Construction of a Novel 3D Indium Phosphate–Phosphite with Extra-Large 16-MRs Channels: Synthesis, Structure and Fluorescence Property

Article Preview

Abstract:

A novel 3D anionic indium phosphatephosphite, formulated as |(C10H10N2)1.5(H3O)3|[In18(H2O)12(HPO4)12(HPO3)16(H2PO3)6] (1), was hydrothermally prepared by using 4, 4-bipyridine (4, 4-bipy) as a structure directing agent (SDA). Single-crystal X-ray diffraction analysis reveals that compound 1 crystallizes in the hexagonal system space group P63/m (No. 176) having unit cell parameters a = 13.7843(19) Å, b = 13.7843(19) Å, c = 28.058(6) Å, V = 4617.0(13) Å3. Compound 1 exhibits a unique pillar-layer open-framework constructed from InO6 octahedra, HPO3 pseudo-tetrahedra and HPO4 tetrahedra, resulting extra-large 16-MRs channels. Synthesis, crystal structure and fluorescence property for compound 1 were reported in this paper.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

901-904

Citation:

Online since:

June 2014

Authors:

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] R. Murugavel, A. Choudhury, M. G. Walawalkar, R. Pothiraja, C. N. R. Rao, Metal Complexes of Organophosphate Esters and Open-Framework Metal Phosphates: Synthesis, Structure, Transformations, and Applications, Chem. Rev. 108 (2008), 3549-3655.

DOI: 10.1021/cr000119q

Google Scholar

[2] J. Yu, R. Xu, Insight into the construction of open-framework aluminophosphates, Chem. Soc. Rev., 35 (2006) 593-604.

DOI: 10.1039/b505856m

Google Scholar

[3] C. N. R. Rao, S. Natarajan, A. Choudhury, S. Neeraj, A. A. Ayi, Aufbau Principle of Complex Open-Framework Structures of Metal Phosphates with Different Dimensionalities, Acc. Chem. Res., 34 (2001) 80-87.

DOI: 10.1021/ar000135+

Google Scholar

[4] A. K. Cheetham, G. Férey, T. Loiseau, Angew. Chem. Int. Ed., 38 (1999) 3268, and references therein.

Google Scholar

[5] D. Maspoch, D. Ruiz-Molina, J. Veciana, Chem. Soc. Rev., 36 (2007) 770, and references therein.

Google Scholar

[6] T. Rojo, J. L. Mesa, J. Lago, B. Bazan, J. L. Pizarro, M. I. Arriortua, Organically templated open-framework phosphites, J. Mater. Chem., 19 (2009) 3793-3818.

DOI: 10.1039/b808795b

Google Scholar

[7] S. Natarajan, S. Mandal, Open-Framework Structures of Transition-Metal Compounds, Angew. Chem. Int. Ed., 47 (2008) 4798-4828.

DOI: 10.1002/anie.200701404

Google Scholar

[8] L. Wang, T. Song, J. Xu, Y. Wang, Z. Tian. S. Shi, Synthesis and characterization of two new organically templated indium phosphites built from one-dimensional ladders, Micropor. Mesoporo. Mater., 96 (2006) 287-292.

DOI: 10.1016/j.micromeso.2006.07.008

Google Scholar

[9] L. Huang, T. Song, Y. Fan, L. Yang, L. Wang, H. Zhang, L. Wang, J. Xu, Hydrothermal syntheses, characterizations of novel three-dimensional indium phosphite and indium phosphite–phosphate with intersecting 8-membered ring channels: [In3(H2PO3)3(HPO3)4]·(trans-C6N2H16) and [In6(HPO3)8(H2PO3)5(H2PO4)]·(C3N2H12)2, Micropor. Mesoporo. Mater., 132 (2010).

DOI: 10.1016/j.micromeso.2010.03.020

Google Scholar

[10] Z. Dong, Y. Yan, Y. Li, J. Li, J. Yu, R. Xu, A new open-framework indium phosphate–phosphite containing intersecting extra-large 16-ring channels, Inorg. Chem. Commun., 14 (2011), 727–730.

DOI: 10.1016/j.inoche.2011.02.019

Google Scholar

[11] H. Li, L. Zhang, L. Liu, T. Jiang, Y. Yu, G. Li, Q. Huo, Y. Liu, Organic template-directed indium phosphite-oxalate hybrid material: Synthesis and characterization of a novel 3D |C6H14N2|[In2(HPO3)3(C2O4)] compound with intersecting channels, Inorg. Chem. Commun., 12 (2009).

DOI: 10.1016/j.inoche.2009.08.011

Google Scholar

[12] H. Li, L. Zhang, Q. Huo, Y. Liu, Construction of two novel indium phosphites with (3, 6)- and (3, 5)-connected frameworks: Synthesis, structure and characterization, J. Solid State Chem., 197 (2013) 75-80.

DOI: 10.1016/j.jssc.2012.09.017

Google Scholar

[13] G. M. Sheldrick, SHELXTL-NT, Version 5. 1, Bruker AXS Inc. Madison, WI, (1997).

Google Scholar