAl thin films, Thin Solid Films 420-421 (2002) 386-391
Krysina, V.V.Denisov, Generation of low-temperature gas discharge plasma in large vacuum volumes for plasma chemical processes, Russian Journal of General Chemistry 85(5) (2015) 1326-1338, doi: 10.1134/S1070363215050485 [8] Yu.F.
Online since: June 2010
Authors: Francesco Delogu
There exists a huge
number of unequivocally proven evidences in such direction in areas of science as different as heat
conduction, magnetism, plasticity and solution chemistry to name just a few [6-13].
For this reasons, the physics and chemistry of nanometer-sized systems are commonly regarded as a new subject of scientific investigation [6-13].
Such particular regime of motion originates a dynamical structure showing a relatively high degree of order on the short range, but no order in the long range.
What is the relationship between coordination number of surface species, surface free energy and surface structure?
Denier van der Gon, in: Chemistry and Physics of Solid Surfaces, Vol. 7, edited by R.
For this reasons, the physics and chemistry of nanometer-sized systems are commonly regarded as a new subject of scientific investigation [6-13].
Such particular regime of motion originates a dynamical structure showing a relatively high degree of order on the short range, but no order in the long range.
What is the relationship between coordination number of surface species, surface free energy and surface structure?
Denier van der Gon, in: Chemistry and Physics of Solid Surfaces, Vol. 7, edited by R.
Online since: September 2013
Authors: Yong Gang Wen, Qiu Xiong Chen, Yun Wen Chen, Shuan Shi Fan
Different ice-layer structure and internal structure on the surface of hydrates lead to different stability of itself.
Composition, structure and properties of frozen hydrate-containing soils.
Journal of Natural Gas Chemistry, 21: 91-97. (2012) [18] Yingmei Wang, Qingbai Wu, Peng Zhang, et al.
Physics and Chemistry of Ice.
Phyical Chemistry, 96: 8599-8603. (1992) [29] Davidson D, Garg S, Gough S, et al.
Composition, structure and properties of frozen hydrate-containing soils.
Journal of Natural Gas Chemistry, 21: 91-97. (2012) [18] Yingmei Wang, Qingbai Wu, Peng Zhang, et al.
Physics and Chemistry of Ice.
Phyical Chemistry, 96: 8599-8603. (1992) [29] Davidson D, Garg S, Gough S, et al.
Online since: September 2013
Authors: Xiu Cheng Zheng, Qiu Ying Huang, Bei Bei Dong
The results indicated that the as-prepared sample was in the keggin -type structure and the optimal parameters under the reaction conditions were as follows: 0.5 g of catalyst, reacted at 80 ◦C for 5 h.
The results indicated that the as-prepared sample was in the Keggin-type molecular structure of H3PW12O40 [6].
The SEM micrograph reveals that the HPW obtained was in the non-regular large bulk macro-structure (Fig. 2).
The bulk structure was responsible for the low surface area (1 m2/g). 31P NMR spectrum of as-prepared HPW displayed a characteristic peak at -14.75 ppm, which was consistent with that of H3PW12O40 reported in literature [7].
The results indicated that the prepared sample was in the keggin-type structure, and the optimal reaction parameters were as follows: 0.5 g of HPW, reacted at 80 ◦C for 5 h.
The results indicated that the as-prepared sample was in the Keggin-type molecular structure of H3PW12O40 [6].
The SEM micrograph reveals that the HPW obtained was in the non-regular large bulk macro-structure (Fig. 2).
The bulk structure was responsible for the low surface area (1 m2/g). 31P NMR spectrum of as-prepared HPW displayed a characteristic peak at -14.75 ppm, which was consistent with that of H3PW12O40 reported in literature [7].
The results indicated that the prepared sample was in the keggin-type structure, and the optimal reaction parameters were as follows: 0.5 g of HPW, reacted at 80 ◦C for 5 h.
Online since: April 2014
Authors: Ji Ping Liu, Zhuo Chen, Wei Zhao, Xian Dong, Ke Jia Liu
Thermal and flame retardant properties of MWNT reinforced conductive PAN film
Chen Zhuo1,a, Dong Xian2,a, Zhao Wei1,b, Liu Kejia2,b, Liu Jiping2,a, b*
aSchool of Chemistry and Material Science, Guizhou Normal University, Guiyang 550001, China
bMaterial Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
1,a email: chenzhuo@gznu.edu.cn
2,a e-mail: dongxiangood@163.com
1,be-mail: lkj890926@163.com
2,be-mail: beiou@bit.edu.cn
2a,b*e-mail:liujp@bit.edu.cn
Keywords: flame retardant, MWNT, PAN, conductive film
Abstract: Conductive polyacrylonitrile film reinforced by multiwall carbon nanotubes was prepared via ultrasonic dispersion and vacuum casting.
The structure of MWNT/PAN composite film was characterized by WAXD and FT-IR.
Fig. 2 WAXD patterns of MWNT , PAN, MWNT/PAN composites From Fig.2 it can be seen that the crystalline characteristic peak of PAN at 2θ=17° are maintained in all composites, which means that low content MWNT does not affect the packing structure of PAN.
It is observed that the rare MWNT phase dispersed as network structure embodying the enriched PAN phase.
The network structure of MWNT in PAN matrix should be responsible to flame retardant performance and high conductivity.
The structure of MWNT/PAN composite film was characterized by WAXD and FT-IR.
Fig. 2 WAXD patterns of MWNT , PAN, MWNT/PAN composites From Fig.2 it can be seen that the crystalline characteristic peak of PAN at 2θ=17° are maintained in all composites, which means that low content MWNT does not affect the packing structure of PAN.
It is observed that the rare MWNT phase dispersed as network structure embodying the enriched PAN phase.
The network structure of MWNT in PAN matrix should be responsible to flame retardant performance and high conductivity.
Online since: November 2012
Authors: Rong Wu, Ji Kang Jian, Jin Li, Dong Pan
XRD patterns show that the Gd-doped film maintains the hexagonal wurtzite structure with the (002) preferred c-axis orientation.
The quenching of UV emissions in AlN: Tm appears related to the thermal activation of the excitons bound to the RE structure isovalent charge trap.
The crystal structure of the product can be determined as hexagonal AlN and is in good agreement with that reported in ICDD-PDF65-0891, indicating a c-axis texture normal to the film plane.
Secondly, from the XRD patterns samples with different Gd concentration, only Gd concentration of 1.5% sample deposited on (111) shows clear AlN (002) peak, while other content doped samples are non-crystalline structure.
From the results, it was seen that the product shows hexagonal AlN crystal structure with Gd content of 1.5 at. %.
The quenching of UV emissions in AlN: Tm appears related to the thermal activation of the excitons bound to the RE structure isovalent charge trap.
The crystal structure of the product can be determined as hexagonal AlN and is in good agreement with that reported in ICDD-PDF65-0891, indicating a c-axis texture normal to the film plane.
Secondly, from the XRD patterns samples with different Gd concentration, only Gd concentration of 1.5% sample deposited on (111) shows clear AlN (002) peak, while other content doped samples are non-crystalline structure.
From the results, it was seen that the product shows hexagonal AlN crystal structure with Gd content of 1.5 at. %.
Online since: August 2007
Authors: De Liang Chen, Yoshiyuki Sugahara
Investigation of Factors Influencing the Formation of Tungstate-Based
Inorganic-Organic Hybrid Nanobelts/Nanotubes
Deliang Chen and Yoshiyuki Sugahara
Department of Applied Chemistry, School of Science and Engineering, Waseda University,
Shinjuku-ku, Tokyo 169-8555, Japan
ys6546@waseda.jp (Y.
Results and Discussion Typical Morphology and Structures.
It is clear that the filamentous structures are nanobelts, most of which are scrolled to make nanotubes with apparent diameters of 200−500 nm.
The high-resolution TEM image at point A of Fig. 1c is shown as Fig. 1d, which indicates that the nanobelt/nanotube has a lamellar structure along its length.
Its XRD pattern suggests that the interlayer distance of the lamellar structure is 2.59(1) nm.
Results and Discussion Typical Morphology and Structures.
It is clear that the filamentous structures are nanobelts, most of which are scrolled to make nanotubes with apparent diameters of 200−500 nm.
The high-resolution TEM image at point A of Fig. 1c is shown as Fig. 1d, which indicates that the nanobelt/nanotube has a lamellar structure along its length.
Its XRD pattern suggests that the interlayer distance of the lamellar structure is 2.59(1) nm.
Online since: August 2014
Authors: Eduardo Salas-Bañales, Antonio Campero, Fernando Rojas-González, Miguel A. García-Sánchez, R. Iris Y. Quiroz-Segoviano
García-Sánchez*
Department of Chemistry, Universidad Autónoma Metropolitana-Iztapalapa, Av.
Structures of porphin tetrapyrrolic macrocycles.
Dolphin, The Porphyrins, Physical Chemistry, Part A and B; Academic Press: New York, NY, USA, 1979
Livage, Chimie Douce: From Shake-and-bake Processing to Wet Chemistry, New J.
The Structure of the Porphine Ring System.
Structures of porphin tetrapyrrolic macrocycles.
Dolphin, The Porphyrins, Physical Chemistry, Part A and B; Academic Press: New York, NY, USA, 1979
Livage, Chimie Douce: From Shake-and-bake Processing to Wet Chemistry, New J.
The Structure of the Porphine Ring System.
Online since: November 2020
Authors: Nikolay Yu. Pankratov, Alexey Karpenkov, Galina Aleksandrovna Politova, Alexey Filimonov, Denis Dankin, Vladimir V. Popov, Maksim Ganin, Tatiana Kaminskaya
Figure 3 shows the structure of the surface area of Sm0.5Gd0.5Fe2 and Sm0.5Tb0.5Fe2 alloys and their domain structure in the same place.
In general, the domain structure of the samples can be characterized as irregular.
Clark, Magnetostrictive RFe2 intermetallic compounds, in Handbook on the Physics and Chemistry of Rare Earths, vol. 2, Gschneidner K A and Eyring L, Eds.
Gao et al., Structure and Phase Transformation in the Giant Magnetostriction Laves-Phase SmFe2, Inorganic Chemistry. 57(2) (2018) 689-694
Viryus, The Influence of Hydrogenation on the Structure, Magnetic and Magnetocaloric Properties of Tb–Dy–Co Alloys with a Laves Phase Structure, Physics of the Solid State. 61 (7) (2019) 1169-1175
In general, the domain structure of the samples can be characterized as irregular.
Clark, Magnetostrictive RFe2 intermetallic compounds, in Handbook on the Physics and Chemistry of Rare Earths, vol. 2, Gschneidner K A and Eyring L, Eds.
Gao et al., Structure and Phase Transformation in the Giant Magnetostriction Laves-Phase SmFe2, Inorganic Chemistry. 57(2) (2018) 689-694
Viryus, The Influence of Hydrogenation on the Structure, Magnetic and Magnetocaloric Properties of Tb–Dy–Co Alloys with a Laves Phase Structure, Physics of the Solid State. 61 (7) (2019) 1169-1175