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Online since: April 2012
Authors: C. Witthayaprapakorn, Robert Molloy
Molloy2,b
1Department of Science (Chemistry), Faculty of Sciences and Agricultural Technology, RMUTL,
Chiang Mai Campus, Chiang Mai 50300, Thailand
2Biomedical Polymers Technology Unit, Department of Chemistry, Faculty of Sciences,
Chiang Mai University, Chiang Mai 50200, Thailand
achinanatw@hotmail.com, brobert@cmu.ac.th
Keywords: redox initiation, hydrogel, wound dressings
Abstract.
The result was that an already partially hydrated hydrogel was obtained because water was remained within a 3-dimensional crosslinked structure.
Acknowledgements The corresponding author (CW) wishes to thank the Department of Science (Chemistry), Faculty of Sciences and Agricultural Technology, Rajamangala University of Technology LANNA, Chiang Mai Campus, Biomedical Polymers Technology Unit, Department of Chemistry of Chiang Mai University and the Biomaterials Research Unit, School of Chemical Engineering and Applied Chemistry, Aston University, Birmingham, UK, for providing the research facilities.
The result was that an already partially hydrated hydrogel was obtained because water was remained within a 3-dimensional crosslinked structure.
Acknowledgements The corresponding author (CW) wishes to thank the Department of Science (Chemistry), Faculty of Sciences and Agricultural Technology, Rajamangala University of Technology LANNA, Chiang Mai Campus, Biomedical Polymers Technology Unit, Department of Chemistry of Chiang Mai University and the Biomaterials Research Unit, School of Chemical Engineering and Applied Chemistry, Aston University, Birmingham, UK, for providing the research facilities.
Online since: August 2012
Authors: Xiao Bing Shi, Yang Li, Wei Qiang Pang
Preparation, Characterization of Co3O4 Nano-particles and Its Catalytic Effect on the Combustion of Fuel Rich Propellants
PANG Wei-qiang1,a, SHI Xiao-bing1,b, LI Yang1,c
1 Xi’an Modern Chemistry Research Institute, Shaanxi Xi’an 710065 China
anwpu_pwq@163.com, bnwpu_pwq@126.com, cnwpu_pwq@163.com
Keywords: Material chemistry, nano-particle, fuel rich solid propellant, catalytic effect
Abstract: The mono-dispersed Co3O4 nano-particles were prepared by means of solid phase synthetical method.
The particle size, specific surface area, crystal structure and morphology of the samples were characterized by laser particle size analysis, x-ray diffraction (XRD) and transmission electron microscopy (TEM), respectively.
The particle size, specific surface area, crystal structure and morphology of the samples were characterized by laser particle size analysis, x-ray diffraction (XRD) and transmission electron microscopy (TEM), respectively.
Online since: August 2010
Authors: Heng Wei, Lei Wei, Fu Ling Yin, Jian Hui Yin, Wei Dong Liu, Xian Gui Liu, Guo Qi Wei, Hou Hua Li, Jun Han Liu
The fractal dimensions of the pore structures of low
permeability oil reservoirs are less than 2.
Fractal geometry has been applied in the fields of geology and chemistry.
In the field of chemistry, the activity of a molecule depends on whether its fractal dimension matches the fractal dimension of the target [6].
Zeng, "Fractal analysis of thioredoxin reductase structure", Acta Scientiarum Naturalium Unversitatisi Pekinensis, vol 44, 2008, p.165-170. in Chinese [7] C.W.
Li, "A study on quartenary ammonium salt gemini surfactant G-52 for water injection well stimulation in low permeability reservoirs", Oilfield Chemistry, vol 24, 2007, p.138-142. in Chinese
Fractal geometry has been applied in the fields of geology and chemistry.
In the field of chemistry, the activity of a molecule depends on whether its fractal dimension matches the fractal dimension of the target [6].
Zeng, "Fractal analysis of thioredoxin reductase structure", Acta Scientiarum Naturalium Unversitatisi Pekinensis, vol 44, 2008, p.165-170. in Chinese [7] C.W.
Li, "A study on quartenary ammonium salt gemini surfactant G-52 for water injection well stimulation in low permeability reservoirs", Oilfield Chemistry, vol 24, 2007, p.138-142. in Chinese
Online since: June 2012
Authors: Ya Lan Wang, Cheng Gen Zhang, Shu Yuan Yu
A Computational Study on Structures, Stabilities and Electronic Properties of Trifluoromethyl Silsesquioxanes Si2nO3n(CF3)2n (n=1-5)
Shu-Yuan Yu 1,a, Cheng-Gen Zhang 1,2,b, Yalan Wang1
1 Department of Chemistry and Material Science, Langfang Normal College, Langfang 065000, China
2 College of Chemistry and Chemical Engineering, Graduate University of Chinese Academy of Sciences, Beijing 100049, China
ayushuyuan05@mails.gucas.ac.cn, bchgzhang04@mails.gucas.ac.cn
Keywords: trifluoromethyl silsesquioxanes, HOMO–LUMO gaps, density functional theory
Abstract.
Our study focuses on the structures, stabilities, and electronic properties of the trifluoromethyl silsesquioxanes.
The B3LYP method was a widely used density functional in theoretical investigations on molecule structures.
Results and Discussion The Structures of Trifluoromethyl Silsesquioxanes Si2nO3n(CF3)2n (n=1-5).
Frontier orbitals (HOMO and LUMO) for the structures of Si2nO3n(CF3)2n (n=1-5).
Our study focuses on the structures, stabilities, and electronic properties of the trifluoromethyl silsesquioxanes.
The B3LYP method was a widely used density functional in theoretical investigations on molecule structures.
Results and Discussion The Structures of Trifluoromethyl Silsesquioxanes Si2nO3n(CF3)2n (n=1-5).
Frontier orbitals (HOMO and LUMO) for the structures of Si2nO3n(CF3)2n (n=1-5).
Online since: January 2007
Authors: Byung Joo Kim, Soo Jin Park, Young Seak Lee
A Gas Control by Metal Nanoclusters-supported Porous Carbon
Nanofibers
Byung-Joo Kim1 , Young-Seak Lee2 , and Soo-Jin Park3,*
1
Green Chemistry & Environmental Biotechnology, Univ. of Science & Technology,
P.O.
Box 107, Yuseong, Daejeon 305-600, Korea (South) 2 Dept. of Fine Chemical Engineering and Chemistry, Chungnam National Univ., 220, Kung-dong, Yuseong, Daejeon 305-764, Korea (South) 3 Department of Chemistry, Inha Univ., 253, Nam-gu, Incheon 402-751, Korea (South) *sjpark@inha.ac.kr Keywords: Noxious gas, Metal loading, Porous carbon, Carbon nanofibers.
In common, carbon nanofibers (CNFs) observed in the early 1980s are prepared by a catalytic method, and CNFs have been recognized as one of very attractive materials due to their nano-structure and particular properties.
Total pore volume was estimated to be the liquid volume of the nitrogen at a relative pressure of about 0.995, and the micropore structures were analyzed by using D-R equations [10].
This result probably means that porous CNFs have various pore structures including high amount of micro- and mesopores.
Box 107, Yuseong, Daejeon 305-600, Korea (South) 2 Dept. of Fine Chemical Engineering and Chemistry, Chungnam National Univ., 220, Kung-dong, Yuseong, Daejeon 305-764, Korea (South) 3 Department of Chemistry, Inha Univ., 253, Nam-gu, Incheon 402-751, Korea (South) *sjpark@inha.ac.kr Keywords: Noxious gas, Metal loading, Porous carbon, Carbon nanofibers.
In common, carbon nanofibers (CNFs) observed in the early 1980s are prepared by a catalytic method, and CNFs have been recognized as one of very attractive materials due to their nano-structure and particular properties.
Total pore volume was estimated to be the liquid volume of the nitrogen at a relative pressure of about 0.995, and the micropore structures were analyzed by using D-R equations [10].
This result probably means that porous CNFs have various pore structures including high amount of micro- and mesopores.
Online since: July 2005
Authors: Pavol Šajgalík, M. Liška, David Salamon
Introduction
The term SiAlON was originally coined to describe materials containing Si, Al, O and N (and
other metals), of very wide compositions and crystal structures [1].
Crystal structure of α-Sialons requires an extra cation for stability.
Some larger cations can enter the structure only in combination with other cations.
Improvement of Sialon properties has been obtained by optimization of the chemistry and microstructure.
Improvement of fracture toughness is possible by the microstructure control, when usually equiaxed morphology of grains is changed by proper chemistry to the elongated one [9].
Crystal structure of α-Sialons requires an extra cation for stability.
Some larger cations can enter the structure only in combination with other cations.
Improvement of Sialon properties has been obtained by optimization of the chemistry and microstructure.
Improvement of fracture toughness is possible by the microstructure control, when usually equiaxed morphology of grains is changed by proper chemistry to the elongated one [9].
Online since: February 2006
Authors: Tomohiro Ozawa, Hideki Masuda, Hidekazu Arii, Yasuhiro Funahashi, Yasutaka Honda
The structure/function relationship for them
was discussed.
The study on structure/reactivity relationship of the active sites in oxidoreductases, such as soluble methane monooxygenase (sMMO) and ribonucleotide reductase (RNR) with high-valent Fe2(µ-O)2 species as intermediates in enzymatic reactions, have attracted much attention also from the point of view of organic, catalytic and industrial chemistries [1-4].
Schematic structure fully-optimized for (µ-O)(µ-CH3COO-)(µ-O22)[FeIII (A3CY)]2+.
Schematic structure fullyoptimized for (µ-O2)[FeIII (A3CY)Cl2]2.
Lippard: Advances in Inorganic Chemistry Vol. 42 (Academic Press, Inc., 1995)
The study on structure/reactivity relationship of the active sites in oxidoreductases, such as soluble methane monooxygenase (sMMO) and ribonucleotide reductase (RNR) with high-valent Fe2(µ-O)2 species as intermediates in enzymatic reactions, have attracted much attention also from the point of view of organic, catalytic and industrial chemistries [1-4].
Schematic structure fully-optimized for (µ-O)(µ-CH3COO-)(µ-O22)[FeIII (A3CY)]2+.
Schematic structure fullyoptimized for (µ-O2)[FeIII (A3CY)Cl2]2.
Lippard: Advances in Inorganic Chemistry Vol. 42 (Academic Press, Inc., 1995)
Online since: August 2005
Authors: Jiang Wen Liu, F.Z. Zeng, Zhong Ning Guo
The physical and chemical property includes the surface
hardness, residual stress, strength, structure ingredient and so on.
It seems that these result from the cumulate effects of electrochemistry and chemistry.
It appears that the function of electrolysis and chemistry is able to lower the surface hardness of workpiece greatly.
The dense pinholes in pictures are the result of the accumulative effect of electrolysis and chemistry.
It is revealed that the function of electrolysis and chemistry is harmful to the surface integrity.
It seems that these result from the cumulate effects of electrochemistry and chemistry.
It appears that the function of electrolysis and chemistry is able to lower the surface hardness of workpiece greatly.
The dense pinholes in pictures are the result of the accumulative effect of electrolysis and chemistry.
It is revealed that the function of electrolysis and chemistry is harmful to the surface integrity.
Online since: April 2005
Authors: Steven Verhaverbeke, Jian She Tang, Brian J. Brown, Han Wen Chen, Jim Papanu, Raymond Hung, Cathy Cai, Dennis Yost
Broussous, et al. investigated the cleaning efficiency and mechanisms of different cleaning
chemistries [5, 6].
Dispensing of chemistry to both the front side and backside allows for simultaneous removal of micro-contamination from both sides of the wafer.
O'Dwyer: BEOL Post ash Residue Removal Using DSP Chemistry in an FSI batch Spray Tool, (Trans Tech Publications, Switzerland, 2003)
Besson, Post Etch Cleaning Chemistries Evaluation for Low-k Cu Integration, Solid State Phenomena, Vol. 92 (2003), p263~266
Thompson, Electromigration in Cu Interconnects with very DifferentGgrain Structures, Applied Physics Letters, volume 78, No. 22, May 2001
Dispensing of chemistry to both the front side and backside allows for simultaneous removal of micro-contamination from both sides of the wafer.
O'Dwyer: BEOL Post ash Residue Removal Using DSP Chemistry in an FSI batch Spray Tool, (Trans Tech Publications, Switzerland, 2003)
Besson, Post Etch Cleaning Chemistries Evaluation for Low-k Cu Integration, Solid State Phenomena, Vol. 92 (2003), p263~266
Thompson, Electromigration in Cu Interconnects with very DifferentGgrain Structures, Applied Physics Letters, volume 78, No. 22, May 2001
Online since: January 2013
Authors: Xi Hong Lu, Xue Hu Li, Zhong Jia, Zhi Jun Xin, Dian He, Jian Ping Liang, Lei Tao
Introduction
Searching for new antimycobacterial compounds is one of the most challenging tasks in current medicinal chemistry.
Chemistry The synthetic route of N-(pyridin-4-yl) salicylamides was depicted in Fig. 1 N-(pyridin-4-yl) salicylamides 1a-6h were prepared by treatment of the corresponding substituted acetylsalicyloyl chlorides with substituted 4-amino-pyridines in chloroform in the presence of triethylamine.
The structures were fully identified by 1H NMR, 13C NMR and IR spectra.
With respecting to the activities against M. tuberculosis (TB), there are two additional major aspects considered: innate resistance, the unique structure and composition of the highly hydrophobic cell wall that must be traversed.
However, being based on our research, the activities were affected by not only hydrophobicity but also structure and electronic requirements.
Chemistry The synthetic route of N-(pyridin-4-yl) salicylamides was depicted in Fig. 1 N-(pyridin-4-yl) salicylamides 1a-6h were prepared by treatment of the corresponding substituted acetylsalicyloyl chlorides with substituted 4-amino-pyridines in chloroform in the presence of triethylamine.
The structures were fully identified by 1H NMR, 13C NMR and IR spectra.
With respecting to the activities against M. tuberculosis (TB), there are two additional major aspects considered: innate resistance, the unique structure and composition of the highly hydrophobic cell wall that must be traversed.
However, being based on our research, the activities were affected by not only hydrophobicity but also structure and electronic requirements.