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Online since: March 2016
Authors: Jian Guo Gao, Jian Gao, Shu Zhen Pan, Xiao Yun Song, Shu Li Zhang, Lun Hua Yang, Hui Liu, Zhuo Jun Sun
., Qingdao 266031, China.
2University of California, Berkeley, B.A. 2700 Hearst Avenue, Stern Hall, Room 337A, Berkeley, CA 94720, U.S.A.
3Qingdao Entry-Exit Inspection and Quarantine Bureau, Qingdao 266001, China
4College of Chemistry and Chemical Engineering,Shandong University of Science and Technology,Qingdao 266590,China,
asunzhuojun66@163.com, bjessica_gao@berkeley.edu, c15069553514@126.com, dpsz_xiaoyu@163.com, ezhangshuli1002@163.com, fyanglunhua@dpsc.cn, gsxy854234635@163.com, hchina.gjg@163.com,
Keywords: Bisphenol A, Gas chromatography - mass spectrometry, Release, Kinetics of thermal decomposition.
In addition, more branched and cross-linked structures are detected in the air, which indicates that the oxygen in the air promotes the formation of the chain and the chain structure.
Between 120~168 h, due to the aging condition of polycarbonate deepens, it may appeared that a small amount of the crosslinking structure of the thermal stability of the polycarbonate and increase oxygen absorbed is reduced, below aging polycarbonate.
Aging phenomenon of the second phase of the reason may be: hot weightlessness in the second stage, aging time after 120 h, polycarbonate surface of the sample may be crosslinked structure, make the polycarbonate thermal degradation rate slows, the degradation temperature to high temperature direction.
In addition, more branched and cross-linked structures are detected in the air, which indicates that the oxygen in the air promotes the formation of the chain and the chain structure.
Between 120~168 h, due to the aging condition of polycarbonate deepens, it may appeared that a small amount of the crosslinking structure of the thermal stability of the polycarbonate and increase oxygen absorbed is reduced, below aging polycarbonate.
Aging phenomenon of the second phase of the reason may be: hot weightlessness in the second stage, aging time after 120 h, polycarbonate surface of the sample may be crosslinked structure, make the polycarbonate thermal degradation rate slows, the degradation temperature to high temperature direction.
Online since: November 2019
Authors: Kamrun N. Keya, Alamgir Habib, Sampa Akhter, Hasan M. Tamim, Maksuda Akhter
But with high rise buildings comes the new challenge of providing high-performance structures.
Other disadvantages, which directly affect the durability of the structures, are high porosity, insignificant tensile strength, poor adhesion to old structures, high permeability and poor chemical resistance to acid and salts of the conventional Portland cement concrete and mortar.
In Bangladesh, the polymer is recently used for repair works of important structures.
Belgacem, Furans in polymer chemistry, Progress in Polymer Science, 22(6), (1997) 1203–1379
Other disadvantages, which directly affect the durability of the structures, are high porosity, insignificant tensile strength, poor adhesion to old structures, high permeability and poor chemical resistance to acid and salts of the conventional Portland cement concrete and mortar.
In Bangladesh, the polymer is recently used for repair works of important structures.
Belgacem, Furans in polymer chemistry, Progress in Polymer Science, 22(6), (1997) 1203–1379
Online since: August 2016
Authors: Petr Lenfeld, Martin Boruvka, Jiří Habr, Luboš Bĕhálek, Chakaphan Ngaowthong
Their lignocellulosic structure contains strongly polarized hydroxyl groups which lowers the compatibility with hydrophobic polymeric matrix during composite processing.
It negatively influencing not only the structure change and material properties but also shape and dimensional instabilities of injected parts.
At Figure 6 (left) it is clearly visible that multicellular structure of short PALF has been damaged.
Youngblood, Cellulose nanomaterials review: structure, properties and nanocomposites, Chem.
Kaur, Cellulose fibers: bio-and nano-polymer composites: green chemistry and technology, Springer, 2011
It negatively influencing not only the structure change and material properties but also shape and dimensional instabilities of injected parts.
At Figure 6 (left) it is clearly visible that multicellular structure of short PALF has been damaged.
Youngblood, Cellulose nanomaterials review: structure, properties and nanocomposites, Chem.
Kaur, Cellulose fibers: bio-and nano-polymer composites: green chemistry and technology, Springer, 2011
Online since: November 2016
Authors: Priscilla Gloria Lorraine Baker, Xolani Terrance Ngema, Emmanuel Iheanyichukwu Iwuoha, Siyabulela Hamnca, Meryk Ward
But for metal ions with mixed redox states (in solution or in the solid phase), metal complexes or organic structures, the matter of a charge-transfer reaction is more complex, and a conclusion of some intermediate states, like radicals from the number of transferred electrons, ends up in speculation [30].
Electrochemical characterization of GCE/PAA in 0.1 M PBS (pH7) Table. 1 Electrochemical parameters of PAA Material Epa1 (mV) Epa2 (mV) Epc1 (mV) Epc2 (mV) GCE/PAA 119 295 205 -115 ITO/PAA 204 683 150 -135 The peak (Epa1) at 204 mV from the ITO/PAA electrode was due to the removal of one electron from nitrogen atoms at the tetraphenyl-1,4-phenylenediamine structure in each repeating unit to yield one stable delocalised radical cation, poly(amine-amide)+ and the peak (Epa2) at 683 mV was due to one stable quinoid type dication poly(amine-amide)2+.
Hence UV/vis spectroscopy and voltammetry confirm the formation of stable electrodeposited PAA films on the ITO electrode. 4.3.3 UV/vis Spectro-electrochemistry of PAA thin films on ITO Electrode The electronic structure of the conjugated polymers is not only important in the description of the electrical properties, but it also determines their optical properties.
These Absmax values at 200 mV are associated with the removal of an electron from nitrogen atoms at the tetraphenyl-1,4-phenylenediamine structure in each repeating unit to yield a stable delocalised radical cation, poly(amine-amide)+.
Colmsjo A.H.N The handbook of environmental chemistry part 1, PAHs and related compounds.
Electrochemical characterization of GCE/PAA in 0.1 M PBS (pH7) Table. 1 Electrochemical parameters of PAA Material Epa1 (mV) Epa2 (mV) Epc1 (mV) Epc2 (mV) GCE/PAA 119 295 205 -115 ITO/PAA 204 683 150 -135 The peak (Epa1) at 204 mV from the ITO/PAA electrode was due to the removal of one electron from nitrogen atoms at the tetraphenyl-1,4-phenylenediamine structure in each repeating unit to yield one stable delocalised radical cation, poly(amine-amide)+ and the peak (Epa2) at 683 mV was due to one stable quinoid type dication poly(amine-amide)2+.
Hence UV/vis spectroscopy and voltammetry confirm the formation of stable electrodeposited PAA films on the ITO electrode. 4.3.3 UV/vis Spectro-electrochemistry of PAA thin films on ITO Electrode The electronic structure of the conjugated polymers is not only important in the description of the electrical properties, but it also determines their optical properties.
These Absmax values at 200 mV are associated with the removal of an electron from nitrogen atoms at the tetraphenyl-1,4-phenylenediamine structure in each repeating unit to yield a stable delocalised radical cation, poly(amine-amide)+.
Colmsjo A.H.N The handbook of environmental chemistry part 1, PAHs and related compounds.
Online since: October 2013
Authors: Baraneedharan Pari, Nehru Kasi, Sivakumar Muthusamy, Siva Chidambaram
Hierarchical structured SnO2 based photo anode
The oriented attachment of one dimensional SnO2 nanostructures though promotes faster electron transport and slower recombination rate is inferior to hierarchical structured photo anode.
TiO2 or Al2O3 layer deposited using above SnO2 structures [37].
The hierarchical structures have compactly packed microstructures and poly dispersed aggregates with nanosized crystallites.
Zn-Sn-O nanocactus structure composed of Zn2SnO4 plate and Zn doped SnO2 nanothrons both of which posses higher electron mobility.
Sunkara, Band edge engineered hybrid structures for dye sensitized solar cells based on SnO2 nanowires, Adv.
TiO2 or Al2O3 layer deposited using above SnO2 structures [37].
The hierarchical structures have compactly packed microstructures and poly dispersed aggregates with nanosized crystallites.
Zn-Sn-O nanocactus structure composed of Zn2SnO4 plate and Zn doped SnO2 nanothrons both of which posses higher electron mobility.
Sunkara, Band edge engineered hybrid structures for dye sensitized solar cells based on SnO2 nanowires, Adv.
Online since: November 2018
Authors: Getahun Aklilu, Sarp Adali, Glen Bright
It may affect the performance of the advanced composite blade structures during service.
Researchers carried out extensive study on the behaviour of fiber/matrix interface on variable temperature on FRP composite structures.
Many researchers were explored containing a detail an experimental investigation to measure the adhesion between fibre and matrix to determine the interfacial chemistry and material behaviour known qualitatively that poor adhesion usually meant that composite properties were poor as well consequently lesser interlaminar shear failure strength.
Stang, Structural testing and numerical simulation of a 34m composite wind turbine blade, Composite Structures, 76 (2006) 52-61
Verijenko, Minimum cost design of hybrid composite cylinders with temperature dependent properties. composite structures, Composite Structures, 38 (1997) 623-630
Researchers carried out extensive study on the behaviour of fiber/matrix interface on variable temperature on FRP composite structures.
Many researchers were explored containing a detail an experimental investigation to measure the adhesion between fibre and matrix to determine the interfacial chemistry and material behaviour known qualitatively that poor adhesion usually meant that composite properties were poor as well consequently lesser interlaminar shear failure strength.
Stang, Structural testing and numerical simulation of a 34m composite wind turbine blade, Composite Structures, 76 (2006) 52-61
Verijenko, Minimum cost design of hybrid composite cylinders with temperature dependent properties. composite structures, Composite Structures, 38 (1997) 623-630
Online since: May 2023
Authors: Xiao Wen Qi, Bing Li Fan, Zheng Jie Li, Yi Wei Guo, Chang Xin Liu, An Nan Sun
Because MoS2 has a layered structure similar to graphite, the series of lubricating oil additives containing metal molybdenum synthesized by physical and chemical reactions also have good lubricating performance [12].
With its unique metastable structure, silicate mineral particles can significantly improve the lubrication performance of base oil and effectively reduce friction and wear as lubricating oil additives.
Surface energy spectrum of lubricating oil samples with different additives after friction test Based on the composition and structure characteristics of the self-developed polymer-based lubricating oil additive, combined with the analysis results of wear surface morphology and element content, the antifriction and self-repair mechanism of the self-developed polymer-based lubricating oil additive is as follows: BN has a lamellar structure similar to graphene, B-N in the same layer is mainly connected by covalent bond, B-N between different layers is connected by van der Waals force, during friction, part of BN and ALN enter the surface of friction sample for micro-polishing and self-repair, and the other part of BN undergoes interlaminar shear slip under the joint action of shear force and average load, and covers the surface of friction sample through a series of physical and chemical reactions.
Journal of Physics and Chemistry of Solids, 2021, 156: 110172
With its unique metastable structure, silicate mineral particles can significantly improve the lubrication performance of base oil and effectively reduce friction and wear as lubricating oil additives.
Surface energy spectrum of lubricating oil samples with different additives after friction test Based on the composition and structure characteristics of the self-developed polymer-based lubricating oil additive, combined with the analysis results of wear surface morphology and element content, the antifriction and self-repair mechanism of the self-developed polymer-based lubricating oil additive is as follows: BN has a lamellar structure similar to graphene, B-N in the same layer is mainly connected by covalent bond, B-N between different layers is connected by van der Waals force, during friction, part of BN and ALN enter the surface of friction sample for micro-polishing and self-repair, and the other part of BN undergoes interlaminar shear slip under the joint action of shear force and average load, and covers the surface of friction sample through a series of physical and chemical reactions.
Journal of Physics and Chemistry of Solids, 2021, 156: 110172
Online since: November 2019
Authors: Mamoun Fellah, Abdelyamine Boukhobza, Mohamed Bouleghlem, Moussa Zahzouh, Mohamed Hamidouche
It is preferable to introduce TiC in the form of WC/TiC solid solution [4,5].The WC-TiC-Co grades have two distinct carbides in the microstructure, prismatic crystals of almost pure WC and rounded (W,Ti)C mixed crystals with core–rim structure, consisting of TiC core phase and (Ti,W)C rim phase because of differential diffusion effects [4,6].
The results of EDS analysis of sintered alloy, as shown in Fig.4 (a)-(f) and fig.5, clearly reveal that the (W,Ti)C grain have a rounded morphology, called γ phase show a core–rim structure with the core (blue area) having the composition of (Ti, W)C with higher amount of Ti and lower amount of W (12,20 at.% tungsten vs. 33,97 at.% titanium (Fig.6 (c)) while the rim show a higher amount of W and lower amount of Ti (yellow area (18,08 at.% tungsten vs. 24,55 at.% titanium (Fig.6(d)) and orange area (22,54 at.% tungsten vs. 4,84 at.% titanium (Fig.6 (a)).
Which is a little superior to that found by Jan Dutkiewicz1 et al [20] which have studied the effect of TiC on structure and hardness of WC-Co cemented carbides; and they found that the fracture toughness KIc was in the range of 10.9-11.2 MPam1/2 for the samples containing 0-10% TiC.
References [1] Jonathan Weidow, Effect of metal and cubic carbide additions on interface chemistry, phase composition and grain growth in WC-Co based cemented carbides (Phd Thesis), CHALMERS University of Technology, Sweden (2010)
[20] Dutkiewicz, J., Szutkowska, M., Leśniewski, W., Wieliczko, P., & Pieczara, A.The effect of TiC on structure and hardness of WC-Co composites prepared using various consolidation methods.
The results of EDS analysis of sintered alloy, as shown in Fig.4 (a)-(f) and fig.5, clearly reveal that the (W,Ti)C grain have a rounded morphology, called γ phase show a core–rim structure with the core (blue area) having the composition of (Ti, W)C with higher amount of Ti and lower amount of W (12,20 at.% tungsten vs. 33,97 at.% titanium (Fig.6 (c)) while the rim show a higher amount of W and lower amount of Ti (yellow area (18,08 at.% tungsten vs. 24,55 at.% titanium (Fig.6(d)) and orange area (22,54 at.% tungsten vs. 4,84 at.% titanium (Fig.6 (a)).
Which is a little superior to that found by Jan Dutkiewicz1 et al [20] which have studied the effect of TiC on structure and hardness of WC-Co cemented carbides; and they found that the fracture toughness KIc was in the range of 10.9-11.2 MPam1/2 for the samples containing 0-10% TiC.
References [1] Jonathan Weidow, Effect of metal and cubic carbide additions on interface chemistry, phase composition and grain growth in WC-Co based cemented carbides (Phd Thesis), CHALMERS University of Technology, Sweden (2010)
[20] Dutkiewicz, J., Szutkowska, M., Leśniewski, W., Wieliczko, P., & Pieczara, A.The effect of TiC on structure and hardness of WC-Co composites prepared using various consolidation methods.
Online since: May 2014
Authors: Antonio Contreras-Cuevas, Ricardo Galván-Martínez, Luis M. Quej-Aké, J. Marín-Cruz
Actually, the concern with the environment is very important and a better understanding of the soil as a corrosive agent becomes necessary to use more adequate protection for buried structures.
Soil properties depend of soil particle size distribution, organic content, mineralogical composition and structure.
The advantage of these methods is that it is possible to obtain physico-chemical data in coated underground metallic structures.
Low carbon steels tend to have a ferrite–pearlite structure containing little pearlite in the grain boundaries mainly.
Sparks, Environmental Soil Chemistry.
Soil properties depend of soil particle size distribution, organic content, mineralogical composition and structure.
The advantage of these methods is that it is possible to obtain physico-chemical data in coated underground metallic structures.
Low carbon steels tend to have a ferrite–pearlite structure containing little pearlite in the grain boundaries mainly.
Sparks, Environmental Soil Chemistry.
Online since: September 2018
Authors: Arshad Bashir, Fahd Jamshaid, Muhammad Adrees, Muhammad Yasir, Sajid Rasheed Ahmad, Adnan Ahmad, Faiza Hassan, Waheed Gull Khan, Sadia Sagar Iqbal
Tuning of Thermo-Mechanical Performance: Modified Multiwalled Carbon Nanotubes Reinforced SBR/NBR/SR Nanocomposites
SADIA Sagar Iqbal1,a,*, MUHAMMAD Adrees1b, ADNAN Ahmad1c,
FAIZA Hassan2d, MUHAMMAD Yasir3e, ARSHAD Bashir4f,
SAJID Rashid Ahmad5g, FAHAD Jamshad1h, WAHEED Gul Khan4i
1Department of Polymer Engineering & Technology, CEET,
University of the Punjab, Lahore, Pakistan
2Department of Chemistry, University of the Lahore, Pakistan
3Institute of Space Technology, Islamabad, Pakistan
4Institute of Industrial Control System, P.O.
Fig. 2b reveals the diffraction peaks at 23.71 and 42.21degree referring to the graphite structure derived from MWCNTs.
Another reason of hardness improvement is the decrease of the polymeric chain mobility with the addition of F-MWCNTs in the elastomeric matrices as additional crosslinking and bridging is introduced in the composite structure due to the presence of functional nanotubes bridge among the host polymer matrix chain [8, 15, 16].
· Molecular structural study of the treated/untreated MWCNTs illustrates the graphitic structure confirmation and preservation even after the functional group attachment with the nanotubes
Somoza, A study about the structure of vulcanized natural rubber/styrene butadiene rubber blends and the glass transition behavior, J Appl Polym Sci., 125 (2012) 992-999
Fig. 2b reveals the diffraction peaks at 23.71 and 42.21degree referring to the graphite structure derived from MWCNTs.
Another reason of hardness improvement is the decrease of the polymeric chain mobility with the addition of F-MWCNTs in the elastomeric matrices as additional crosslinking and bridging is introduced in the composite structure due to the presence of functional nanotubes bridge among the host polymer matrix chain [8, 15, 16].
· Molecular structural study of the treated/untreated MWCNTs illustrates the graphitic structure confirmation and preservation even after the functional group attachment with the nanotubes
Somoza, A study about the structure of vulcanized natural rubber/styrene butadiene rubber blends and the glass transition behavior, J Appl Polym Sci., 125 (2012) 992-999