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Online since: August 2020
Authors: Ekaterina Borisovna Markova, Alexander Genrihovich Cherednichenko, V.V. Kurilkin, J.M. Serov
Morphology of the structures of gadolinium zirconate.
Study of the structure of powders.
In the second case, the synthesis is carried out to form an ordered structure.
Kurilkin Features of Propane Conversion in the Presence of SmVO3 and SmVO4 // Russian Journal of Physical Chemistry A, 2016, V. 90, No. 9, P. 1754–1759 [2] Gurav H.R., Dama S., Samuel V., Chilukuri S.
Chemistry and Physics of Carbon // Marcel Dekker.
Study of the structure of powders.
In the second case, the synthesis is carried out to form an ordered structure.
Kurilkin Features of Propane Conversion in the Presence of SmVO3 and SmVO4 // Russian Journal of Physical Chemistry A, 2016, V. 90, No. 9, P. 1754–1759 [2] Gurav H.R., Dama S., Samuel V., Chilukuri S.
Chemistry and Physics of Carbon // Marcel Dekker.
Online since: February 2012
Authors: Li Wang, Cong Liu, Yi Zhang
Surfactants with special molecule structures and properties play a key role in reverse micelle.
The relationship between the P value of surfactants and structure of the reverse micelle From the obtained results, it was confirmed that when P was less than 1.35, layer structure reverse micelle formed, which made CaSO4 present nanometer flakes; when P ranged from about 1.4 to 2.5, clavate structure reverse micelle was formed, which made CaSO4 present nanometer rods; when P was greater than 3.4, spherical structure reverse micelle was formed, which made CaSO4 present nanometer spheres.
(2) When P was less than 1.35, layer structure reverse micelle was formed, but when P ranged from about 1.4 to 2.5 or greater than 3.4, clavate structure or spherical structure reverse micelle was formed respectively
Yu: Materials Chemistry.
[8] Haicheng Zhou, Jian Xu, Sheng Xu and Yadong Li: Journal of Inorganic Chemistry.
The relationship between the P value of surfactants and structure of the reverse micelle From the obtained results, it was confirmed that when P was less than 1.35, layer structure reverse micelle formed, which made CaSO4 present nanometer flakes; when P ranged from about 1.4 to 2.5, clavate structure reverse micelle was formed, which made CaSO4 present nanometer rods; when P was greater than 3.4, spherical structure reverse micelle was formed, which made CaSO4 present nanometer spheres.
(2) When P was less than 1.35, layer structure reverse micelle was formed, but when P ranged from about 1.4 to 2.5 or greater than 3.4, clavate structure or spherical structure reverse micelle was formed respectively
Yu: Materials Chemistry.
[8] Haicheng Zhou, Jian Xu, Sheng Xu and Yadong Li: Journal of Inorganic Chemistry.
Online since: July 2011
Authors: Sheng Sun, Pun Jun Jin
Silicone usually refers to linear polymers with the following structure:
Fig. 1 silicone structure
The R groups along the chain where = Methyl or PDMS can be substituted by many other groups.
Silicone polymers do not have carbon as part of the backbone structure.
Although the silicon is in the same group as carbon in the periodic table, it has quite different chemistry.
Silicone polymers have an alternating -Si-O- type structure.
The most prominent factors affecting these structures are the environment, pollution, and tourism.
Silicone polymers do not have carbon as part of the backbone structure.
Although the silicon is in the same group as carbon in the periodic table, it has quite different chemistry.
Silicone polymers have an alternating -Si-O- type structure.
The most prominent factors affecting these structures are the environment, pollution, and tourism.
Online since: April 2009
Authors: Daryoush Emadi, Mahi Sahoo, Maria Aniolek, W. Kasprzak
Selected structure analysis results including XRD and TEM/EDX as well as
elevated temperature tensile testing are presented.
Consequently, the 356 and 319 chemistries can not maintain their properties at highly stressed areas and temperatures reaching up to 250o C [1-4].
To meet such requirements proper development of alloy chemistry and heat treatment processing is needed [5].
Experimental Procedures Two primary Al-Si-Cu base alloys were selected from about 30 chemistries studied so far.
This was done to determine the effects of alloy chemistry and processing parameters on structure development.
Consequently, the 356 and 319 chemistries can not maintain their properties at highly stressed areas and temperatures reaching up to 250o C [1-4].
To meet such requirements proper development of alloy chemistry and heat treatment processing is needed [5].
Experimental Procedures Two primary Al-Si-Cu base alloys were selected from about 30 chemistries studied so far.
This was done to determine the effects of alloy chemistry and processing parameters on structure development.
Online since: October 2007
Authors: Fei Li, Peng Fei Ren, Hong Dan Zhang, Xiao Ping Zou, Jin Cheng, Mao Fa Wang, Guang Zhu
Raman spectroscopy was used for structure analysis of CNFs synthesized by catalytic combustion
technique.
Figure 4 shows a strong D peak and a weak G peak, indicating relatively small size graphite clusters within the CNF structure.
Raman spectrum of typical sample produced by using 1mol/l ferric chloride as the catalyst precursor over copper plate. higher than the D band, indicating relatively large size graphite clusters within the CNF structure.
Meng of Technical Institute of Physics and Chemistry of CAS for the aid in SEM analysis and F.
Holmen: Materials chemistry and physics Vol. 92 (2005), p. 71 [6] E.
Figure 4 shows a strong D peak and a weak G peak, indicating relatively small size graphite clusters within the CNF structure.
Raman spectrum of typical sample produced by using 1mol/l ferric chloride as the catalyst precursor over copper plate. higher than the D band, indicating relatively large size graphite clusters within the CNF structure.
Meng of Technical Institute of Physics and Chemistry of CAS for the aid in SEM analysis and F.
Holmen: Materials chemistry and physics Vol. 92 (2005), p. 71 [6] E.
Online since: October 2008
Authors: Rudi Cloots, Marcel Ausloos, Tatyana Koutzarova, Svetoslav Kolev, Kornely Grigoriev Grigorov, Chavdar Ghelev, Ivan Nedkov, Tadeusz Mydlarz, Andrzej Zaleski
The most common method of synthesis of nano-sized powders is by the use of a "wet
chemistry" process.
The reverse microemulsion system exhibits a dynamic structure of nanosized aqueous droplets which are in constant formation, breakdown, and coalescence.
The diffractograms of the two samples correspond to the barium hexaferrite structure, except for the additional minor peaks corresponding to haematite in the case of mE-I.
The particles in sample mE-I were predominantly of a platelet-like structure with an irregular shape and an average size of 180 nm.
It should be pointed out that the magnetic parameters of sample mE-IІ are comparable to those of powders produced by other "wet chemistry" techniques.
The reverse microemulsion system exhibits a dynamic structure of nanosized aqueous droplets which are in constant formation, breakdown, and coalescence.
The diffractograms of the two samples correspond to the barium hexaferrite structure, except for the additional minor peaks corresponding to haematite in the case of mE-I.
The particles in sample mE-I were predominantly of a platelet-like structure with an irregular shape and an average size of 180 nm.
It should be pointed out that the magnetic parameters of sample mE-IІ are comparable to those of powders produced by other "wet chemistry" techniques.
Online since: January 2015
Authors: Ya Hui Zhang, Xi Cheng, Qing Wang
Indium selenide (In2Se3) is an important narrow band gap III-V semiconducting material with a layered crystal structure.
Among them, hydrothermal or solvethermal method is regarded as a very effective and potential soft-chemistry route to tune the architectures of metal selenide.
Weon-kyu Koh et al[7] studied the role of different Se precursors for PbSe nanorod synthesis, focusing on phosphine chemistry to understand precursor decomposition (Figure 1c).
Prospects Metal selenide nanostructures have novel properties and functions corresponding to their unique structures.
Sen, The Journal of Physical Chemistry B Vol. 118 (2014), p. 2284 [2] Z.
Among them, hydrothermal or solvethermal method is regarded as a very effective and potential soft-chemistry route to tune the architectures of metal selenide.
Weon-kyu Koh et al[7] studied the role of different Se precursors for PbSe nanorod synthesis, focusing on phosphine chemistry to understand precursor decomposition (Figure 1c).
Prospects Metal selenide nanostructures have novel properties and functions corresponding to their unique structures.
Sen, The Journal of Physical Chemistry B Vol. 118 (2014), p. 2284 [2] Z.
Online since: September 2013
Authors: Lei Zhang, Xiang Dong Di, Hong Bao Liang, Ying Chen, Xiao Na Dong
Provincial Key Laboratory of Oil & Gas Chemical Technology, College of Chemistry & Chemical Engineering,Northeast Petroleum University,Daqing 163318, China;
3.
This is because the different interaction between crude oil components (asphaltenes ,resins ,aromatics and saturated hydrocarbons)and rock and different displacement solution of different displacement ability make the content of asphaltenes and resins in produced crude oil different.The interaction between unsaturated hydrocarbon polarity and rock is mainly VDW(lesser),adsorption viscosity on rock surface is small,so it is easy to be out;aromatic hydrocarbon with weak polarity and have benzene ring structure so that the interaction among the rock expect VDW is the coordination bond with the bigger interaction formed byπbond and the cation on the rock surface ,the interaction between the bigger coordinate and the rock is bigger than saturated hydrocarbons,therefore,the adsorption viscosity on the rock surface is bigger than saturated hydrocarbons,make it hard displacement compared with the saturated hydrocarbons;Asphaltenes and resins have polycyclic aromatic hydrocarbons.The interaction
increase of asphaltenes content,more and more asphaltenes gathered on the oil-water interface,the strength of the film increased gradually,the emulsion stability increased,but when concentration of asphaltenes increased to its critical concentration,because of the special structure of asphaltenes[4],it is easy to form hydrogen bond and aromatic sheet easy accumulation form a larger micelle aggregates between molecule,causing the oil - water interface asphaltenes concentration decreased and the emulsion stability decreased.For the resins,with the increase of resins content,dehydration rate gradually decreased.Because it is difficult for resins to form micellar aggregates,with the development of oil - water interface resins concentration increased,the strength of the film increased,stability gradually increased.
[4] Wang Z J,The chemistry and physics of the petroleum asphaltenes ⅡThe structure and chemical composition of the asphaltenes [J].
The viscosity of the polymer flooding produced water [J].Oilfild chemistry. 1998,15(4):336-339.
This is because the different interaction between crude oil components (asphaltenes ,resins ,aromatics and saturated hydrocarbons)and rock and different displacement solution of different displacement ability make the content of asphaltenes and resins in produced crude oil different.The interaction between unsaturated hydrocarbon polarity and rock is mainly VDW(lesser),adsorption viscosity on rock surface is small,so it is easy to be out;aromatic hydrocarbon with weak polarity and have benzene ring structure so that the interaction among the rock expect VDW is the coordination bond with the bigger interaction formed byπbond and the cation on the rock surface ,the interaction between the bigger coordinate and the rock is bigger than saturated hydrocarbons,therefore,the adsorption viscosity on the rock surface is bigger than saturated hydrocarbons,make it hard displacement compared with the saturated hydrocarbons;Asphaltenes and resins have polycyclic aromatic hydrocarbons.The interaction
increase of asphaltenes content,more and more asphaltenes gathered on the oil-water interface,the strength of the film increased gradually,the emulsion stability increased,but when concentration of asphaltenes increased to its critical concentration,because of the special structure of asphaltenes[4],it is easy to form hydrogen bond and aromatic sheet easy accumulation form a larger micelle aggregates between molecule,causing the oil - water interface asphaltenes concentration decreased and the emulsion stability decreased.For the resins,with the increase of resins content,dehydration rate gradually decreased.Because it is difficult for resins to form micellar aggregates,with the development of oil - water interface resins concentration increased,the strength of the film increased,stability gradually increased.
[4] Wang Z J,The chemistry and physics of the petroleum asphaltenes ⅡThe structure and chemical composition of the asphaltenes [J].
The viscosity of the polymer flooding produced water [J].Oilfild chemistry. 1998,15(4):336-339.
Online since: October 2014
Authors: Yu Ming Zhou, Wei Sun, Hu Chuan Wang
Performance of an maleic anhydride based polymers as scale inhibitor and Iron (III) scaling in industrial cooling water systems
Huchuan Wang 1, a, Yuming Zhou 2, b*, Wei Sun 3, c
1 School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, P.
China 2 School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, P.
Structures of APEG, APEM, and MA-APEM were identified by FT-IR.
Preparation of MA-APEM Inhibition Test [11] RESULTS AND DISCUSSION Structure Analysis of the Copolymer The FTIR spectra of APEG (a), APEM (b), and MA-APEM (c) were shown in Fig. 3.
China 2 School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, P.
Structures of APEG, APEM, and MA-APEM were identified by FT-IR.
Preparation of MA-APEM Inhibition Test [11] RESULTS AND DISCUSSION Structure Analysis of the Copolymer The FTIR spectra of APEG (a), APEM (b), and MA-APEM (c) were shown in Fig. 3.
Online since: July 2011
Authors: Shu Jun Li, Shuang Yue Li, Li Jun Zhang, Tao Liang
The chemical structure of the product as a rosin amide derivative was identified by Fourier transform infrared spectroscopy (FTIR) and liquid chromatography-mass spectrometry (LC-MS) method.
The structure and purity of N-(3-rosin acyloxy-2-hydroxyl) propyl-N,N diethanolamine were characterized by FTIR and LC-MS methods.
References [1] Li Jihui, Ha Chengyong, Progress on the Study of Rosin Modifications, Nature Product Research and Development, Vol. 15(2003), p.552-558 [2] Cao Qifeng, Song Wensheng, Summarization of Research on Rosin Modification, Guangzhou Chemical Industry, Vol. 35(2007), p.10-13 [3] Liu Qing, Problem and Counter Measure in the Development of Chinese Rosin Industry,Chemistry and Industry of Forest Products, Vol. 38(2004), p.36-39 [4] Hao Qiang, Ha Chengyong, Development of Research on Catalytic Esterification of Rosin, Chemistry and Industry of Forest Products, Vol. 20(2000), p.80-86 [5] Liang Menglan, Ye Jianfeng, Synthesis and Performances of Quaternary Ammonium Cationic Surfactants with Dehydroabietyl Group, Chemical World, (2000), p.138-141 [6] Jiao Xueshun, Synthesis and Properties of Amphoteric Surfactant──N-(3-Dodecyloxy-2- Hydroxy)Propyl-N, N-Dimethyl Betaine, surfactant industry, (1999) [J].p.16~19 [7] Jian Li, Shuangyue Li, Shujun Li, Jing Wang and Dan Liu.
The structure and purity of N-(3-rosin acyloxy-2-hydroxyl) propyl-N,N diethanolamine were characterized by FTIR and LC-MS methods.
References [1] Li Jihui, Ha Chengyong, Progress on the Study of Rosin Modifications, Nature Product Research and Development, Vol. 15(2003), p.552-558 [2] Cao Qifeng, Song Wensheng, Summarization of Research on Rosin Modification, Guangzhou Chemical Industry, Vol. 35(2007), p.10-13 [3] Liu Qing, Problem and Counter Measure in the Development of Chinese Rosin Industry,Chemistry and Industry of Forest Products, Vol. 38(2004), p.36-39 [4] Hao Qiang, Ha Chengyong, Development of Research on Catalytic Esterification of Rosin, Chemistry and Industry of Forest Products, Vol. 20(2000), p.80-86 [5] Liang Menglan, Ye Jianfeng, Synthesis and Performances of Quaternary Ammonium Cationic Surfactants with Dehydroabietyl Group, Chemical World, (2000), p.138-141 [6] Jiao Xueshun, Synthesis and Properties of Amphoteric Surfactant──N-(3-Dodecyloxy-2- Hydroxy)Propyl-N, N-Dimethyl Betaine, surfactant industry, (1999) [J].p.16~19 [7] Jian Li, Shuangyue Li, Shujun Li, Jing Wang and Dan Liu.