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Online since: June 2014
Authors: Hui Duan Li
Synthesis, structure and characterization of a novel 3D zinc organophosphonate
LI Hui-duan 1, a *
1 Department of Chemistry and Life Science, Chuxiong Normal University, Chuxiong 675000, PR China
aemail: lhd08@cxtc.edu.cn
Keywords: [piperazine-1,4-diyldi(methylene)]bis(phosphonic acid); zinc organophosphonate; Solvothermal synthesis.
Notably, the structure of compound 1 featured one-dimensional channel in the [001] direction.
Synthesis, structure and characterization of 1 were reported in this paper.
Acknowledgements The authors acknowledge the financial support of the Natural Science Foundation of Yunnan province (Grant No. 2012FD050) and the State Key Laboratory of Inorganic Synthesis and Preparative Chemistry of Jilin University.
Structures and luminescent properties of lanthanide phosphonates[J].
Notably, the structure of compound 1 featured one-dimensional channel in the [001] direction.
Synthesis, structure and characterization of 1 were reported in this paper.
Acknowledgements The authors acknowledge the financial support of the Natural Science Foundation of Yunnan province (Grant No. 2012FD050) and the State Key Laboratory of Inorganic Synthesis and Preparative Chemistry of Jilin University.
Structures and luminescent properties of lanthanide phosphonates[J].
Online since: February 2014
Authors: Tao Lou, Xue Jun Wang, Kun Peng He, Zhen Yang
The decrease of copper binding coefficient was significantly correlated with the humic acid structure parameters (SUVA270 and E2/E3) during the photodegradation.
Correlation with structure parameters.
The decrease of copper binding coefficient was significantly correlated with the humic acid structure parameters (SUVA270 and E2/E3) during the photodegradation.
Peñuela, Photodegradation of the endocrine-disrupting chemicals 4n-nonylphenol and triclosan by simulated solar UV irradiation in aqueous solutions with Fe(III) and in the absence/presence of humic acids, Journal of Photochemistry and Photobiology A: Chemistry 251 (2013) 41-49
Mopper, Photochemical bleaching of oceanic dissolved organic matter and its effect on absorption spectral slope and fluorescence, Marine Chemistry 155 (2013) 81-91.
Correlation with structure parameters.
The decrease of copper binding coefficient was significantly correlated with the humic acid structure parameters (SUVA270 and E2/E3) during the photodegradation.
Peñuela, Photodegradation of the endocrine-disrupting chemicals 4n-nonylphenol and triclosan by simulated solar UV irradiation in aqueous solutions with Fe(III) and in the absence/presence of humic acids, Journal of Photochemistry and Photobiology A: Chemistry 251 (2013) 41-49
Mopper, Photochemical bleaching of oceanic dissolved organic matter and its effect on absorption spectral slope and fluorescence, Marine Chemistry 155 (2013) 81-91.
Online since: February 2015
Authors: Zi Ran Chen, You Hui Xu, Yong Hua Guan
To synthesize experimentally more superior derivatives of benzoxazinoids, we applied the theories of quantum chemistry to theoretical calculation for optimization of the structure of the experimentally synthesized BMIPBI, and obtained without experimental data the infrared spectrum, electronic absorption spectrum and thermodynamic properties, for the expectation of providing more information for researching the structure-activity relationship of such compounds.
Fig.1 Stable molecular structure of the BMIPBI Fig. 1 demonstrated that the molecule of BMIPBI was composed of isopropane and two side chains of 2, 4-dihydro-2H-3-(4-N-maleimade) phenyl-1, 3-benzoxazine.
Infrared spectrum of the BMIPBI molecule was obtained by frequency calculation on the basis of optimal structure, see Fig. 2.
Theoretic Study of 3-(4-N-Maleimido)-Phenyl-2, 4-dihydro-2H-1, 3-benzoxazineMolecular Structure, Spectrum and Thermodynamic Properties [J].
Physic Chemistry, Science Press, Beijing2008, 556–557.
Fig.1 Stable molecular structure of the BMIPBI Fig. 1 demonstrated that the molecule of BMIPBI was composed of isopropane and two side chains of 2, 4-dihydro-2H-3-(4-N-maleimade) phenyl-1, 3-benzoxazine.
Infrared spectrum of the BMIPBI molecule was obtained by frequency calculation on the basis of optimal structure, see Fig. 2.
Theoretic Study of 3-(4-N-Maleimido)-Phenyl-2, 4-dihydro-2H-1, 3-benzoxazineMolecular Structure, Spectrum and Thermodynamic Properties [J].
Physic Chemistry, Science Press, Beijing2008, 556–557.
Online since: July 2015
Authors: Wen Sheng Yu, Chun Song Zhu, Qian Li Ma, Wen Wen Ma, Jin Xian Wang, Xiang Ting Dong
The results indicate that LaOBr:Eu3+ luminescent nanofibers are tetragonal in structure with space group P4/nmm.
[2] P Hagenmuller, Inorganic solid fluorides-chemistry and physics, Academic Press, London, 1985
[3] J Holsa, E Sailynoja, P Ylha, P Porcher, P Deren, W Stek, Analysis of the crystal structure and optical spectra of stoichiometric SmOF, Journal of Physical Chemistry 100 (1996) 14736-14744
[5] J Yang, J Gong, H Fan, L Yang, The structure and luminescence characteristics of LaOBr:Tb3+(Dy3+), Journal of Materials Science 40 (2005) 3725-3728
[8] J Lee, Q W Zhang, F Saito, Mechanochemical synthesis of LaOX(X = Cl, Br) and their solid state solutions, Journal of Solid State Chemistry 160 (2001) 469-473
[2] P Hagenmuller, Inorganic solid fluorides-chemistry and physics, Academic Press, London, 1985
[3] J Holsa, E Sailynoja, P Ylha, P Porcher, P Deren, W Stek, Analysis of the crystal structure and optical spectra of stoichiometric SmOF, Journal of Physical Chemistry 100 (1996) 14736-14744
[5] J Yang, J Gong, H Fan, L Yang, The structure and luminescence characteristics of LaOBr:Tb3+(Dy3+), Journal of Materials Science 40 (2005) 3725-3728
[8] J Lee, Q W Zhang, F Saito, Mechanochemical synthesis of LaOX(X = Cl, Br) and their solid state solutions, Journal of Solid State Chemistry 160 (2001) 469-473
Online since: May 2017
Authors: Jantip Setthayanond, Potjanart Suwanruji, Supakit Achiwawanich, Thipchanok Bowornhathai, Sutasinee Kityakarn
SEM images illustrated highly ordered macroporous structure which was a characteristic for 3DOM materials.
The result suggested that its ordered porous structure is great advantage for photocatalysis.
The 3DOM TiO2 exhibited highly ordered porous structure with interconnected wall (Fig. 2B).
Even though its band gap energy was similar to that of NP TiO2, hierarchical macroporous structure of the 3DOM TiO2 may enhance photodegradation of MB.
Fourmentin: Journal of Photochemistry and Photobiology A: Chemistry Vol. 318 (2016), p. 142-149
The result suggested that its ordered porous structure is great advantage for photocatalysis.
The 3DOM TiO2 exhibited highly ordered porous structure with interconnected wall (Fig. 2B).
Even though its band gap energy was similar to that of NP TiO2, hierarchical macroporous structure of the 3DOM TiO2 may enhance photodegradation of MB.
Fourmentin: Journal of Photochemistry and Photobiology A: Chemistry Vol. 318 (2016), p. 142-149
Online since: April 2005
Authors: Alex Kabansky, Harry Lee
Experiment
Gate structure fabrication.
The W polymetal gate structure was fabricated on 200mm p-type wafers following SRAM process flow.
Being left on the structure these defects can be decorated by spacer nitride film and block the structure.
We think that this issue corresponds to a fundamental behavior of metals that trap Br and Cl atoms from etch chemistries.
Different plasma modes (direct, remote and their combination) and chemistries were explored.
The W polymetal gate structure was fabricated on 200mm p-type wafers following SRAM process flow.
Being left on the structure these defects can be decorated by spacer nitride film and block the structure.
We think that this issue corresponds to a fundamental behavior of metals that trap Br and Cl atoms from etch chemistries.
Different plasma modes (direct, remote and their combination) and chemistries were explored.
Online since: December 2010
Authors: Ping Chen Hsieh, Chang Jin Chen, Yaw Nan Shieh
The structure and morphology of these films were analyzed using XRD and SEM analysis.
X-ray diffraction results show that the film structures had only a single phase corresponding to SnO2 with the tetragonal rutile structure.
Materials Chemistry and Physics, 2006. 100: p. 275–280
Materials Chemistry and Physics, 1999. 61(1): p. 50-54
Materials Chemistry and Physics, 2000. 64(3): p. 184-188
X-ray diffraction results show that the film structures had only a single phase corresponding to SnO2 with the tetragonal rutile structure.
Materials Chemistry and Physics, 2006. 100: p. 275–280
Materials Chemistry and Physics, 1999. 61(1): p. 50-54
Materials Chemistry and Physics, 2000. 64(3): p. 184-188
Online since: June 2012
Authors: Yong Li Wang, Li Hua Wang, Zhan Zhong Hou, Yan Zhu Liu
Introduction
Complexes of Schiff bases with special structures are playing important roles in the development of catalysis, medicine and functional materials [1-5].
Tong: Chinese Journal of Analytical Chemistry, Vol.37 (2009) ,p.111“In Chinese” [7]F.L.
Zhang: Chinese Journal of Analytical Chemistry, 2003, Vol.31 (2003),p. 217“In Chinese” [9] B .Liu, G.
Yang: Chinese Journal of Oganic Chemistry, Vol.23(2003), p.1387“In Chinese” [16] H.Q.
Ding: Inorganic Chemistry, vol.45 (2006), p.5822
Tong: Chinese Journal of Analytical Chemistry, Vol.37 (2009) ,p.111“In Chinese” [7]F.L.
Zhang: Chinese Journal of Analytical Chemistry, 2003, Vol.31 (2003),p. 217“In Chinese” [9] B .Liu, G.
Yang: Chinese Journal of Oganic Chemistry, Vol.23(2003), p.1387“In Chinese” [16] H.Q.
Ding: Inorganic Chemistry, vol.45 (2006), p.5822
Online since: February 2011
Authors: Feng Jiu Li
In this article, to oolitic hematite ore, the chemistry dispersion research is conducted to provide the foundation for further selective flocculation separation.
Introduction Oolitic hematite can been found very easly in our counctry, which is known by people because of the oolitic structure, and its total account for 1/9 iron ore reserves.
The multi-layer structure is formed, which is from the center of oolitic particles to outward.
Sodium tripolyphosphate (STPP) is a multi-charge of a micelle structure of the electrolyte, which charge more than micellar absorption in the mineral grains on the surface to enhance the mineral grains on the surface of the potential negative.
Surface chemistry of a rheology relationships in concentrated mineral suspensions.
Introduction Oolitic hematite can been found very easly in our counctry, which is known by people because of the oolitic structure, and its total account for 1/9 iron ore reserves.
The multi-layer structure is formed, which is from the center of oolitic particles to outward.
Sodium tripolyphosphate (STPP) is a multi-charge of a micelle structure of the electrolyte, which charge more than micellar absorption in the mineral grains on the surface to enhance the mineral grains on the surface of the potential negative.
Surface chemistry of a rheology relationships in concentrated mineral suspensions.
Online since: March 2013
Authors: Qiang Li, Dan Yu Jiang, Hao Wu, Wu Chao Shi, Cheng Chen
Both PMN and PZT are perovskite oxides and typical functional materials applicable to various devices for its chemistry and physics properties.
Structure characterization.
X-ray diffraction (XRD) was performed to identify the crystal structure of the powders.
As can be seen from Figure 2, the powders which is a reunion structure of Nano-particles.
Kulkarni, Synthesis and Dielectric Properties of Lead Magnesium Niobate, a Review, Materials chemistry and physics. 39 (1994) 98–109
Structure characterization.
X-ray diffraction (XRD) was performed to identify the crystal structure of the powders.
As can be seen from Figure 2, the powders which is a reunion structure of Nano-particles.
Kulkarni, Synthesis and Dielectric Properties of Lead Magnesium Niobate, a Review, Materials chemistry and physics. 39 (1994) 98–109