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Online since: August 2008
Authors: Sukon Phanichphant, Pusit Pookmanee, J. Yotasing
Phanichphant2,3,c
1
Department of Chemistry, Faculty of Science, Maejo University, Chiang Mai, 50290, Thailand
2
Department of Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai, 50200,Thailand
3
NANOTEC Center Excellence at Chiang Mai University, Chiang Mai, 50200, Thailand
a
pusit@mju.ac.th,
b
jatupoly@yahoo.co.th,
c
sphanichphant@yahoo.com
Keywords: Coprecipitation oxalate method, ZnTiO3
Abstract.
Zinc titanate (ZnTiO3) has an ordered corundum structure, lattice parameters of a- and c-axis are 5.0787 and 13.9271 Å, respectively [6].
At lower calcinations temperature, 500 oC for 2h, the XRD pattern shows a mixture multiphase of ZnO with hexagonal and ZnTiO3 with cubic structure (Fig. 1.
At calcinations temperature, 700 oC for 2h, the XRD pattern shows a mixture multiphase of TiO2 with anatase and ZnTiO3 with cubic structure (Fig. 1.
Acknowledgements The authors would like to thank the financially support from the Department of Chemistry, the Faculty of Science, Maejo University, Chiang Mai, Thailand.
Zinc titanate (ZnTiO3) has an ordered corundum structure, lattice parameters of a- and c-axis are 5.0787 and 13.9271 Å, respectively [6].
At lower calcinations temperature, 500 oC for 2h, the XRD pattern shows a mixture multiphase of ZnO with hexagonal and ZnTiO3 with cubic structure (Fig. 1.
At calcinations temperature, 700 oC for 2h, the XRD pattern shows a mixture multiphase of TiO2 with anatase and ZnTiO3 with cubic structure (Fig. 1.
Acknowledgements The authors would like to thank the financially support from the Department of Chemistry, the Faculty of Science, Maejo University, Chiang Mai, Thailand.
Online since: October 2006
Authors: Yuichi Ikuhara, Koji Morita, Taketo Sakuma, Keijiro Hiraga, Byung Nam Kim, Takahisa Yamamoto, Hidehiro Yoshida
The present paper aims to briefly summarize
our recent experimental data of the doping effect on the high temperature plastic flow in 3mol%
Y2O3-stabilized TZP (3Y-TZP) and Al2O3, and to show that change in chemistry of grain boundaries
is responsible for the doping effect.
Grain Boundary Structure in Oxide Ceramics.
The present results indicate that the high temperature plastic flow in TZP and Al2O3 is strongly influenced by chemistry in the grain boundaries.
The present study is probably the first trial to explain the doping effect on the high temperature plastic flow in oxide ceramics in terms of the chemistry in the grain boundaries.
structure.
Grain Boundary Structure in Oxide Ceramics.
The present results indicate that the high temperature plastic flow in TZP and Al2O3 is strongly influenced by chemistry in the grain boundaries.
The present study is probably the first trial to explain the doping effect on the high temperature plastic flow in oxide ceramics in terms of the chemistry in the grain boundaries.
structure.
Online since: July 2023
Authors: Leo Cristobal C. Ambolode II, Art Anthony Z. Munio, Alvanh Alem G. Pido
Electronic Structure
To gain insights into the electronic properties of the complexes, we calculated the electronic band structures and density of states.
Taghiyari, Electronic Properties Of Graphene Oxide In The Presence Of Cellulose Chains: A Density Functional Theory Approach, Cellulose Chemistry and Technology. 53 (2019) 411–416 [27] M.
Ambolode II, Non-Covalent Functionalization of Biphenylene Network by Cellulose and Nylon-6: A First-Principles Study, Biointerface Research in Applied Chemistry 13 (2023) [37] J.
Steiner, The Weak Hydrogen Bond: In Structural Chemistry and Biology, International Union of Crystallography Monographs on Crystallography, Oxford University Press: Oxford, 2001 [44] T.
Dag, Oxygenation of Carbon Nanotubes: Atomic Structure, Energetics, and Electronic Structure.
Taghiyari, Electronic Properties Of Graphene Oxide In The Presence Of Cellulose Chains: A Density Functional Theory Approach, Cellulose Chemistry and Technology. 53 (2019) 411–416 [27] M.
Ambolode II, Non-Covalent Functionalization of Biphenylene Network by Cellulose and Nylon-6: A First-Principles Study, Biointerface Research in Applied Chemistry 13 (2023) [37] J.
Steiner, The Weak Hydrogen Bond: In Structural Chemistry and Biology, International Union of Crystallography Monographs on Crystallography, Oxford University Press: Oxford, 2001 [44] T.
Dag, Oxygenation of Carbon Nanotubes: Atomic Structure, Energetics, and Electronic Structure.
Online since: August 2013
Authors: Daniela Ionescu, Maria Kovaci
The tunability of the electromagnetic properties, considered until now as a matter of chemistry, strictly depending on the synthesizing process and studied by experimental methods with enough precision at frequencies no higher than a few MHz, can be reached by the 3D simulation methods, which reproduce the structure and simulate the interactions between constituents and with external fields at any frequencies.
The 3D simulation methods, which reproduce the structure and simulate the interactions between constituents and with external fields at any frequencies, offer the possibility to indentify and choose the optimal control parameters at structure level.
The stable phase structure corresponds to a sintering temperature around 1280°C–1300°C.
The functions , and depend on crystalline phase structure and the structure of nonograins.
Hsiao-Lin, Structure and Dielectric Properties of Perovskite -Barium Titanate (BaTiO3), Subm. in Part.
The 3D simulation methods, which reproduce the structure and simulate the interactions between constituents and with external fields at any frequencies, offer the possibility to indentify and choose the optimal control parameters at structure level.
The stable phase structure corresponds to a sintering temperature around 1280°C–1300°C.
The functions , and depend on crystalline phase structure and the structure of nonograins.
Hsiao-Lin, Structure and Dielectric Properties of Perovskite -Barium Titanate (BaTiO3), Subm. in Part.
Online since: September 2014
Authors: Carlos Alberto Soufen, Carlos Alberto Fonzar Pintão, Momotaro Imaizumi, Marcelo Capella de Campos
The FP-LAPW is among the most accurate band structure calculations currently available and is based on the density functional theory with general gradient approximation for the exchange and correlation potential.
Computational methods based on ab initio calculations of the electronic structure include density functional theory and the full potential linearized augmented plane waves (FP-LAPW) method with APW+lo [2] using a gradient general approximation as the exchange and correlation potential[3].
Computational Method The FP-LAPW is among the most accurate band structure calculations currently available.
Table1 Shows the equilibrium lattice constant (a0),the bulk modulus B(1011N/m2), and the minimum total energy E0 (eV) Veq(Å3) a0(Å) B(1011N/m2) E0(eV) 64 6.36 1.45 –76277.39 For a cubic structure, the bulk modulus should be consider a good indicator of hardness due to the existing correlation between them [9,10].
Vienna, Austria) (2001) 1-187 [3] Wu, Z., Cohen, R.E., More accurate generalized gradient approximation for solids, Physical Review B 73 (2006) 235116-1 235116-5 [4] Sahnoun, M., Zbirli, M., Daul,C., Khenata, R., Baltache, H., Driz, M., Full potential calculation of structural, electronic and optical properties of KMgF3, Materials Chemistry and Physics, 91 (2005) 185-191 2005 [5] Terki, R., Feraoun, H., Bertrand,G., Aroung,H., Full potential calculation of structural , elastic and electronic properties of BaZo3 and SrZro3 Physics Status Solid b, 242 (2005) 1054-1062 [6] Imaizumi, M., Soufen, C.A.
Computational methods based on ab initio calculations of the electronic structure include density functional theory and the full potential linearized augmented plane waves (FP-LAPW) method with APW+lo [2] using a gradient general approximation as the exchange and correlation potential[3].
Computational Method The FP-LAPW is among the most accurate band structure calculations currently available.
Table1 Shows the equilibrium lattice constant (a0),the bulk modulus B(1011N/m2), and the minimum total energy E0 (eV) Veq(Å3) a0(Å) B(1011N/m2) E0(eV) 64 6.36 1.45 –76277.39 For a cubic structure, the bulk modulus should be consider a good indicator of hardness due to the existing correlation between them [9,10].
Vienna, Austria) (2001) 1-187 [3] Wu, Z., Cohen, R.E., More accurate generalized gradient approximation for solids, Physical Review B 73 (2006) 235116-1 235116-5 [4] Sahnoun, M., Zbirli, M., Daul,C., Khenata, R., Baltache, H., Driz, M., Full potential calculation of structural, electronic and optical properties of KMgF3, Materials Chemistry and Physics, 91 (2005) 185-191 2005 [5] Terki, R., Feraoun, H., Bertrand,G., Aroung,H., Full potential calculation of structural , elastic and electronic properties of BaZo3 and SrZro3 Physics Status Solid b, 242 (2005) 1054-1062 [6] Imaizumi, M., Soufen, C.A.
Online since: September 2013
Authors: Yuan Yang, Jian Min Gao, Tian Ma, Xin Min Hao, Jin Ju Sun, Xin Yu Cui
Results and Discussion
Effect of air-phosphoric acid on the microcrystalline structure of hemp stem
Fig.1shows the microcrystalline structures of hemp stem and mesoporous carbon (AC-50).
Fig.2c shows that the sample has developed pore structure.
These results in pore structure agree well with those obtained from FE-SEM.
Chemistry and Industry of Forest Products, Vol.6( 2010),p.13-16.
Chemistry and industry of forest products, Vol.6(2010),p.24-28.
Fig.2c shows that the sample has developed pore structure.
These results in pore structure agree well with those obtained from FE-SEM.
Chemistry and Industry of Forest Products, Vol.6( 2010),p.13-16.
Chemistry and industry of forest products, Vol.6(2010),p.24-28.
Online since: September 2016
Authors: Nikita V. Martyushev, Natalya V. Plotnikova, Alexander I. Smirnov, Vladimir G. Burov
Features of the Fine Structure of the Active Layers of Organic Solar Cells
Alexander I.
The structure of the active layer of the film is mainly amorphous.
TEM images of film structure after annealing, P3HT:ICBA (1:1 wt. %).
Schwartz Room to Improve Conjugated Polymer-Based Solar Cells: Understanding how Thermal Annealing Affects the Fullerene Component of a Bulk Heterojunction Photovoltaic Device, Journal of Physical Chemistry C. 48 (2008) 18711-18716
Improving the reproducibility of P3HT: PCBM solar cells by controlling the PCBM/cathode interface, Journal of Physical Chemistry. (2009) 18978–1898
The structure of the active layer of the film is mainly amorphous.
TEM images of film structure after annealing, P3HT:ICBA (1:1 wt. %).
Schwartz Room to Improve Conjugated Polymer-Based Solar Cells: Understanding how Thermal Annealing Affects the Fullerene Component of a Bulk Heterojunction Photovoltaic Device, Journal of Physical Chemistry C. 48 (2008) 18711-18716
Improving the reproducibility of P3HT: PCBM solar cells by controlling the PCBM/cathode interface, Journal of Physical Chemistry. (2009) 18978–1898
Online since: October 2014
Authors: Yue Xian Liu, Nan Zhe Zhang
Experiment
As shown in Fig. 1, by opening five courses of discipline basis experiment, it enables students to master the basic theory knowledge and experimental skills of physics and chemistry aspects which are required for the chemical engineering discipline, and cultivates students' manipulative ability.
Practical Teaching System of Chemical Engineering Practical Training Practice Extra- curricular Practical Activities Discipline Basis Experiment Specialty Basis Experiment Specialty Experiment Experiment University Physics Experiment (24p) Chemistry Basis Experiment C.E.
Specialty Experiment (64p) Inorganic Chemistry Experiment (32p) Analytical Chemistry Experiment (32p) Organic Chemistry Experiment (64p) Physical Chemistry Experiment (32p) Engineering Training (2w) Specialty Computer Training (3w) C.E.
Note: C.E. = Chemical Engineering; P.T. = Practical Training; C.D. = Course Design; p = periods; w = weeks Fig. 1 The structure diagram on practical teaching system of chemical engineering In the teaching of chemical engineering principle experiment, through the introduction of the simulation experiment, it can fast, vividly and conveniently show experimental device, experimental process, experimental result and experimental law; students can preview experiments on the computer in the simulation laboratory, in order to better grasp the experimental process and method, to obtain more knowledge and information, and to lay a good foundation for the next actual experimental operation; it can greatly mobilize the students' enthusiasm, strengthen the experimental process and improve the experimental teaching effect.
Practical Teaching System of Chemical Engineering Practical Training Practice Extra- curricular Practical Activities Discipline Basis Experiment Specialty Basis Experiment Specialty Experiment Experiment University Physics Experiment (24p) Chemistry Basis Experiment C.E.
Specialty Experiment (64p) Inorganic Chemistry Experiment (32p) Analytical Chemistry Experiment (32p) Organic Chemistry Experiment (64p) Physical Chemistry Experiment (32p) Engineering Training (2w) Specialty Computer Training (3w) C.E.
Note: C.E. = Chemical Engineering; P.T. = Practical Training; C.D. = Course Design; p = periods; w = weeks Fig. 1 The structure diagram on practical teaching system of chemical engineering In the teaching of chemical engineering principle experiment, through the introduction of the simulation experiment, it can fast, vividly and conveniently show experimental device, experimental process, experimental result and experimental law; students can preview experiments on the computer in the simulation laboratory, in order to better grasp the experimental process and method, to obtain more knowledge and information, and to lay a good foundation for the next actual experimental operation; it can greatly mobilize the students' enthusiasm, strengthen the experimental process and improve the experimental teaching effect.
Online since: June 2014
Authors: Shang Hui Ding, Chu Yang Tang, Teng Fei Chang, Ying Dong Jia, Ge Wang, Mei Yu Gu
The lingo-cellulosic structure of hazelnut shell provided high devolatilization rates even at low temperatures.
Chemistry of coal utilization (Wiley Publications, New Year 1981)
Journal of Fuel Chemistry and Technology Vol. 35(2007). p. 4
Journal of Fuel Chemistry and Technology Vol 39(2011). p. 728
Journal of Fuel Chemistry and Technology Vol 34(2006). p. 650
Chemistry of coal utilization (Wiley Publications, New Year 1981)
Journal of Fuel Chemistry and Technology Vol. 35(2007). p. 4
Journal of Fuel Chemistry and Technology Vol 39(2011). p. 728
Journal of Fuel Chemistry and Technology Vol 34(2006). p. 650
Online since: August 2011
Authors: Xin Quan Xin, Dao Hua Li
Spectra characterization of Mo(W)-S-Ag cluster compounds films modified silver electrodes and their electrochemical behavior
Dao-hua LI 1, a, Xin-quan XIN 2,b
1College of Chemistry and Chemical Engineering,Neijiang Normal University, Neijiang 641112, China; 2Coordination Chemistry Institute, Nanjing University, State Key Laboratory of Coordination Chemistry, Nanjing 210093, China
adaohl@163.com, bxinxq@163.com
Keywords: Mo(W)-S-Ag cluster compounds films; modified electrodes; spectra characterization; electrochemical behavior
Abstract.
Introduction Many scientists have great interest in transition metal thiometalates because of their unique characteristics in complex and domains of bioinorganic chemistry, nutrition physiology and many other fields.
Numerous Mo(W)-S-Ag cluster compounds containing these thiometalates units with various framework structures have been synthesized and investigated.
The average value of seven determinations was 97% with 0.09 relative standard deviation which is fitted to the chemistry dictionary.
LI:Chinese Journal of Chemistry, 2005, 23(2)
Introduction Many scientists have great interest in transition metal thiometalates because of their unique characteristics in complex and domains of bioinorganic chemistry, nutrition physiology and many other fields.
Numerous Mo(W)-S-Ag cluster compounds containing these thiometalates units with various framework structures have been synthesized and investigated.
The average value of seven determinations was 97% with 0.09 relative standard deviation which is fitted to the chemistry dictionary.
LI:Chinese Journal of Chemistry, 2005, 23(2)