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Online since: April 2016
Authors: Xia Jiang, Fen Xu, Li Xian Sun
GO was supplied from institute of coal chemistry (Shanxi, China).
Results and discussion The evolution of structure, morphology and thermal property of GNPC were investigated by powder X-ray diffraction, scanning electron microscopy and TGA.
After composited with GO, GO@ZIF-8 retains a typical crystal morphology similar to that of the parent ZIF-8 (Fig. 2b), suggesting that the GO just attaches on the ZIF-8 and the precursor still remains the crystal structure of ZIF-8.
Yu: Journal of Materials Chemistry A, Vol. 2 (2014) No.17, p.6086
Cao: Journal of Materials Chemistry A, Vol. 2 (2014) No.32, p.12873
Results and discussion The evolution of structure, morphology and thermal property of GNPC were investigated by powder X-ray diffraction, scanning electron microscopy and TGA.
After composited with GO, GO@ZIF-8 retains a typical crystal morphology similar to that of the parent ZIF-8 (Fig. 2b), suggesting that the GO just attaches on the ZIF-8 and the precursor still remains the crystal structure of ZIF-8.
Yu: Journal of Materials Chemistry A, Vol. 2 (2014) No.17, p.6086
Cao: Journal of Materials Chemistry A, Vol. 2 (2014) No.32, p.12873
Online since: March 2017
Authors: Yan Ching Jean, J. David van Horn, Matthew D. Paul, Jonathan S. Davis
David Van Horn1d*
1Department of Chemistry, University of Missouri, Kansas City, Missouri 64110, USA
amdpht7@mail.umkc.edu, bjsdr4c@mail.umkc.edu, cjeany@umkc.edu, dvanhornj@umkc.edu
Keywords: 3D printing, polymer additives, ABS, PLA, PETG, PALS.
Recently, modified polymers containing different additives have been used to change the properties of the polymer structures being printed.
Nonetheless, we speculate that specialized printing patterns, methods, or future resolution enhancements may allow for nano- to meso-porous structure or void formation in “printed” materials.
Katherine Bloemker (UMKC School of Computing and Engineering), and Zhonghua Peng and Kathleen Kilway (UMKC Chemistry), and Trinity Biotech (Kansas City) for project assistance.
We thank the UMKC Summer Undergraduate Research Opportunity Program (SUROP) and the Dept. of Chemistry for funding.
Recently, modified polymers containing different additives have been used to change the properties of the polymer structures being printed.
Nonetheless, we speculate that specialized printing patterns, methods, or future resolution enhancements may allow for nano- to meso-porous structure or void formation in “printed” materials.
Katherine Bloemker (UMKC School of Computing and Engineering), and Zhonghua Peng and Kathleen Kilway (UMKC Chemistry), and Trinity Biotech (Kansas City) for project assistance.
We thank the UMKC Summer Undergraduate Research Opportunity Program (SUROP) and the Dept. of Chemistry for funding.
Online since: October 2015
Authors: Sergey Kozyukhin, Vladimir Kozik, Michael Presniakov, Alexander Baranchikov, Alexey Sadovnikov, Lyudmila P. Borilo, Vladimir K. Ivanov
Hydrothermal Synthesis of Nanocrystalline Titanium Dioxide
for Use as a Photoanode of DSSCs
KOZYUKHIN Sergey1, 2, a, SADOVNIKOV Alexey1, b,
PRESNIAKOV Michael3,c, BARANCHIKOV Alexander1,d, BORILO Lyudmila2,e,
KOZIK Vladimir2, f, IVANOV Vladimir1, 2, g
1Kurnakov Institute of General and Inorganic Chemistry, RAS, 31, Leninsky Pr., Moscow, 119991, Russia
2Tomsk State University, Department of Chemistry, 36, Lenin Pr., Tomsk, 634050, Russia
3NBICS-Centre Kurchatov Institute, 1, Akademika Kurchatova pl., Moscow, 123182, Russia
asergkoz@igic.ras.ru, btrinki13@gmail.com, cmpresniakov@gmail.com, da.baranchikov@yandex.ru, eborilo@mail.ru, fvkozik@mail.ru, gvan@igic.ras.ru
Keywords: titanium dioxide, DSSC, TEM.
According to XRD analysis, all samples obtained during microwave-assisted synthesis both in the presence and in the absence of ammonium fluoride in reaction mixtures are single phase anatase powders with particle size 10–15 nm (tetragonal structure, space group I41/amd, lattice parameters a = 3.784 Å and c = 9.514 Å [17]).
The interplanar distances and diffraction ring intensities derived from the SADP unambiguously pointed to anatase crystal structure [19] of TiO2 film.
Chemistry, 2011, 441, 361-364
Weirich, T.E.; Winterer, M.; Seifried, S.; Mayer, J., Structure of nanocrystalline anatase solved and refined from electron powder data, Acta Crystallographica A 58 (2002) 308-315.
According to XRD analysis, all samples obtained during microwave-assisted synthesis both in the presence and in the absence of ammonium fluoride in reaction mixtures are single phase anatase powders with particle size 10–15 nm (tetragonal structure, space group I41/amd, lattice parameters a = 3.784 Å and c = 9.514 Å [17]).
The interplanar distances and diffraction ring intensities derived from the SADP unambiguously pointed to anatase crystal structure [19] of TiO2 film.
Chemistry, 2011, 441, 361-364
Weirich, T.E.; Winterer, M.; Seifried, S.; Mayer, J., Structure of nanocrystalline anatase solved and refined from electron powder data, Acta Crystallographica A 58 (2002) 308-315.
Online since: July 2012
Authors: Ying Xin Zhang, Jia Ying Xin, Chun Gu Xia, Hua Nan Guan, Dan Dan Chen, Chao Ze Yan
The importance of hydrogen peroxide as an analyte is dominated by its application in clinical chemistry [2].
The chemical structure of mb is shown in Fig. 1 [5].
Catechol is an important phenol compound, and the measurement of catechol is often related to the brain chemistry.
Fig. 1 Chemical structure of mb, the two oxazolone rings are labeled OxaA and OxaB.
Conclusions The development of mimetic peroxidase is a focus in chemistry, aiming to synthesize a sort of organic complex with not only functions of enzymes but advantages over bioenzymes’ excessive sensitivity to the environment.
The chemical structure of mb is shown in Fig. 1 [5].
Catechol is an important phenol compound, and the measurement of catechol is often related to the brain chemistry.
Fig. 1 Chemical structure of mb, the two oxazolone rings are labeled OxaA and OxaB.
Conclusions The development of mimetic peroxidase is a focus in chemistry, aiming to synthesize a sort of organic complex with not only functions of enzymes but advantages over bioenzymes’ excessive sensitivity to the environment.
Online since: January 2005
Authors: Lang Liu, Yali Cao, Dienzeng Jia, Ding Quan Xiao
Introduction
The field of nanostructured materials is a fascinating area of chemistry and materials science
because of their novel properties that differ from those of bulk materials and potential applications
ranging from mesoscopic research to the development of nanodevices [1-2].
One-dimensional (1D) materials are an important category of nanostructured materials and have been widely researched yielding various special structures such as nanotubes, nanorods, nanowires and nanobelts etc [3-6].
These zinc oxide nanorods or nanobelts reported previously had high purity and well-crystalline structure, but the growth temperature was too high to allow to be used as low-temperature-endurance substrates.
Experimental All the reagents are analytical pure from shanghai chemistry and were used without further purification.
The variation of relative intensity for the peaks may frequently happen for nanoscale structures because of the size-effect and disorder arising from nanostructures.
One-dimensional (1D) materials are an important category of nanostructured materials and have been widely researched yielding various special structures such as nanotubes, nanorods, nanowires and nanobelts etc [3-6].
These zinc oxide nanorods or nanobelts reported previously had high purity and well-crystalline structure, but the growth temperature was too high to allow to be used as low-temperature-endurance substrates.
Experimental All the reagents are analytical pure from shanghai chemistry and were used without further purification.
The variation of relative intensity for the peaks may frequently happen for nanoscale structures because of the size-effect and disorder arising from nanostructures.
Online since: February 2014
Authors: Ali Ramazani, Morteza Rouhani, Sang Woo Joo
Silica Nanoparticles from Rice Husk Ash: A Green Catalyst for the One-Pot Three- Component Synthesis of Benzo[B]Furan Derivatives
Ali Ramazani1,a,*, Morteza Rouhani1,b and Sang Woo Joo2,c,*
1Department of Chemistry, University of Zanjan, P O Box 45195-313, Zanjan, IRAN
2World Class University Nano Research Center, School of Mechanical Engineering, Yeungnam University, Gyongsan 712-749, Republic of Korea
aaliramazani@gmail.com , brouhani.morteza@gmail.com , cswjoo@yu.ac.kr
Keywords: Silica nanoparticles, Multi-component reaction, Isocyanide, 2-Hydroxy-5- nitro-benzaldehyde, 2-Hydroxy-5-bromo-benzaldehyde, Secondary amine, Benzo[b]furan, Iminium ion.
Introduction Multi-component reactions (MCRs) have attracted significant attention in combinatorial chemistry [1].
The structures of compounds 7a–j were deduced from their IR, and high-field 1H and 13C NMR spectra, and their mass spectra.
Periasamy, in: The Chemistry of Functional Groups, edtied by S.
Dibble, in: Comprehensive Heterocyclic Chemistry II, edtied by A.R.
Introduction Multi-component reactions (MCRs) have attracted significant attention in combinatorial chemistry [1].
The structures of compounds 7a–j were deduced from their IR, and high-field 1H and 13C NMR spectra, and their mass spectra.
Periasamy, in: The Chemistry of Functional Groups, edtied by S.
Dibble, in: Comprehensive Heterocyclic Chemistry II, edtied by A.R.
Online since: October 2014
Authors: Juan Ying Peng, Ren Bin Yang
The change of compound structure or aggregation state will certainly accompany with the change of entropy.
Food Chemistry, 2005, 97 (1): 181~188
Environmental Chemistry, 1994, 13 (3): 206~209
Journal of Environmental Chemistry, 2001, 20 (2): 168~171
Chemistry Behavior of Triadimefon in Aquatic Environment [D].Changsha: Hunan Agriculture University, 2005.
Food Chemistry, 2005, 97 (1): 181~188
Environmental Chemistry, 1994, 13 (3): 206~209
Journal of Environmental Chemistry, 2001, 20 (2): 168~171
Chemistry Behavior of Triadimefon in Aquatic Environment [D].Changsha: Hunan Agriculture University, 2005.
Online since: February 2016
Authors: Jing Xu
It was showed that obtained powders had the same structure as purchased.
Agriculture and Food Chemistry, 2010, 58 (5): 2848-2853
Industrial & Engineering Chemistry Research, 2009, 48 (18): 8493-8499
Industrial & Engineering Chemistry Research, 2007, 46 (14): 4839-4845
Industrial & Engineering Chemistry Research, 2006, 45 (7): 2287-2293
Agriculture and Food Chemistry, 2010, 58 (5): 2848-2853
Industrial & Engineering Chemistry Research, 2009, 48 (18): 8493-8499
Industrial & Engineering Chemistry Research, 2007, 46 (14): 4839-4845
Industrial & Engineering Chemistry Research, 2006, 45 (7): 2287-2293
Online since: April 2008
Authors: Donald W. Brenner, Yun Feng Shi
However, the hotspot formation
mechanism, i.e. why chemistry is localized, has not been fully established at the atomic level.
Such shock chemistry enhancement is due to momentum/energy focusing although no jetting was observed [15].
These results provide useful insights in understanding shape-dependent shock chemistry during void collapsing.
Nitrogen cubane molecules are packed in simple cubic structure in a simulation box of 46×52×0.9 nm3.
Brenner, Journal of Physical Chemistry C, submitted (2008)
Such shock chemistry enhancement is due to momentum/energy focusing although no jetting was observed [15].
These results provide useful insights in understanding shape-dependent shock chemistry during void collapsing.
Nitrogen cubane molecules are packed in simple cubic structure in a simulation box of 46×52×0.9 nm3.
Brenner, Journal of Physical Chemistry C, submitted (2008)
Online since: June 2020
Authors: Brigita Neiberte, Anrijs Verovkins, Galia Shulga, Jevgenijs Jaunslavietis, Mārtiņš Kalniņš, Jurijs Ozolins
Recycled Paper Additive for Wood-Polymer Composite: Preparation and Characterization
Jevgenijs Jaunslavietis1,2,a*, Jurijs Ozolins2,c, Martins Kalnins2, Galia Shulga1,b, Brigita Neiberte1,e and Anrijs Verovkins1,d
1Laboratory of Lignin Chemistry, Latvian State Institute of Wood Chemistry, Dzerbenes 27, Riga, Latvia, LV-1006
2Faculty of Materials Science and Applied Chemistry, Riga Technical University, Paula Valdena 3, Riga, Latvia, LV-1048
aj.jaunslavietis@inbox.lv, bshulga@junik.lv, cjuris_oz@inbox.lv, danrivero@inbox.lv, ebricis46@inbox.lv
Keywords: waste paper, cellulose, contact angle.
Capillary constant values (which are related to powder structure, density, morphology, packing etc.) were different for RPAP and CEL.
Gast, Physical Chemistry of Surfaces, New York : John Wiley & Sons, 1997.
Capillary constant values (which are related to powder structure, density, morphology, packing etc.) were different for RPAP and CEL.
Gast, Physical Chemistry of Surfaces, New York : John Wiley & Sons, 1997.