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Online since: May 2018
Authors: Ahmed M. El-Khatib, Mohamed S. Badawi, Gamal D. Roston, Alaa M. Khalil, Moustafa M. Mohamed, Ramy M. Moussa
These properties are highly dependent on size, structure, morphology and accordingly on their mechanism of synthesis [1].
This modification allows controlling the properties of the synthesized nanostructured cobalt, such as composition, structure, morphology, and magnetic properties.
Orpe et al., Local structure of cobalt nanoparticles synthesized by high heat flux plasma process.
Radiation Physics and Chemistry, (2016)
Veintemillas-Verdaguer, Bulk metastable cobalt in fcc crystal structure.
This modification allows controlling the properties of the synthesized nanostructured cobalt, such as composition, structure, morphology, and magnetic properties.
Orpe et al., Local structure of cobalt nanoparticles synthesized by high heat flux plasma process.
Radiation Physics and Chemistry, (2016)
Veintemillas-Verdaguer, Bulk metastable cobalt in fcc crystal structure.
Online since: June 2013
Authors: Traian Onet, Olar Radu
reference)
28.90 (reference)
silica fume (15%)
18.90 (+7.38%)
31.80 (+10.03%)
nano-SiO2
(3%)
18.60 (+5.68%)
32.90 (+13.84%)
nano-SiO2
(5%)
21.30 (+21.02%)
33.80 (+16.95%)
nano-SiO2
(10%)
21.30 (+21.02%)
36.40 (+25.95%)
§ the accelerating effect in cement paste - more rapid hydration of cement in the presence of nano-silica due to its chemical reactivity resulting from their important surface activity [9],
§ the tendency for supplementary water adsortion – the mixture needs more water in order to maintain a constant workability [10] ,
§ a stronger tendency to agglomerate – to prevent this, dispersing additive (superplasticizers) must be used,
§ a smaller water permeability of hardened concrete – for the same workability, using 10 to 20nm nano-silica particles with a specific surface area of 160m2/g [11],
§ nano-silica increase the interfacial transition zone between aggregates and cement paste due to the reaction with the crystals of Ca(OH)2 and fills the voids in the C-S-H gel structure
The high impact collisions that reduce the microcrystalline materials down to nanocrystalline structure, don’t affect chemically the composition of the fly-ash [15].
Nano-cement particles In order to increase the cement behaviour by decreasing the size of its particles down to nano-scaled dimensions, several approaches are possible [27, 28]: § top-down method that consists in a high energy milling of Portland cement particles, § bottom-up method that is a chemical synthesis of nano-particles, § the nano-binder method that involves an inter-grinding of cement with dry mineral additives in the ball mill [29], § the use as admixtures to cement of nano-clay particles (~1nm size), obtained by exfoliating the base structure of clays that is formed by crystalline layers of aluminium phyllosilicates [30].
A great advantage of this software concept is the logical structure and the „self-learning” ability, all this presented in a simple but precise manner.
Another advantage is the „web-free-acces” posibility, that offers the oportunity to bring togheter researchers from the concrete domain, materials science, chemistry, physics and other researches domains with interest in the nano-materials field.
The high impact collisions that reduce the microcrystalline materials down to nanocrystalline structure, don’t affect chemically the composition of the fly-ash [15].
Nano-cement particles In order to increase the cement behaviour by decreasing the size of its particles down to nano-scaled dimensions, several approaches are possible [27, 28]: § top-down method that consists in a high energy milling of Portland cement particles, § bottom-up method that is a chemical synthesis of nano-particles, § the nano-binder method that involves an inter-grinding of cement with dry mineral additives in the ball mill [29], § the use as admixtures to cement of nano-clay particles (~1nm size), obtained by exfoliating the base structure of clays that is formed by crystalline layers of aluminium phyllosilicates [30].
A great advantage of this software concept is the logical structure and the „self-learning” ability, all this presented in a simple but precise manner.
Another advantage is the „web-free-acces” posibility, that offers the oportunity to bring togheter researchers from the concrete domain, materials science, chemistry, physics and other researches domains with interest in the nano-materials field.
Online since: December 2022
Authors: Nila Tanyela Berghuis, Zulfikar Fauzan Ali
Synthesis of Fatty Imidazoline from Oleic Acid with Ethylenediamine and its Characterization
Nila Tanyela Berghuis1,a*, Zulfikar Fauzan Ali1,b
1Department of Chemistry, Universitas Pertamina
*Corresponding author: Jl.
The structures are as follows in Figure 1. [7] Figure 1.
The structures of imidazole, imidazoline and imidazoline corrosion inhibitor The organic inhibitor used in this research is Fatty Imidazoline which contains nitrogen atoms.
drawing of the resulting product structure in Figure 10 below.
Structure of Product Fraction A dan C (Oleamide) dan Fraction D (Fatty Imidazole) Then to ensure that Fraction D is the target compound (fatty imidazoline), a second characterization was carried out, namely 1H-NMR.
The structures are as follows in Figure 1. [7] Figure 1.
The structures of imidazole, imidazoline and imidazoline corrosion inhibitor The organic inhibitor used in this research is Fatty Imidazoline which contains nitrogen atoms.
drawing of the resulting product structure in Figure 10 below.
Structure of Product Fraction A dan C (Oleamide) dan Fraction D (Fatty Imidazole) Then to ensure that Fraction D is the target compound (fatty imidazoline), a second characterization was carried out, namely 1H-NMR.
Online since: September 2016
Authors: Atef Badr, Socrates Ioannou, Haidar Al Maroof
Introduction
The utilization of mineral admixtures, particularly fly ash (FA), in concrete structures has noticeably increased due to the increase in environmental awareness.
Numerous concrete structures and concrete pavements could be exposed to very cold weather and freezing conditions during their life cycle.
Structures made with FA concrete are no exception.
The cement chemistry and the hydration process controlling the rapid strength development have been the topic of several scientific studies [14, 19].
Materials and Structures, 10 (1977): 212-215.
Numerous concrete structures and concrete pavements could be exposed to very cold weather and freezing conditions during their life cycle.
Structures made with FA concrete are no exception.
The cement chemistry and the hydration process controlling the rapid strength development have been the topic of several scientific studies [14, 19].
Materials and Structures, 10 (1977): 212-215.
Online since: June 2014
Authors: Yue Hong Shu, Zuo Cheng, Xue Liu
Environmental protection technology of modern lead-acid battery production
Yuehong Shu1, 2, a*, Zuo Cheng1, 2, b and Xue Liu1, 2, c
1School of Chemistry and Environment, South China Normal University, Guangzhou 510006, PR China
2Base of Production, Education & Research on Energy Storage and Power Battery of Guangdong Higher Education Institutes, Guangzhou 510006, PR China
ahongershu@163.com, b18658731702@sina.cn, cliuxue828128@126.com
Keywords: environmental protection technology, pollutants, environmental machines, lead-acid battery
Abstract.
It is designed as a compact structure with main body, fan, sound insulation room, spraying pump and controller all in one.
The device is most widely used high efficient pollution control equipment with strong pollution control capacity, high quality, long service life , simple structure, low operation noise, easy maintenance and stable performance
Adopt auto or manual ash-removing structure to shake off dust adhering to filter by patting at intervals, drop to dust collector then plug by hand[10].
(2) Structure.
It is designed as a compact structure with main body, fan, sound insulation room, spraying pump and controller all in one.
The device is most widely used high efficient pollution control equipment with strong pollution control capacity, high quality, long service life , simple structure, low operation noise, easy maintenance and stable performance
Adopt auto or manual ash-removing structure to shake off dust adhering to filter by patting at intervals, drop to dust collector then plug by hand[10].
(2) Structure.
Online since: October 2025
Authors: Riska Rachmantyo, Lia Amelia Tresna Wulan Asri, Richard Adventus Hutasoit
The advantages of lightweight concrete include a reduction in cost, a reduction in handling and production time, and an improvement in the thermal insulation performance of concrete structures[13].
LDPE belongs to the type of polymers that have a branched structure.
This indicates that the granules tested are polymers with a linear structure, as the wave number regions at 1469 cm-1 and 719 cm-1 are not branched.
On the basis of these two peaks and according to the reference of Rajandas et al. it is confirmed that the structure is consistent with LDPE and LLDPE [16,17].
Fequet, Current trends of unsustainable plastic production and micro(nano)plastic pollution, TrAC - Trends in Analytical Chemistry 160 (2023)
LDPE belongs to the type of polymers that have a branched structure.
This indicates that the granules tested are polymers with a linear structure, as the wave number regions at 1469 cm-1 and 719 cm-1 are not branched.
On the basis of these two peaks and according to the reference of Rajandas et al. it is confirmed that the structure is consistent with LDPE and LLDPE [16,17].
Fequet, Current trends of unsustainable plastic production and micro(nano)plastic pollution, TrAC - Trends in Analytical Chemistry 160 (2023)
Online since: October 2023
Authors: Nila Riyaz Saputri, Lina Mahardiani
Antibacterial Activity Edible Coating of Jackfruit Seed Starch and Alginate Incorporated with ZnO Nanoparticles Applied to Cherry Tomatoes
Lina Mahardiani1,a* and Nila Riyaz Saputri1,b
1Department of Chemistry Education, Faculty of Teacher Training and Education, Universitas Sebelas Maret, Surakarta, Indonesia.
The advantages of alginate as a basic ingredient for edible coatings are safe for consumption, has a unique colloidal structure, stabilizer, binder, suspending agent, gelling agent, and emulsion stability [8].
This is the main characteristic of the starch structure of jackfruit seeds.
There is a difference in the diameter of the resulting inhibition zone due to differences in the structure of the cell wall between the two bacteria.
S. aureus bacteria have a cell wall structure with low lipid content which is more easily penetrated by antibacterial compounds than E. coli bacteria which have a more complex wall structure.
The advantages of alginate as a basic ingredient for edible coatings are safe for consumption, has a unique colloidal structure, stabilizer, binder, suspending agent, gelling agent, and emulsion stability [8].
This is the main characteristic of the starch structure of jackfruit seeds.
There is a difference in the diameter of the resulting inhibition zone due to differences in the structure of the cell wall between the two bacteria.
S. aureus bacteria have a cell wall structure with low lipid content which is more easily penetrated by antibacterial compounds than E. coli bacteria which have a more complex wall structure.
Online since: December 2013
Authors: Denis V. Kuznetsov, Alexander A. Gusev, Anna Yu. Godymchuk, Elizaveta Karepina
Herewith, the literature data state high toxicity of nanosized aluminum particles (depression of pulmonary function, inflammation of the respiratory tract [16], neuronal cell death [17], distortion of the structure of blood vessels [18] and damage to the structure of the brain [19, 20]).
Product drying in the air does not provide their full dehydration, and gibbsite phase formation aligns with the investigation data [34], according to which low heating of “nanoaluminum-water” system may give rise to porous oxide/hydroxide structures, where aluminum hydroxide of the described morphology is formed.
Though, it can be suggested that the gibbsite formed may have an amorphous structure which requires further investigation.
Il’in, Formation of porous structure of the oxide-hydroxide of aluminum in the interaction of aluminum nanopowders with water, Phys.
Chan, The effect of nanoparticle size, shape, and surface chemistry on biological systems, Annu.
Product drying in the air does not provide their full dehydration, and gibbsite phase formation aligns with the investigation data [34], according to which low heating of “nanoaluminum-water” system may give rise to porous oxide/hydroxide structures, where aluminum hydroxide of the described morphology is formed.
Though, it can be suggested that the gibbsite formed may have an amorphous structure which requires further investigation.
Il’in, Formation of porous structure of the oxide-hydroxide of aluminum in the interaction of aluminum nanopowders with water, Phys.
Chan, The effect of nanoparticle size, shape, and surface chemistry on biological systems, Annu.
Online since: July 2006
Authors: B. Bonnetot, A. Gervasini, A. Auroux, G. Postole
., UMR 5615, UCB Lyon 1, 69622 Villeurbanne Cedex, France.
4
Institute of Physical Chemistry of the Romanian Academy, Spl.
Introduction The catalytic activity and selectivity of metal supported catalysts are well known to depend strongly upon the dispersion, loading and the local structure of metal additives.
The crystalline structure was examined by X-ray diffraction using a Bruker (Siemens) D5005 apparatus.
The differences in surface area can easily be related to the BN structure.
The hexagonal BN crystallographic structure consists of three BN groups stacked into a hexagonal framework leading to BN layers as described for graphite.
Introduction The catalytic activity and selectivity of metal supported catalysts are well known to depend strongly upon the dispersion, loading and the local structure of metal additives.
The crystalline structure was examined by X-ray diffraction using a Bruker (Siemens) D5005 apparatus.
The differences in surface area can easily be related to the BN structure.
The hexagonal BN crystallographic structure consists of three BN groups stacked into a hexagonal framework leading to BN layers as described for graphite.
Online since: June 2004
Authors: P. Pirouz, Robert S. Okojie, Sergey P. Tumakha, Leonard J. Brillson, M. Zhang
These localized states form not only as a result of interface chemical bonding but also
due to the formation of new local structures/polytypes.
Rather this corresponds to a new local structure/polytype with a larger band gap.
Depth-resolved LEEN spectra of oxides on SiC reveal additional states that depend sensitively on the local interface chemistry.
The lowest thickness is most common and corresponds to a single stacking fault in the 4H-SiC lattice structure.
Brillson, "Surfaces and Interfaces: Atomic-Scale Structure, Band Bending and Band Offsets", in Handbook on Semiconductors, Vol. 1, edited by P.
Rather this corresponds to a new local structure/polytype with a larger band gap.
Depth-resolved LEEN spectra of oxides on SiC reveal additional states that depend sensitively on the local interface chemistry.
The lowest thickness is most common and corresponds to a single stacking fault in the 4H-SiC lattice structure.
Brillson, "Surfaces and Interfaces: Atomic-Scale Structure, Band Bending and Band Offsets", in Handbook on Semiconductors, Vol. 1, edited by P.