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Online since: January 2011
Authors: Ke Chao Zhou, Lei Zhang, Zhi You Li, Li Ma
No remnants of NiO platelets formed on the surface layer were observed after oxidation at 960°C, while many small pyramid structures on the surface layers was observed.
The formation of the porous structure of the oxide scale formed on sample A also might be associated with the substrate crystal structure.
It also shows that the different crystal structure for sample B, such as high preferred orientation, might be contributing to the high oxidation resistance for Ni coatings.
Xue: Materials Chemistry and Physics Vol.99 (2006), p.96
The formation of the porous structure of the oxide scale formed on sample A also might be associated with the substrate crystal structure.
It also shows that the different crystal structure for sample B, such as high preferred orientation, might be contributing to the high oxidation resistance for Ni coatings.
Xue: Materials Chemistry and Physics Vol.99 (2006), p.96
Online since: February 2007
Authors: Xiao Feng Chen, Ying Jun Wang, L.Y. Wang, Kai Hui Nan, Na Ru Zhao
The ideal structures must be formed by an interconnected porous network
with a wide variety of pores sizes, large pores that allow tissue ingrowth and vascularization of the
new formed tissue [14], and pores in the microporous range to promote protein adhesion and
consequently cell adhesion and proliferation.
SEM analysis of the porous structures of the sample before immersion revealed a microstructure composed of various size pores (refer with: Fig.3a).
The special structure improves the activity of chemical reaction with physiological body fluid for biomaterials, and also provides a great deal of "crystal nucleus" for the aggradation of hydroxy- carbonate-apatite (HCA).
Conclusions The bioglass reinforced tricalcium phosphate scaffold possesses an inter-connectively porous structure with the pore diameters from 100 to 500 µm.
West: Life Chemistry Report.
SEM analysis of the porous structures of the sample before immersion revealed a microstructure composed of various size pores (refer with: Fig.3a).
The special structure improves the activity of chemical reaction with physiological body fluid for biomaterials, and also provides a great deal of "crystal nucleus" for the aggradation of hydroxy- carbonate-apatite (HCA).
Conclusions The bioglass reinforced tricalcium phosphate scaffold possesses an inter-connectively porous structure with the pore diameters from 100 to 500 µm.
West: Life Chemistry Report.
Online since: June 2012
Authors: Yan Song Zhu
Introduction
Atomization technology is extensively applied into agriculture, coal, chemistry and other industry.
But the process of atomization is so complicated, because the geometrical structure of nozzle and the inlet pressure of nozzle and some others factors are all affecting the water droplet generation.
The Analysis of Jet Exhausting Atomization Nozzle A.The Structure and Principle of Jet Exhausting Atomization Nozzle.
Fig.1 gives its structure.
Journal of Engineering Thermophysics Vol.24 (2003), p.613-616 [7] T.Gawehn, A.Gülhan, N.S.Al-Hasan and G.H.Schner: Experimental and Numerical Analysis of the Structure of Pseudo-shock Systems in Laval Nozzles with Parallel Side Walls.
But the process of atomization is so complicated, because the geometrical structure of nozzle and the inlet pressure of nozzle and some others factors are all affecting the water droplet generation.
The Analysis of Jet Exhausting Atomization Nozzle A.The Structure and Principle of Jet Exhausting Atomization Nozzle.
Fig.1 gives its structure.
Journal of Engineering Thermophysics Vol.24 (2003), p.613-616 [7] T.Gawehn, A.Gülhan, N.S.Al-Hasan and G.H.Schner: Experimental and Numerical Analysis of the Structure of Pseudo-shock Systems in Laval Nozzles with Parallel Side Walls.
Online since: June 2004
Authors: Stephen E. Saddow, A. Savtchouk, A.M. Hoff, E. Oborina
Introduction
High quality thermal oxides on silicon carbide are a key to the fabrication of future generations of
field effect and other electronic device structures.
This corona-based method, described in [5], facilitates the rapid evaluation of processing effects while the complications and cost associated with the fabrication of capacitor structures are avoided.
The afterglow gas chemistry used in this work was O2 and 10% volume flow of N2O.
The SiC sample is held on a vacuum chuck that moves in sequence under a charging structure and then under the potential probe.
Evidence of the effective removal of carbon from films grown in the afterglow process is seen in the insert of Fig. 2 where scatter plots for 300Å films show the dependence of QC versus VCPD, or COX when the oxide-semiconductor structure is biased in accumulation.
This corona-based method, described in [5], facilitates the rapid evaluation of processing effects while the complications and cost associated with the fabrication of capacitor structures are avoided.
The afterglow gas chemistry used in this work was O2 and 10% volume flow of N2O.
The SiC sample is held on a vacuum chuck that moves in sequence under a charging structure and then under the potential probe.
Evidence of the effective removal of carbon from films grown in the afterglow process is seen in the insert of Fig. 2 where scatter plots for 300Å films show the dependence of QC versus VCPD, or COX when the oxide-semiconductor structure is biased in accumulation.
Online since: June 2010
Authors: Hanna J. Krztoń
Introduction
One of the by-products of steel industry is steelmaking dust, formed during steelmaking
processes, and its chemical composition strongly depends on the chemistry of the kind of processed
steel.
In every sample, the calculated fraction of an amorphous component contained also the part of the phases of the unknown crystal structure.
Unfortunately, there is still no structure data of the identified lead compounds, so - excluding lanarkite - there was no possibility to include these compounds in the calculated pattern.
The calculated values of "amorphous content" contain the fractions of lead compounds which structures are unknown and cannot be used in Rietveld refinement quantification.
But in these investigations, a considerable rise to χ2 values comes from not fitted diffraction lines of phases of unknown structures.
In every sample, the calculated fraction of an amorphous component contained also the part of the phases of the unknown crystal structure.
Unfortunately, there is still no structure data of the identified lead compounds, so - excluding lanarkite - there was no possibility to include these compounds in the calculated pattern.
The calculated values of "amorphous content" contain the fractions of lead compounds which structures are unknown and cannot be used in Rietveld refinement quantification.
But in these investigations, a considerable rise to χ2 values comes from not fitted diffraction lines of phases of unknown structures.
Online since: January 2013
Authors: C.H. Hu, Feng Jun Qi, Hai Jiang, Qian Liu, Xin Zhang, Jun Cao
Plasma diffusing technology may endow the workpiece with well wear resistance, fatigue resistance and causticity resistance through changing the chemical composition and structure of the workpiece surface material.
The morphology and phase structure of the duplex layer was observed and examined by using Quanta200 scanning electron microscopy (SEM) and D8 ADVANCE X-ray diffractometer(XRD), respectively.
Results and Discussion Morphologies and Structure.
It can be seen that the FeS solid lubrication duplex layer has loose structure, and the sulphide grains pile layer upon layer, and their dimensions are very fine and in micron nano scale.
Chinese Journal of Inorganic Chemistry, 2008, 24(2):275-279.In Chinese
The morphology and phase structure of the duplex layer was observed and examined by using Quanta200 scanning electron microscopy (SEM) and D8 ADVANCE X-ray diffractometer(XRD), respectively.
Results and Discussion Morphologies and Structure.
It can be seen that the FeS solid lubrication duplex layer has loose structure, and the sulphide grains pile layer upon layer, and their dimensions are very fine and in micron nano scale.
Chinese Journal of Inorganic Chemistry, 2008, 24(2):275-279.In Chinese
Online since: June 2014
Authors: P. Devendran, T. Alagesan, K. Pandian
Synthesis and Characterization of Bi2S3 Nanorods Decorated on Carbon Sphere and Study its Electrochemical Application
P.DEVENDRAN,1a T.ALAGESAN, *1b and K.PANDIAN*2c
*1 Department of Physics, Presidency College, Chennai-600 005, India,
*2 Department of Inorganic Chemistry, University of Madras, Guindy Campus,
Chennai-600 025, India.
The C-H bending vibration comes around at 847 cm-1and also the corresponding intensity of Bi-S bond (PVA-Bi2S3@CS) are decreased for the reason that the size of Bi2S3 NRs converted into very small size, so easily adsorbed on CSs as shown in Fig.1(d). 3.2 Structural and Morphological Studies The positions and relative intensities of all the peaks are in good conformity with those of the orthorhombic crystal structure of Bi2S3 and are indexed according to JCPDS card number 17-0320.The broadening of the peaks clearly indicates that the size of the product is in Fig. 2: XRD spectrum of Bi2S3 NRs coated on carbon spheres, (a) - without PVP, (b) - low Concentration of PVP, (c) - high concentration of PVP.
While increasingthe time duration (24 h), the nanorods were formed as flower like structures on the carbon spheres as shown in Fig.4(E-G).
Bi(DTC)3shows the principle weight loss between 200ºC to 375ºC with a maximum at 273ºC (Fig.5-a) is corresponding to the complete decomposition of its Bi(DTC)3metal complex structure.Fig.5-b. showsTG-DTA curves ofBi2S3 NRs coated CS nanocomposites.
From the XRD data, we confirmed the crystalline structure and NRs size of the nanomaterials.
The C-H bending vibration comes around at 847 cm-1and also the corresponding intensity of Bi-S bond (PVA-Bi2S3@CS) are decreased for the reason that the size of Bi2S3 NRs converted into very small size, so easily adsorbed on CSs as shown in Fig.1(d). 3.2 Structural and Morphological Studies The positions and relative intensities of all the peaks are in good conformity with those of the orthorhombic crystal structure of Bi2S3 and are indexed according to JCPDS card number 17-0320.The broadening of the peaks clearly indicates that the size of the product is in Fig. 2: XRD spectrum of Bi2S3 NRs coated on carbon spheres, (a) - without PVP, (b) - low Concentration of PVP, (c) - high concentration of PVP.
While increasingthe time duration (24 h), the nanorods were formed as flower like structures on the carbon spheres as shown in Fig.4(E-G).
Bi(DTC)3shows the principle weight loss between 200ºC to 375ºC with a maximum at 273ºC (Fig.5-a) is corresponding to the complete decomposition of its Bi(DTC)3metal complex structure.Fig.5-b. showsTG-DTA curves ofBi2S3 NRs coated CS nanocomposites.
From the XRD data, we confirmed the crystalline structure and NRs size of the nanomaterials.
Online since: October 2017
Authors: Azizah Hanom Ahmad, Rosnah Zakaria, MOHD HAMIZAN SELAMAT
The chemical structure of polyurethane-diol and NaI have achieved highest conductivity of 8.06x10-5 S.cm-1 where structural of polyurethane-diol with NaI shown redox Fermi vectorial energy transfer evaluated for performance of efficiency.
The conductivity, σ is subsequently calculated using the equation below: σ = 1/ R (1) Fig. 1.1: DSSC cell diagram and respective circuit analysis for electrolyte 2.3 DSSC fabrication DSSC device was made of several layered structures of electrodes and electrolyte placement in between photoanode/electrolyte/counter electrode orientation as in figure 1.1.
Materials Chemistry and Physics 143: 1191-1198 [10] Sharma, G.D.; Balraju, P. and Kumar, M.; Roy, M.S.; 2014: Quasi solid state dye sensitized solar cells employing a polymer electrolyte and xanthene dyes.
The conductivity, σ is subsequently calculated using the equation below: σ = 1/ R (1) Fig. 1.1: DSSC cell diagram and respective circuit analysis for electrolyte 2.3 DSSC fabrication DSSC device was made of several layered structures of electrodes and electrolyte placement in between photoanode/electrolyte/counter electrode orientation as in figure 1.1.
Materials Chemistry and Physics 143: 1191-1198 [10] Sharma, G.D.; Balraju, P. and Kumar, M.; Roy, M.S.; 2014: Quasi solid state dye sensitized solar cells employing a polymer electrolyte and xanthene dyes.
Online since: August 2022
Authors: Siham Malki, Ibtissam Guesmi, Zakariae Darhi, Larbi El Farh, Allal Challioui
Challioui2,e
1Laboratory of Theoretical Physics, Particles, Modeling and Energies " LPTPME ", Morocco.
2Laboratory of Applied Chemistry and Environment, Morocco.
The calculation of the pressure and the temperature dependence of the thermodynamic properties of VSb2 material is obtained from that of the electronic structure, within the framework of the Quasi-Harmonic Approximation (QHA).The thermodynamic properties such as the primitive cell volume V(Bohr3), the bulk modulus B (GPa), the heat capacities CV(J.mol-1.K-1) and CP(J.mol-1.K-1), the thermal expansion coefficient α (K-1), the Grüneisen parameter γ, and the Debye temperature qD(K) have been studied depending on the temperature (T) in the range [0°K; 500°K], and the pressure (P) in the interval [0 ; 15 GPa].
It crystallizes in the tetragonal CuAl2-type structure, where each vanadium atom is coordinated by eight antimony atoms at equal distance, with vanadium (V) atoms occupy the Wyckoff position 4a (0,0,0.25) and antimony (Sb) atoms are located at the Wyckoff position 8h (0.1566,0.65566,0)[2].
The calculation of the pressure and the temperature dependence of the thermodynamic properties of VSb2 material is obtained from that of the electronic structure, within the framework of the Quasi-Harmonic Approximation (QHA).The thermodynamic properties such as the primitive cell volume V(Bohr3), the bulk modulus B (GPa), the heat capacities CV(J.mol-1.K-1) and CP(J.mol-1.K-1), the thermal expansion coefficient α (K-1), the Grüneisen parameter γ, and the Debye temperature qD(K) have been studied depending on the temperature (T) in the range [0°K; 500°K], and the pressure (P) in the interval [0 ; 15 GPa].
It crystallizes in the tetragonal CuAl2-type structure, where each vanadium atom is coordinated by eight antimony atoms at equal distance, with vanadium (V) atoms occupy the Wyckoff position 4a (0,0,0.25) and antimony (Sb) atoms are located at the Wyckoff position 8h (0.1566,0.65566,0)[2].
Online since: October 2014
Authors: Yang Zhang, Qiang Yu, Yan Jiang, Hong Wen Zhang, Shi Long Zhou
On the one hand, the KH-570 inside the block copolymer affects immovable phase of GPC; On the other hand, the spatial structure of functional block copolymer is complex.
Furthermore, ductile fracture characteristics of composites are exhibited by the wire mesh structure on the impact fracture surfaces.
The IR, UV, 1H NMR and GPC were used to characterize the structures and composition of block macromolecular coupling agents.
This kind of block macromolecular coupling agent with well-defined structures may be used in many fields such as bond, coating, and damping materials.
[6] Libang Feng, Lin He, Yingxia Ma: Materials Chemistry and Physics, Vol. (116)2009, p. 158-163
Furthermore, ductile fracture characteristics of composites are exhibited by the wire mesh structure on the impact fracture surfaces.
The IR, UV, 1H NMR and GPC were used to characterize the structures and composition of block macromolecular coupling agents.
This kind of block macromolecular coupling agent with well-defined structures may be used in many fields such as bond, coating, and damping materials.
[6] Libang Feng, Lin He, Yingxia Ma: Materials Chemistry and Physics, Vol. (116)2009, p. 158-163