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Online since: May 2004
Authors: L. Malmusi, A. Tucci, Leonardo Esposito, E. Rastelli
Spodumene is a fluxing agent which reduces the
firing temperature and can be successful used to stabilise the suspension and to reduce the high
firing temperature necessary to obtain the characteristic compact structure of porcelain stoneware.
These phenomena of time-dependency are all due to the presence of a colloidal structure.
In fact, the silicate structure makes the Table 1.
system sterically large, with a lower degree of hydration, as compared to the zirconia structure.
Grimshaw: The chemistry and physics of clays and allied ceramic materials (Ernest Benn Limited Published, 1971) [7] W.E.
These phenomena of time-dependency are all due to the presence of a colloidal structure.
In fact, the silicate structure makes the Table 1.
system sterically large, with a lower degree of hydration, as compared to the zirconia structure.
Grimshaw: The chemistry and physics of clays and allied ceramic materials (Ernest Benn Limited Published, 1971) [7] W.E.
Online since: January 2015
Authors: Hai Tao Zhao, Qiao Wang, Rui Ping Liu, Kai Xin Yang
The morphology, structure and properties for the TiO2/PPy composite are also studied in this work.
Results and discussion Structure and morphology of the samples.
This unambiguously confirms the formation of a pure anatase structure(Fig.1a).
TiO2 is a pure anatase-type structure.
Yu, Preparation and characterization of visible-light-driven plasmonic photocatalyst Ag/AgCl/TiO2 nanocomposite thin films, Journal of photochemistry and Photobiology A: Chemistry. 223(2011) 82–87
Results and discussion Structure and morphology of the samples.
This unambiguously confirms the formation of a pure anatase structure(Fig.1a).
TiO2 is a pure anatase-type structure.
Yu, Preparation and characterization of visible-light-driven plasmonic photocatalyst Ag/AgCl/TiO2 nanocomposite thin films, Journal of photochemistry and Photobiology A: Chemistry. 223(2011) 82–87
Online since: November 2010
Authors: Zhi Bo Yang, Jiu Hua Xu, Gui Bin Zhang
Introduction
Diamond is the hardest material and is widely used as cutting, grinding and polishing tools, diamond tools are usually prepared in the form of composite structures, wherein diamond grits are bonded using either a plastic, ceramic, or metallic bonding matrix.
The Cr carbide may be formed by the reaction between Cr and C at elevated temperature, and the corresponding Gibbs free energy (unit: [J]) (T unit: [K]) could be described as follows [5,6]: (1) The brazing temperature should not be excessively high, because the cubic structure of the synthetic diamond can transform into laminar graphite or carbon when exposed to high temperatures (here as the temperature of 1323K).
In brazed processing, owing to the inherent flaws of diamond crystal structure, the crystal lattice vibration intensified at the high temperature.
The structures of the formed compounds were decided by the atomic ratio of C and Cr. the quantity of Cr atoms is insufficiency to form Cr3C2 [6].
TSAI and S.T.LIN: Materials Chemistry and Physics, Vol. 84 (2004), pp. 251–258
The Cr carbide may be formed by the reaction between Cr and C at elevated temperature, and the corresponding Gibbs free energy (unit: [J]) (T unit: [K]) could be described as follows [5,6]: (1) The brazing temperature should not be excessively high, because the cubic structure of the synthetic diamond can transform into laminar graphite or carbon when exposed to high temperatures (here as the temperature of 1323K).
In brazed processing, owing to the inherent flaws of diamond crystal structure, the crystal lattice vibration intensified at the high temperature.
The structures of the formed compounds were decided by the atomic ratio of C and Cr. the quantity of Cr atoms is insufficiency to form Cr3C2 [6].
TSAI and S.T.LIN: Materials Chemistry and Physics, Vol. 84 (2004), pp. 251–258
Online since: August 2016
Authors: Keila Machado Medeiros, Hélio Lucena Lira, Vanessa da Nóbrega Medeiros, Edcleide Maria Araújo, Diego Farias Lima, Carlos Antônio Pereira de Lima
Verified to the top surfaces of the membranes with 1 and 5% w/w of CaCl2 (Figures 1 and 2), independent of the exposure time at which they were subjected, showed a structure denser and the presence of a small amount of pores, or closed cells.
All end surfaces of the membranes 15 and 20% w/w of CaCl2 (Figure 4 and 5), irrespective of the time of exposure, show a very open and irregular morphological structure, with the presence of regions sponge and the predominance of macrovoids, which dramatically increases the porosity of the entire superficial layer of membranes analyzed.
Based on the results and discussion, it was verified that the addition of 1% and 5% w/w of CaCl2, promoted the formation of a denser structure and the presence of a small amount of pores, or closed cells.
While the addition of 15% and 20% w/w of CaCl2, showed a structure irregular and very open, in the presence of foamed regions and the predominance of macrovoids.
Lee: Journal Industrial Engineering Chemistry.
All end surfaces of the membranes 15 and 20% w/w of CaCl2 (Figure 4 and 5), irrespective of the time of exposure, show a very open and irregular morphological structure, with the presence of regions sponge and the predominance of macrovoids, which dramatically increases the porosity of the entire superficial layer of membranes analyzed.
Based on the results and discussion, it was verified that the addition of 1% and 5% w/w of CaCl2, promoted the formation of a denser structure and the presence of a small amount of pores, or closed cells.
While the addition of 15% and 20% w/w of CaCl2, showed a structure irregular and very open, in the presence of foamed regions and the predominance of macrovoids.
Lee: Journal Industrial Engineering Chemistry.
Online since: October 2016
Authors: Grigory E. Khadeev, Dmitrii Ringinen, Leonid Efron
Back stress [2] and Orowan [3] theories of the Bauschinger effect correlate plate to pipe property change with the dislocation structure and microalloying precipitates.
These chemistries were chosen as the most popular in the production of pipes.
Structure was imaged in RD-ND plane at ¼ of thickness after nital etching.
Results Pictures of the steels structure are shoved on Fig. 1.
Analysis of the structures revealed that steel 1 has ferrite-pearlite microstructure (87% ferrite, 13% pearlite), steels 2 and 3 have ferrite-bainite microstructure (30% ferrite, 70% bainite and 40% ferrite, 60% bainite corresponding) (Fig. 1).
These chemistries were chosen as the most popular in the production of pipes.
Structure was imaged in RD-ND plane at ¼ of thickness after nital etching.
Results Pictures of the steels structure are shoved on Fig. 1.
Analysis of the structures revealed that steel 1 has ferrite-pearlite microstructure (87% ferrite, 13% pearlite), steels 2 and 3 have ferrite-bainite microstructure (30% ferrite, 70% bainite and 40% ferrite, 60% bainite corresponding) (Fig. 1).
Online since: October 2014
Authors: Zdeněk Peřina, Marie Wolfová, Boris Plšek
The surfaces affected by mould may be an example of the apparent degradation by moisture on the building structure [5].
The method of chemical injection is more and more commonly used due to the development of new technologies in the field of structural chemistry.
However, there is a change of the emissivity of the structure surface.
This fact allows us to infer the reach of grouting if the injection medium affects the surface of the remediated structure.
Wolfová, Program RRC/04/2010-02 - Support Of Science And Research In The Moravian-Silesian Region 2010 entitled: Experimental Using Of Nondirect Methods Of Infrared Radiation To Determine The Effective Range Of Injection By Long-term Monitoring Of Structures, Final Report 12/2012 – The Authority of The Moravian-Silesian Region (http://verejna-sprava.kr-moravskoslezsky.cz/dot_17903.html) [3] M.
The method of chemical injection is more and more commonly used due to the development of new technologies in the field of structural chemistry.
However, there is a change of the emissivity of the structure surface.
This fact allows us to infer the reach of grouting if the injection medium affects the surface of the remediated structure.
Wolfová, Program RRC/04/2010-02 - Support Of Science And Research In The Moravian-Silesian Region 2010 entitled: Experimental Using Of Nondirect Methods Of Infrared Radiation To Determine The Effective Range Of Injection By Long-term Monitoring Of Structures, Final Report 12/2012 – The Authority of The Moravian-Silesian Region (http://verejna-sprava.kr-moravskoslezsky.cz/dot_17903.html) [3] M.
Online since: March 2016
Authors: Ahmad Zaidi Sulaiman, Nurul Aimi Mohd Zainul Abidin, Norazman Mohamad Nor, Risby Mohd Sohaimi, Ariffin Ismail, Fauziah Abdul Aziz, Shahidan Radiman, Wan Md Zin Wan Yunus, Dian Darina Indah Daruis, Norhana Abdul Halim
The term MFC is generally used to describe the 0.1-1.0µm thick fibrils cellulose structure with a corresponding minimum length of 5-50µm and most of the small fibrils isolated from natural fibers normally have a wide range of diameters, some are above 0.1µm and most are below 100nm [3].
Determination of surface structure via FESEM analysis showed the effects of chemical treatment on the morphology of the samples.
Borsali, in: Rodlike Cellulose Microcrystals: Structure, Properties and Applications, Macromolecules Rapid Communications, Vol. 25 (2004), p. 771-787
Young: Cellulose Structure Modification and Hydrolysis, Wiley, New York (1986), ISBN 0471827614
BeMiller: Cellulosic, in Carbohydrates Chemistry for For Food Scienctist, Vol. 1 (1997), p. 155
Determination of surface structure via FESEM analysis showed the effects of chemical treatment on the morphology of the samples.
Borsali, in: Rodlike Cellulose Microcrystals: Structure, Properties and Applications, Macromolecules Rapid Communications, Vol. 25 (2004), p. 771-787
Young: Cellulose Structure Modification and Hydrolysis, Wiley, New York (1986), ISBN 0471827614
BeMiller: Cellulosic, in Carbohydrates Chemistry for For Food Scienctist, Vol. 1 (1997), p. 155
Online since: February 2011
Authors: Rattikorn Yimnirun, Laongnuan Srisombat, Rewadee Wongmaneerung, Supon Ananta
Surface Characterization of the Corundum-Route Lead Magnesium Niobate Ferroelectric Ceramics
La-ongnuan Srisombat1,a, Rewadee Wongmaneerung2,b,
Rattikorn Yimnirun3,c and Supon Ananta4,d
1Department of Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai 50200 Thailand
2Department of Physics, Faculty of Science, Maejo University, Chiang Mai 50290 Thailand
3School of Physics, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima 30000 Thailand
4Department of Physics, Faculty of Science, Chiang Mai University, Chiang Mai 50200 Thailand
a๕slaongnuan@yahoo.com, bre_nok@yahoo.com, crattikornyimnirun@yahoo.com, dsuponananta@yahoo.com
Keywords: Lead Magnesium Niobate; X-ray Photoelectron Spectroscopy; Surface Analysis
Abstract.
Several studies have focused on the cystal structure [4], microstructure [5], and electrical properties [6] of this material.
In general, SEM micrograph of as-fired structure of this PMN ceramic shows highly porous and heterogeneous microstructure consisting of flaky and irregular-shaped grains.
The first peak at ~138.2 eV can be assigned to Pb2+ in the perovskite structure [11,12], while the second peak at ~136.8 eV might due to Pb0 which general found on the surface of ferroelectric samples reported in the literatures [13,14].
The first component of at ~206.8 eV corresponds to Nb in the perovskite structure [7,15].
Several studies have focused on the cystal structure [4], microstructure [5], and electrical properties [6] of this material.
In general, SEM micrograph of as-fired structure of this PMN ceramic shows highly porous and heterogeneous microstructure consisting of flaky and irregular-shaped grains.
The first peak at ~138.2 eV can be assigned to Pb2+ in the perovskite structure [11,12], while the second peak at ~136.8 eV might due to Pb0 which general found on the surface of ferroelectric samples reported in the literatures [13,14].
The first component of at ~206.8 eV corresponds to Nb in the perovskite structure [7,15].
Online since: January 2007
Authors: Jae Rock Lee, Fan Long Jin, Soo Jin Park, Mi Jeong Han
Box 107, Yusong, Daejeon 305-600, South Korea
3
Department of Chemistry, Inha University, Nam-gu, Incheon 402-751, South Korea
a
e-mail : sjpark@inha.ac.kr
Keywords: epoxy resins, castor oil, clay, nanocomposites
Abstract.
The structure of ECO and BPH are shown in Fig. 1.
To examine the molecular conformation of the intercalated chains and interlayer structure, the average basal spacing (d-spacing) was determined using X-ray diffraction.
Chemical structure of the materials used. 5 1 01 52 0 (a) 3.51 nm 1.26 nm 2.67 nm C18-MMT C12-MMT N + -MMT Intensity 2θ (o ) 5 1 01 52 0 (b) ECO/C12-MMT ECO/C18-MMT Intensity 2θ (o ) Fig. 2.
Such increased d-spacing indicates that the chain of alkyl ammonium intercalates into the gallery of clay and forms an intercalated structure [6].
The structure of ECO and BPH are shown in Fig. 1.
To examine the molecular conformation of the intercalated chains and interlayer structure, the average basal spacing (d-spacing) was determined using X-ray diffraction.
Chemical structure of the materials used. 5 1 01 52 0 (a) 3.51 nm 1.26 nm 2.67 nm C18-MMT C12-MMT N + -MMT Intensity 2θ (o ) 5 1 01 52 0 (b) ECO/C12-MMT ECO/C18-MMT Intensity 2θ (o ) Fig. 2.
Such increased d-spacing indicates that the chain of alkyl ammonium intercalates into the gallery of clay and forms an intercalated structure [6].
Online since: September 2013
Authors: Shu Lan Cai, Kang Quan Qiao, Fa Mei Feng
Corrosion Inhibition of N,N- diethylammonium O,O′- di (p-chlorophenyl) dithiophosphate for Carbon Steel in HCl Solution
Shulan Cai 1,a, Kangquan Qiao2,b , Famei Feng3,c
1,2,3College of Chemistry & Pharmaceutical Engineering, Sichuan University
of Sciences & Engineering, Zigong 643000, P.
Many of the well-known organic inhibitors commonly contain oxygen atom, sulphur atom, nitrogen atom, or having aromatic or long chain carbon system etc, and possess abundant of π electrons and unshared electron pairs. these structures are beneficial to give electrons to vacant d-orbital of iron or electrostatic attractive between inhibitors and iron by means of electrons transference.
Results and Discussion The molecular structure of EDPDP.
Also, elemental analysis of EDPDP was performed using Vario EL cube type elemental analyzer, and the measured values and the theoretical values was reported in Table 1: Table 1: The elemental content comparison of EDPDP between the theoretical values and the measured values using elemental analyzer Elements C N S H The measured values 48.7826 3.4754 16.2314 5.02845 The theoretical values 48.9825 3.5766 16..3453 5.1386 As can be seen from Table 1, the measured results of element contents have a little error with the theoretical values, which proved that the molecular formula of EDPDP is (p-ClC6H4O)2PS2NH2Et2, and its molecular structure is given in Fig. 1.
Fig. 1 Molecule structure of EDPDP Polarization curves The effect of different EDPDP concentrations on the corrosion of carbon steel in 1.0 mol•L-1 HCl solution is studied using potentiodynamic polarization technique at 25 ℃.
Many of the well-known organic inhibitors commonly contain oxygen atom, sulphur atom, nitrogen atom, or having aromatic or long chain carbon system etc, and possess abundant of π electrons and unshared electron pairs. these structures are beneficial to give electrons to vacant d-orbital of iron or electrostatic attractive between inhibitors and iron by means of electrons transference.
Results and Discussion The molecular structure of EDPDP.
Also, elemental analysis of EDPDP was performed using Vario EL cube type elemental analyzer, and the measured values and the theoretical values was reported in Table 1: Table 1: The elemental content comparison of EDPDP between the theoretical values and the measured values using elemental analyzer Elements C N S H The measured values 48.7826 3.4754 16.2314 5.02845 The theoretical values 48.9825 3.5766 16..3453 5.1386 As can be seen from Table 1, the measured results of element contents have a little error with the theoretical values, which proved that the molecular formula of EDPDP is (p-ClC6H4O)2PS2NH2Et2, and its molecular structure is given in Fig. 1.
Fig. 1 Molecule structure of EDPDP Polarization curves The effect of different EDPDP concentrations on the corrosion of carbon steel in 1.0 mol•L-1 HCl solution is studied using potentiodynamic polarization technique at 25 ℃.