Synthesis, Structure and Characterization of a Novel 3D Zinc Organophosphonate

Abstract:

A novel zinc organophosphonate was synthesized under solvothermal conditions by using [piperazine-1,4-diyldi (methylene)] bis (phosphonic acid) as a organic ligand. Single-crystal X-ray diffraction analysis reveals that compound 1 crystallized in the triclinic space group P-1 (No. 2). Compound 1 formulated as Zn (O₃PCH₂NHC₄H₈NHCH₂PO₃)·H₂O. Compound 1 featured a 3D open-framework. Notably, the structure of compound 1 featured one-dimensional channel in the [00 direction. Water molecules were located in these channels. Further characterizations of compound 1 have been performed, including X-ray powder diffraction, IR, ICP and CHN analyses.

• Periodical: Advanced Materials Research (Volume 936)
• Pages: 915-918
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.936.915
• Online since: June 2014
• Authors: Hui Duan Li*
• Keywords: [Piperazine-1,4-Diyldi(Methylene)]Bis(Phosphonic Acid), Solvothermal Synthesis, Zinc Organophosphonate

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