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Online since: July 2010
Authors: Michael Klink, Richard Akinyeye, Vernon Somerset, Mantoa Sekota, Priscilla Gloria Lorraine Baker, Emmanuel Iwuoha
Introduction
Tremendous advances have been made during the last two decades in our understanding of the
chemistry, structure, electrochemistry, electrical and optical properties, processing routes and
applications of conducting polymers of which polyanilines is the most widely exploited [1-16].
Conducting polymers are characterised by a conjugated structure of alternating single and double bonds.
Boyd: Organic Chemistry, 5th Edition (Allyn and Bacon Inc., USA 1987)
Sorrell: Organic Chemistry (University Science Books, California, USA 1999)
Vogel: Vogel's Text Book of Practical Organic Chemistry, 5th Edition (Wiley, New York 1989)
Conducting polymers are characterised by a conjugated structure of alternating single and double bonds.
Boyd: Organic Chemistry, 5th Edition (Allyn and Bacon Inc., USA 1987)
Sorrell: Organic Chemistry (University Science Books, California, USA 1999)
Vogel: Vogel's Text Book of Practical Organic Chemistry, 5th Edition (Wiley, New York 1989)
Online since: July 2012
Authors: Shou Lian Wei, Xiao Jun Guo, Yong Liu
China
2Faculty of Chemistry and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, P.R.
Ethylene glycol dimethacrylate (EGDMA), di-n-octyl phthalate (DOP), high molecular weight polyvinyl chloride (PVC) and theophylline were purchased from Aladdin Chemistry Co., Ltd.
It can be seen that the surface of the MIP exhibits a more porous and rough structure than NIP.
The regular structure of the non-imprinted polymer is due to the fact that no specific binding sites are created for the polymer.
The cavities in the MIP are probably caused by the structure of the target caffeine molecule.
Ethylene glycol dimethacrylate (EGDMA), di-n-octyl phthalate (DOP), high molecular weight polyvinyl chloride (PVC) and theophylline were purchased from Aladdin Chemistry Co., Ltd.
It can be seen that the surface of the MIP exhibits a more porous and rough structure than NIP.
The regular structure of the non-imprinted polymer is due to the fact that no specific binding sites are created for the polymer.
The cavities in the MIP are probably caused by the structure of the target caffeine molecule.
Online since: July 2016
Authors: Jiu Xin Jiang, Dong Dong Xu, Hui Yan Zeng, Zi Ling Yan, Meng Ran Jiao
However, dendrite–like aragonite and flower–like vaterite [16], rod–shape aragonite, hexagon vaterite and tube–shape vaterite formed by the rolling up of a pseudolayed structure [17], rod–like aragonite grains with high and low aspect ratios [13] have been obtained at 90°C or above temperature.
What should be note that some rod–like particles look more like the rolling structure of lamellar grains (arrowed in Fig. 3b and e), similar to Chen et al.’s research [17].
Considine, Encyclopedia of Chemistry, 4th ed.
Hou, Structure transition from aragonite to vaterite and calcite by the assistance of SDBS, J.
Mason, Sonochemistry: The Uses of Ultrasound in Chemistry, The Royal Society of Chemistry, Cambridge, 1990
What should be note that some rod–like particles look more like the rolling structure of lamellar grains (arrowed in Fig. 3b and e), similar to Chen et al.’s research [17].
Considine, Encyclopedia of Chemistry, 4th ed.
Hou, Structure transition from aragonite to vaterite and calcite by the assistance of SDBS, J.
Mason, Sonochemistry: The Uses of Ultrasound in Chemistry, The Royal Society of Chemistry, Cambridge, 1990
Online since: October 2019
Authors: Siriporn Pranee, Thanakit Sirimahasal, Lida Simasatitkul, Samitthichai Seeyangnok, Semih Durmus, Yutthana Kalhong
These are dissimilar in term of structure and morphology.
The absorption bands at 3200-3800 cm-1and 700-1800 cm-1 correspond respectively to –OH stretching and –OH bending of water molecules in calcium sulfate structure.
Role of ethylene glycol on the transformations of DH to α-HH The phase transformation of DH to α-HH has been investigated using Eq 1, The theory of crystal structure formation of α-HH are dissolution-recrystallization [14] as shown in Eq 2 and Eq 3.
Acknowledgements The authors would like to acknowledge Capacity Building Program for New Researcher 2018 from National Research Council of Thailand (NRCT) and Department of Industrial Chemistry, Faculty of Applied Science, Graduate College, King Mongkut’s University of Technology North Bangkok, Thailand, for their supports in information and operations.
Yu, Effects of metal ions on crystal morphology and size of calcium sulfate whiskers in aqueous HCl solutions, Industrial & Engineering Chemistry Research 53(45) (2014) 17625-17635
The absorption bands at 3200-3800 cm-1and 700-1800 cm-1 correspond respectively to –OH stretching and –OH bending of water molecules in calcium sulfate structure.
Role of ethylene glycol on the transformations of DH to α-HH The phase transformation of DH to α-HH has been investigated using Eq 1, The theory of crystal structure formation of α-HH are dissolution-recrystallization [14] as shown in Eq 2 and Eq 3.
Acknowledgements The authors would like to acknowledge Capacity Building Program for New Researcher 2018 from National Research Council of Thailand (NRCT) and Department of Industrial Chemistry, Faculty of Applied Science, Graduate College, King Mongkut’s University of Technology North Bangkok, Thailand, for their supports in information and operations.
Yu, Effects of metal ions on crystal morphology and size of calcium sulfate whiskers in aqueous HCl solutions, Industrial & Engineering Chemistry Research 53(45) (2014) 17625-17635
Online since: May 2013
Authors: Azlan Abdul Aziz, Bashiru Kayode Sodipo
It indicates the ultra-fine nature, cubic phase structure and small crystallite size of the particles.
However, the crystalline structure of the synthesized SiO2 coated SPION in figure 5a is similar to that in figure 5b.
Turq, The Journal of Physical Chemistry C, 111 (2007) 18568-18576
Yang, Journal of Materials Chemistry, 15 (2005) 4252-4257
Markert, The Journal of Physical Chemistry C, 111 (2007) 18512-18519.
However, the crystalline structure of the synthesized SiO2 coated SPION in figure 5a is similar to that in figure 5b.
Turq, The Journal of Physical Chemistry C, 111 (2007) 18568-18576
Yang, Journal of Materials Chemistry, 15 (2005) 4252-4257
Markert, The Journal of Physical Chemistry C, 111 (2007) 18512-18519.
Online since: September 2013
Authors: Hai Jin Zheng, Shu Quan Zhu, Zhen Xin Zhao, Bu Wei Ma
Low-temperature Pyrolysis Characteristics of Inner Mongolia Lignite
Zhenxin ZHAO1, Buwei MA1, Shuquan ZHU2, Haijin ZHENG1
1 Department of Chemistry and Chemical Engineering, Henan University of Urban Construction, Pingdingshan, Henan,China
2 School of Chemistry & Environmental Engineering, China University of Mining & Technology (Beijing), Beijing, China
Email: zzx@hncj.edu.cn
Key words: lignite; low-temperature pyrolysis; semi-coke; gas product
Abstract: The utilization of high moisture, high volatile low rank coals such as lignite is gaining importance day by day to meet the growing demands of coal for the energy sectors.
So it is of great significance to the development of new technology for lignite conversion to analyze the composition and structure of the lignite before and after modification, which conducives to the rational utilization of the lignite resources[3].
Because the unsaturated structures of lignite such as alicyclic and bis ethylenically are more, the condensation cross linking reactions are prone to produce when the lignite is heated, and the char yield is significantly reduced.
The macromolecular structure of the coal exhibits a "thermal inertia".
Journal of Fuel Chemistry and Technology. 1996,(24)5, 426-433 [9] Ju Fu-dong, Chen Han-ping, Yang Hai-ping et al. coal conversion, 2009 (32)1,5-9 [10] ZHAO Zhen-xin.
So it is of great significance to the development of new technology for lignite conversion to analyze the composition and structure of the lignite before and after modification, which conducives to the rational utilization of the lignite resources[3].
Because the unsaturated structures of lignite such as alicyclic and bis ethylenically are more, the condensation cross linking reactions are prone to produce when the lignite is heated, and the char yield is significantly reduced.
The macromolecular structure of the coal exhibits a "thermal inertia".
Journal of Fuel Chemistry and Technology. 1996,(24)5, 426-433 [9] Ju Fu-dong, Chen Han-ping, Yang Hai-ping et al. coal conversion, 2009 (32)1,5-9 [10] ZHAO Zhen-xin.
Online since: May 2014
Authors: Hong Fang Shen, You Jun Lu, Jie Dong, Guo Li Fang, Yan Min Wang
XRD, FESEM and H2-TPR were applied to characteristic crystalline phase structure, morphology, thermal-stability of LCO samples.
Many synthesis methods were commonly used to prepare perovskite-structure compound oxide, such as high temperature solid phase combustion, sol-gel [8-10], co-precipitation [4, 11, 12] et al.
The possible reason for the above phenomenon is that methyl orange and gold orange II have different surface chemical structures (Fig. 7).
Journal of Fuel Chemistry and Technology, 2002, 30(4): 368-371 [8] Shudan Li, Liqiang Jing, et al.
Science China: Chemistry, 2012, 55 (11): 2292-2310 [19] Wensheng Yao, Rijie Wang, et al.
Many synthesis methods were commonly used to prepare perovskite-structure compound oxide, such as high temperature solid phase combustion, sol-gel [8-10], co-precipitation [4, 11, 12] et al.
The possible reason for the above phenomenon is that methyl orange and gold orange II have different surface chemical structures (Fig. 7).
Journal of Fuel Chemistry and Technology, 2002, 30(4): 368-371 [8] Shudan Li, Liqiang Jing, et al.
Science China: Chemistry, 2012, 55 (11): 2292-2310 [19] Wensheng Yao, Rijie Wang, et al.
Online since: March 2024
Authors: Vaqifa Huseynova, Aynura Yariyeva, Shukufa Eyvazova, Nailya Veysova
The general structure of molecules of physiologically active substances should correspond to the structure of specific molecules of cells.
For this reason, it is very important to buy amines with different structures and functional substitutions.
So, with this method, no solvent is used in the synthesis process, a high-yield product is obtained based on an efficient and safe technology, and the principles of "green chemistry" are ensured.
For this reason, the acquisition of amines with different structures and functional substitutions is of certain importance.
//Azerbaijani chemistry magazine., 2013, № 1. 94-97
For this reason, it is very important to buy amines with different structures and functional substitutions.
So, with this method, no solvent is used in the synthesis process, a high-yield product is obtained based on an efficient and safe technology, and the principles of "green chemistry" are ensured.
For this reason, the acquisition of amines with different structures and functional substitutions is of certain importance.
//Azerbaijani chemistry magazine., 2013, № 1. 94-97
Online since: January 2011
Authors: Yang Cao, Gang Zhou, Jun Hui He
Fig. 2(a) is a SEM image at low-magnification, and indicates that many pimple-like structures grown on the surface of the nickel grain.
The morphological features of the pimple-like structures were clearly displayed by a high magnification SEM image (Fig. 2(b)).
It clearly shows that the morphology of the pimple-like structure is actually nanorod.
The measured lattice spacing is 0.27 nm, corresponding well to the (200) lattice spacing of the cubic Si structure.
KGCX2-YW-370 and KSCX2-YW-G-059), and the Science Fund for Young Scholar of the Technical Institute of Physics and Chemistry, Chinese Academy of Sciences (Grant No.
The morphological features of the pimple-like structures were clearly displayed by a high magnification SEM image (Fig. 2(b)).
It clearly shows that the morphology of the pimple-like structure is actually nanorod.
The measured lattice spacing is 0.27 nm, corresponding well to the (200) lattice spacing of the cubic Si structure.
KGCX2-YW-370 and KSCX2-YW-G-059), and the Science Fund for Young Scholar of the Technical Institute of Physics and Chemistry, Chinese Academy of Sciences (Grant No.
Online since: September 2024
Authors: Yong Li, Yan Qun Shao, Ya Liang Chen
There were a few changes in the structure of ZnO@PDA or ZnO-Ag @PDA.
The metal oxide@PDA with a melanin-like structure can act as a photocatalyst, light absorber, electron transfer receptor, and adhesive interface under the light.
The structure of the ZnO nanoparticles almost had no change after being coated by DA.
The reduction of Eg may be due to the absorption of light by the melanin-like structure of the PDA itself, which affected the diffuse reflectance spectrum.
Jia, Construction of yolk-shell structural polydopamine@WO3 micro/nanospheres for enhanced photocatalytic degradation, Chemistry Select, 8(2023) 1-10, doi:10.1002/slct.202301084
The metal oxide@PDA with a melanin-like structure can act as a photocatalyst, light absorber, electron transfer receptor, and adhesive interface under the light.
The structure of the ZnO nanoparticles almost had no change after being coated by DA.
The reduction of Eg may be due to the absorption of light by the melanin-like structure of the PDA itself, which affected the diffuse reflectance spectrum.
Jia, Construction of yolk-shell structural polydopamine@WO3 micro/nanospheres for enhanced photocatalytic degradation, Chemistry Select, 8(2023) 1-10, doi:10.1002/slct.202301084