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Online since: April 2023
Authors: N.S. Aldebenev, I.R. Toneev, E.S. Zhuravleva, D.A. Demoretsky
Titov, Destructive Materials Thermal properties determination with application for spacecraft structures testing.
Sipyagina, New composite materials on the basis of ceramic high porous heatprotective materials and aerogels, The VIII conference of young scientists on general andinorganic chemistry, Moscow April. 10–13 (2018) 80
[17] Ying Lia, Lu Zhanga, Rujie Hea, Yongbin Mac, Keqiang Zhang, Xuejian Baia, Baosheng Xua, Yanfei Chena, Integrated thermal protection system based on C/SiC composite corrugated core sandwich plane structure, Aerospace Science and Technology.
A multi-layer integrated thermal protection system with C/SiC composite and Ti alloy lattice sandwich, Composite Structures.
Sipyagina, New composite materials on the basis of ceramic high porous heatprotective materials and aerogels, The VIII conference of young scientists on general andinorganic chemistry, Moscow April. 10–13 (2018) 80
[17] Ying Lia, Lu Zhanga, Rujie Hea, Yongbin Mac, Keqiang Zhang, Xuejian Baia, Baosheng Xua, Yanfei Chena, Integrated thermal protection system based on C/SiC composite corrugated core sandwich plane structure, Aerospace Science and Technology.
A multi-layer integrated thermal protection system with C/SiC composite and Ti alloy lattice sandwich, Composite Structures.
Online since: July 2015
Authors: Steeve Dejardin, Tony Montesin, Vincent Duquesnes, Nicolas Creton, Igor Bezverkhyy, Roland Oltra
. % at RT [1, 2], the TiHx hydride in fcc structure is formed [1, 3 - 5].
The formation of the tetragonal structure of TiH2 hydride has especially been reported [5].
By exposing α-Ti to electrolytes, the formation of a continuous hydride layer [2], the hydride precipitates or the hydrogen dissolution in the metal [7] may occur depending on the solution chemistry and pH, the applied potential, used temperature and time.
Results show a typical martensitic structure (60°-oriented edges) inside old b grains with some precipitates located at triple junction of the grain boundaries.
The formation of the tetragonal structure of TiH2 hydride has especially been reported [5].
By exposing α-Ti to electrolytes, the formation of a continuous hydride layer [2], the hydride precipitates or the hydrogen dissolution in the metal [7] may occur depending on the solution chemistry and pH, the applied potential, used temperature and time.
Results show a typical martensitic structure (60°-oriented edges) inside old b grains with some precipitates located at triple junction of the grain boundaries.
Online since: October 2007
Authors: Tohru Yamasaki, Akihisa Inoue, Takeshi Fukami, Hisamichi Kimura, Takeyuki Kikuchi, S. Maeda, Tokujiro Yamamoto, Yoshihiko Yokoyama
Inoue
3
1Department of Materials Science & Chemistry, Graduate School of Engineering,
University of Hyogo, 2167 Shosha, Himeji, Hyogo 671-2280, Japan
2
Institute for Materials Research, Tohoku University, Sendai, Miyagi 980-8577, Japan
3
Tohoku University, Sendai, Miyagi 980-8577, Japan
a
yamasaki@eng.u-hyogo.ac.jp , b
yy@imr.tohoku.ac.jp
Keywords: Zr55Cu30Al10Ni5, bulk metallic glass, supercooled liquid, viscosity, pre-annealing
Abstract.
Pre-annealing effects on viscosity of supercooled liquids Table 1 shows the structure detected by the X-ray diffraction, density, Tg, Tx and ∆Tx=(Tx-Tg) of as-cast and pre-annealed Zr55Cu30Al10Ni5 BMGs at 400 °C for 30, 60 and 120 min.
Table 1 Structure, Density, Tg, Tx and ∆Tx=(Tx-Tg) of Zr55Cu30Al10Ni5 BMGs.
Samples Structure by X-ray-diffraction Density (g/cm3) Tg (°C) Tx (°C) ∆Tx=(Tx-Tg) (°C) As-cast Glassy phase 6.726 425 538 113 400°C-30 min Glassy phase 6.731 424 535 111 60 min Grassy phase 6.741 424 532 108 120 min Grassy phase 6.746 424 528 104 (DSC, Heating rate: 400 °C/min) Figure 3 shows the viscosity (η) of the supercooled liquids of as-cast and pre-annealed Zr55Cu30Al10Ni5 BMGs at 400°C for 120 min as a function of temperature under the high-speed heating rate of 400 °C/min under a applied load of 0.049 N on the cylindrical indentation probe with a diameter of 1.0 mm.
Pre-annealing effects on viscosity of supercooled liquids Table 1 shows the structure detected by the X-ray diffraction, density, Tg, Tx and ∆Tx=(Tx-Tg) of as-cast and pre-annealed Zr55Cu30Al10Ni5 BMGs at 400 °C for 30, 60 and 120 min.
Table 1 Structure, Density, Tg, Tx and ∆Tx=(Tx-Tg) of Zr55Cu30Al10Ni5 BMGs.
Samples Structure by X-ray-diffraction Density (g/cm3) Tg (°C) Tx (°C) ∆Tx=(Tx-Tg) (°C) As-cast Glassy phase 6.726 425 538 113 400°C-30 min Glassy phase 6.731 424 535 111 60 min Grassy phase 6.741 424 532 108 120 min Grassy phase 6.746 424 528 104 (DSC, Heating rate: 400 °C/min) Figure 3 shows the viscosity (η) of the supercooled liquids of as-cast and pre-annealed Zr55Cu30Al10Ni5 BMGs at 400°C for 120 min as a function of temperature under the high-speed heating rate of 400 °C/min under a applied load of 0.049 N on the cylindrical indentation probe with a diameter of 1.0 mm.
Online since: February 2011
Authors: Wei Zhang, Wen Bin Yao, Wei Peng Yu
Results and discussion
Structure of bamboo fiber.
Fig.3 The portrait morphology of natural bamboo fiber (SEM) Fig.4 The transverse structure of natural bamboo fiber (SEM) Fig.3 and Fig.4 shows that bamboo fiber were the bundle fibers contains many fibrils.
The cross-section of fibrils is irregular oval or waist-circular or polygonal with inside cavity, gap could be seened between single fiber. from the structure, bamboo fiber maintain the original morphology and cracking method did not damage to the fibers structural.
Vol.29(2007), p.63 (In Chinese) [5] Zhan Huaiyu: Chemistry and Physics of Fiber. chapter,2 Beijing :Science Press, (2005).
Fig.3 The portrait morphology of natural bamboo fiber (SEM) Fig.4 The transverse structure of natural bamboo fiber (SEM) Fig.3 and Fig.4 shows that bamboo fiber were the bundle fibers contains many fibrils.
The cross-section of fibrils is irregular oval or waist-circular or polygonal with inside cavity, gap could be seened between single fiber. from the structure, bamboo fiber maintain the original morphology and cracking method did not damage to the fibers structural.
Vol.29(2007), p.63 (In Chinese) [5] Zhan Huaiyu: Chemistry and Physics of Fiber. chapter,2 Beijing :Science Press, (2005).
Online since: November 2011
Authors: Jun He, Qi Pang, Li Qin Qin, Jian Peng Han, Ping Fang Tao, Chun Jie Liang
Study on Photoelectrochemical performance of ZnO Nanotube /CdSeQuantum Dot-sensitized Solar Cell
Ping-fang Taoa, Jun Heb, Chunjie Liangc, HAN Jian-pengd, QIN Li-qine
Qi Pangf*
College of chemistry and material, Yulin Normal University, Yulin, Guangxi, 537000, China
a email: tpf005@126.com, bemail:hejun6692@163.com,cemail:liangchunjie012@163.com, demail: hanpengcom@yahoo.com.cn, e email: qinliqin8888@163.com, f*email: pqigx@163.com
Keywords: ZnO; Quantum Dot-sensitized Solar Cell; CdSe; Photoelectrochemical property
Abstract: ZnO nanotubes (NTs) were successfully fabricated with a hydrothermal method at low temperature.
In particular, ZnO and TiO2 NWs or NTs have attracted much attention due to their well-developed synthetic methods and excellent electrical properties arising from their highly crystalline structure[3].
From figure 1, we can see the intensity of diffraction peak (002) of the production is extreme higher then (001) and (101), and a hexagonal wurtzite structure.
The photoelectric properties results shows that the photoelectric conversion efficiency of ZnO nanotube /CdSe quantum dot sensitized electrode is 0.95%, These indicate that the ZnO nanotube arrays produced by hydrothermal method has especial hollow tube structure and direct contacts to the substrate, so it could construct the “high speed channel” that electron can transport from p-n junction surface to substrate, and could improve the performance of battery.
In particular, ZnO and TiO2 NWs or NTs have attracted much attention due to their well-developed synthetic methods and excellent electrical properties arising from their highly crystalline structure[3].
From figure 1, we can see the intensity of diffraction peak (002) of the production is extreme higher then (001) and (101), and a hexagonal wurtzite structure.
The photoelectric properties results shows that the photoelectric conversion efficiency of ZnO nanotube /CdSe quantum dot sensitized electrode is 0.95%, These indicate that the ZnO nanotube arrays produced by hydrothermal method has especial hollow tube structure and direct contacts to the substrate, so it could construct the “high speed channel” that electron can transport from p-n junction surface to substrate, and could improve the performance of battery.
Online since: January 2006
Authors: Hirotoshi Ohgi, Yoko Takezawa, Junko Yahiro, Hiroaki Imai
Control of Nanoscale Morphology of Oxide Crystals
Using Aqueous Solution Systems
Hiroaki Imai, Hirotoshi Ohgi, Yoko Takezawa, and Junko Yahiro
Department of Applied Chemistry, Faculty of Science and Technology, Keio University
3-14-1 Hiyoshi, Hohoku, Yokohama 223-8522, Japan
Keywords: Zinc oxide, Tin dioxide, Titanium dioxide, Crystal growth, Nanosheet, Nanorod
ABSTRACT
We successfully controlled nanoscale morphology of ZnO, SnO2 and TiO2 grown in aqueous
solution systems.
Addition of urea influenced the crystal structure and the morphology of the crystals grown in the solution.
The observation using TEM clarified that the nanosheets consisted of a mosaic of platy nanocrystals having a wurtzite structure.
The nanosheets of ca. 10 nm in thickness had a lamellar structure consisting of a TiO6 framework.
Addition of urea influenced the crystal structure and the morphology of the crystals grown in the solution.
The observation using TEM clarified that the nanosheets consisted of a mosaic of platy nanocrystals having a wurtzite structure.
The nanosheets of ca. 10 nm in thickness had a lamellar structure consisting of a TiO6 framework.
Online since: June 2012
Authors: Soon Ho Lee, Young Don Lim, Whan Gi Kim, Dong Wan Seo, Ho Hyoun Jang, Md. Monirul Islam, Md. Awlad Hossain, Hyun Chul Lee
Monirul Islam1,g, Whan Gi Kim1,a*
1 Department of Applied Chemistry, Konkuk University, 322 Danwol, Chungju, 380-701, Korea
aawlad1975@yahoo.com, bh3boy@hanmail.net, cs0673231@konkuk.ac.kr, dloveknotsh@hanmail.net, ejhl0802@nate.com, ffigfight@hanmail.net, gmonir_acct@yahoo.com, a*wgkim@kku.ac.kr
Keywords: SPDPEKS, fuel cell, proton exchange membrane, BFBDPB, sulfolane, sulfonation, ion exchange capacity, water uptake
Abstract: Sulfonated poly(diphenyl ether ketone sulfone)s, SPDPEKSs were successfully synthesized for proton exchange membranes (PEMs).
The chemical structure of diphenyl ketone monomer, BFBDPB, was identified by 1H NMR shown in Fig.1.
The structures of the PDPEKSs were confirmed by 1H NMR.
The structures of the SPDPEKS were confirmed by 1H NMR and IR spectroscopy.
The chemical structure of diphenyl ketone monomer, BFBDPB, was identified by 1H NMR shown in Fig.1.
The structures of the PDPEKSs were confirmed by 1H NMR.
The structures of the SPDPEKS were confirmed by 1H NMR and IR spectroscopy.
Online since: October 2002
Authors: M.T. Marques, P. Matteazzi, Jose Brito Correia, J.M. Criado, M.J. Diánez
Chemistry, Via Cotonificio 108, I-33100 Udine
Keywords: nanostructured copper alloys; hot extrusion; thermal stability.
However, softening is seen when this structure is subjected to heat treatments above 400ºC.
However, the deformation process combined with the high temperature needed to extrude at moderate pressures promotes rapid coarsening of the grain structure.
However, it is clear that the coarsening of the structure is accelerated by hot deformation process.
However, softening is seen when this structure is subjected to heat treatments above 400ºC.
However, the deformation process combined with the high temperature needed to extrude at moderate pressures promotes rapid coarsening of the grain structure.
However, it is clear that the coarsening of the structure is accelerated by hot deformation process.
Online since: July 2010
Authors: Soo Wohn Lee, Sung Hun Cho, Hyun Hwi Lee, Bhupendra Joshi, Seung Ho Kim
Nowadays advanced ceramics are widely used in cutting tools, dies for
drawing or extrusion, seal rings, valve seats, bearing parts, and a variety of high temperature engine
parts, etc.[4-6] However, the use of single-phase ceramics, even when fully densified, in high
temperature structure or wear application is limited by the variability of their mechanical strength and
their poor fracture toughness.
This strength is related with the mechanical properties of materials such as fine grain and boundary chemistry.
Kilduff, Engineering Materials Technology - Structures, Processing, Properties & Selection (3 rd ed.), Prentice-Hall, Inc., (1997)
R., Structure Ceramics.
This strength is related with the mechanical properties of materials such as fine grain and boundary chemistry.
Kilduff, Engineering Materials Technology - Structures, Processing, Properties & Selection (3 rd ed.), Prentice-Hall, Inc., (1997)
R., Structure Ceramics.
Online since: June 2013
Authors: Robert D. Maksimov, Ugis Cabulis, K. Ivakina, E. Skadins, S. Gaidukov, V. Tupureina, A. Kiyanitsa
Influence of Nanoclay Additive on Mechanical Properties of Bio-Based Polyurethane Nanocomposites
K.Ivakina1, E.Skadins1, A.Kiyanitsa1, S.Gaidukov1a, V.Tupureina1, U.Cabulis2b, R.D.Maksimov3
11Institute of Polymer Materials, Riga Technical University, Riga, Latvia
2Latvian State Institute of Wood Chemistry, Riga, Latvia
3Institute of Polymer Mechanics, University of Latvia, Riga, Latvia
asergejs@ktf.rtu.lv (corresponding author)
bcabulis@edi.lv
Keywords: polyurethane, nanoclay, nanocomposite, mechanical properties.
Aggregates, in comparison to the elementary nanoparticles, do not interact strongly with the polymer matrix, but form the defective structure of the composite, that can drop mechanical properties of material [6].
The organic modifiers’ chemical structures are shown in Fig.1.
The obtained fact of the increase of the tensile properties and microhardness is related to the effect of essential interaction between the polymer matrix and nanoparticles at the interface and the modified structure of polymer matrix in the interphase owing to the decrease of mobility of the macromolecule chains contacting the surface of particles.
Aggregates, in comparison to the elementary nanoparticles, do not interact strongly with the polymer matrix, but form the defective structure of the composite, that can drop mechanical properties of material [6].
The organic modifiers’ chemical structures are shown in Fig.1.
The obtained fact of the increase of the tensile properties and microhardness is related to the effect of essential interaction between the polymer matrix and nanoparticles at the interface and the modified structure of polymer matrix in the interphase owing to the decrease of mobility of the macromolecule chains contacting the surface of particles.