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Online since: May 2023
Authors: Hussein M. Ahmed, Neama Ahmed Sobhy, Mariam E. Fawzy, Wageh A. Ibrahem
Among these, zinc oxide nano-materials (ZnO NPS) are unique in structure with substantial active ingredients and are extensively used as they possess antibacterial, antimicrobial, biological, catalytic, electrical and optical activity.
Maligan, “Zinc oxide nanoparticles synthesis methods and its effect on morphology: A review,” Biointerface Research in Applied Chemistry, vol. 12, no. 3, pp. 4261–4292, 2022, doi: 10.33263/BRIAC123.42614292
Ahmed, “Effective granular activated carbon for greywater treatment prepared from corncobs,” Egyptian Journal of Chemistry, 2022
Saeed, “Pomegranate Peel Extract-Mediated Green Synthesis of ZnO-NPs: Extract Concentration-Dependent Structure, Optical, and Antibacterial Activity,” Journal of Chemistry, vol. 2022, 2022, doi: 10.1155/2022/9647793
Hefny, “Greywater treatment for safe recycling via hybrid constructed wetlands and sludge evaluation,” Egyptian Journal of Chemistry, pp. 1–15, 2022
Maligan, “Zinc oxide nanoparticles synthesis methods and its effect on morphology: A review,” Biointerface Research in Applied Chemistry, vol. 12, no. 3, pp. 4261–4292, 2022, doi: 10.33263/BRIAC123.42614292
Ahmed, “Effective granular activated carbon for greywater treatment prepared from corncobs,” Egyptian Journal of Chemistry, 2022
Saeed, “Pomegranate Peel Extract-Mediated Green Synthesis of ZnO-NPs: Extract Concentration-Dependent Structure, Optical, and Antibacterial Activity,” Journal of Chemistry, vol. 2022, 2022, doi: 10.1155/2022/9647793
Hefny, “Greywater treatment for safe recycling via hybrid constructed wetlands and sludge evaluation,” Egyptian Journal of Chemistry, pp. 1–15, 2022
Online since: May 2013
Authors: Zhi Tao, Jie He, Xiao Jin Zhang, Ye Xin Xu, X. WU
The results indicate that the heterojunction has smaller effects on the structure defect of CNTs [3].
Considering that the polyethylene has good flexibility and a simple physical structure, it is selected as the material of the polymer chain.
This result is mainly because the structure defect at the interfaces leads to scattering during the phonon propagation process and the decrease of phonon mean free path.
Covalent surface chemistry of single-walled carbon nanotubes.
Journal of Physical Chemistry C, 2010, 114(39): 16223-16228
Considering that the polyethylene has good flexibility and a simple physical structure, it is selected as the material of the polymer chain.
This result is mainly because the structure defect at the interfaces leads to scattering during the phonon propagation process and the decrease of phonon mean free path.
Covalent surface chemistry of single-walled carbon nanotubes.
Journal of Physical Chemistry C, 2010, 114(39): 16223-16228
Online since: September 2014
Authors: Bei Ping Liu, Yuan Dao Chen, Xiao Bing Huang, Shi Biao Zhou, Hong Hui Chen, Xian Guang Zeng
The effect of K-doping on lattice structure, morphology and electrochemical characteristics of Li4Ti5O12 was investigated.
The crystal structure of the as-received samples was identified by X-ray powder diffraction analysis (XRD) with a Cu Kα radiation source (DX 2700).
Results and discussion The crystal structure and phase formation of the as-obtained samples were identified using their XRD pattern, which is discribed in Fig.1.
All the peaks can be well indexed on the basis of cubic spinel structure with a Fd-3m space group (PDF#49-0207).
This means that the low doping of K+ does not alter the structure of materials.
The crystal structure of the as-received samples was identified by X-ray powder diffraction analysis (XRD) with a Cu Kα radiation source (DX 2700).
Results and discussion The crystal structure and phase formation of the as-obtained samples were identified using their XRD pattern, which is discribed in Fig.1.
All the peaks can be well indexed on the basis of cubic spinel structure with a Fd-3m space group (PDF#49-0207).
This means that the low doping of K+ does not alter the structure of materials.
Online since: October 2006
Authors: Hirohisa Sato, Hee Joon Kim, Naoki Kamegashira, Migaku Kobayashi, Yoshihiko Hiyoshi, Doh Jae Lee
Thermal Diffusivity and Phase Transition of Rare Earth Manganites
Migaku Kobayashi1,2,a, Hirohisa Satoh1,b, Yoshihiko Hiyoshi1,
Naoki Kamegashira
1,c
, Doh-Jae Lee3 and Hee-Joon Kim
4,d
1
Department of Materials Science, Toyohashi University of Technology, Tempaku-cho,
Toyohashi, 441-8580, Japan
2
Present address: Department of Chemistry and Biochemistry, Numazu College of Technology,
Ooka, Numazu, 410-8501 Japan
3
Chonnam National University, Department of Metallurgical Engineering, Kwang-Ju, Korea
4
Departmernt of Ecological Engineering, Toyohashi University of Technology, Tempaku-cho,
Toyohashi, 441-8580 Japan
a
m.kobayashi@numazu-ct.ac.jp, bhsatoh@tutms.tut.ac.jo,
cnkamegas@tutms.tut.ac.jp, dkim@eco.tut.ac.jp
Keywords: Rare earth manganites; Phase transition; Oxygen nonstoichiometry; Thermal diffusivity.
Introduction LnMnO3 (Ln = rare earth element) has a perovskite-type structure for Ln = La - Dy and a hexagonal structure for a smaller ionic size of rare earths [1].
In general LnMnO3 (Ln=La- Dy) with the perovskite-type structure belongs to an orthorhombic system near stoichiometric composition and this orthorhombic distortion is caused by the Jahn-Teller effect of trivalent Mn ion in the oxygen octahedral field in the crystal structure [7].
structures. 3.
Eyring (Eds.), Handbook on the Physics and Chemistry of Rare Earths, North-Holland, Amsterdam, 1979, p.525, Chap. 29
Introduction LnMnO3 (Ln = rare earth element) has a perovskite-type structure for Ln = La - Dy and a hexagonal structure for a smaller ionic size of rare earths [1].
In general LnMnO3 (Ln=La- Dy) with the perovskite-type structure belongs to an orthorhombic system near stoichiometric composition and this orthorhombic distortion is caused by the Jahn-Teller effect of trivalent Mn ion in the oxygen octahedral field in the crystal structure [7].
structures. 3.
Eyring (Eds.), Handbook on the Physics and Chemistry of Rare Earths, North-Holland, Amsterdam, 1979, p.525, Chap. 29
Online since: August 2013
Authors: Xin Kang Gao, Jun Liu, Ting Hua Wang, Xue Li, Xiao Kai Zhang
For the spin-coated composite film, the microphase separated structures of PS-b-P2VP BCs are not observed (not shown).
After annealing at 150 ºC for 36h, as shown in Fig 2a, microphase separated structures could be observed and the dark dots were randomly distributed in the film.
Upon annealing, the structure of the composite film will evolve to equilibrium gradually.
Hydrogen bonding interactions between P2VP and MUA molecules attached on Fe3O4 MNPs changes the interaction between P2VP and the substrate and finally leads to a change in the structure of the composite film.
The composite films may provide a powerful platform to investigate structure-property correlations and find potential applications in chemical sensors, biosensors, catalysts, chemical separation, etc.
After annealing at 150 ºC for 36h, as shown in Fig 2a, microphase separated structures could be observed and the dark dots were randomly distributed in the film.
Upon annealing, the structure of the composite film will evolve to equilibrium gradually.
Hydrogen bonding interactions between P2VP and MUA molecules attached on Fe3O4 MNPs changes the interaction between P2VP and the substrate and finally leads to a change in the structure of the composite film.
The composite films may provide a powerful platform to investigate structure-property correlations and find potential applications in chemical sensors, biosensors, catalysts, chemical separation, etc.
Online since: January 2011
Authors: Shahrum Abdullah, Azman Jalar, Abdul Aziz Aendraa Azhar, Zainudin Kornain, Junaidi Syarif, Nasrizal Mohd Rashdi, Muhammad Faizol Ahmad Ibrahim
Fig. 1 shows the tensile properties, of the base metal as also the welded structure using difference filler metal.
The yield for welded structure used ER5356 yield strength 200 Mpa and 235Mpa for ER4043.
Tensile strength of welded structure using ER4043 is 180 Mpa and for ER5356 is 190 Mpa.
Excess silicon is generally believed to be beneficial for increasing the ductility of the welded structure.
Wierzbicki: Thin-Walled Structures Vol. 47 (2009), p. 431–441
The yield for welded structure used ER5356 yield strength 200 Mpa and 235Mpa for ER4043.
Tensile strength of welded structure using ER4043 is 180 Mpa and for ER5356 is 190 Mpa.
Excess silicon is generally believed to be beneficial for increasing the ductility of the welded structure.
Wierzbicki: Thin-Walled Structures Vol. 47 (2009), p. 431–441
Online since: October 2011
Authors: Bin Li, Hai Feng Chen, Shi Jiang Zhao, Jun Jun Wu
Optimization of Conditions for Extraction of Acid-soluble Al2O3 from Pyrophyllite
JunJun Wu, HaiFeng Chen, ShiJiang Zhao and Bin Li
Department of Chemistry, Huzhou Teachers College, Huzhou 313000, China
shenlandeye@163.com
Keywords: Acid-soluble; Al2O3; Fitting; Pyrophyllite
Abstract.
At different temperatures after heat activation and structural changes was analysis, the amount of pyrophyllite dissolution of alumina deter-mined by titration under different conditions, to under-stand coordination structure of aluminum dissolution in acid condition.
As Fig. 1 showed, it showed pyrophyllite particle size of about hundreds of μm2 thin sheet (upper right corner of the small map to enlarge), which was similar to the results we expected, because pyrophyllite were 2:1 layered silicon salt compounds [7], layered crystal structure of two adjacent layers connected only van der Waals force, combined with weak, by a simple machining could cause a "thinning" "stripping" effect, so this time we 100 mesh of the sample, with such a structure, could lead to various types of anions and cations into the (thin) layer (intermolecular forces had been largely ineffective), the sample had a certain adsorption capacity.
From the SEM photograph of the whole, this structure the "thinning" "peel" effect and wide distribution, degree of depth, in order to take over the adsorption experiments laid the structural basis, taking into account the pyrophyllite in aqueous samples.
Journal of Physics and Chemistry of Solids Vol. 68 (2007), p. 1225-1229 [4] Erdemo, S.
At different temperatures after heat activation and structural changes was analysis, the amount of pyrophyllite dissolution of alumina deter-mined by titration under different conditions, to under-stand coordination structure of aluminum dissolution in acid condition.
As Fig. 1 showed, it showed pyrophyllite particle size of about hundreds of μm2 thin sheet (upper right corner of the small map to enlarge), which was similar to the results we expected, because pyrophyllite were 2:1 layered silicon salt compounds [7], layered crystal structure of two adjacent layers connected only van der Waals force, combined with weak, by a simple machining could cause a "thinning" "stripping" effect, so this time we 100 mesh of the sample, with such a structure, could lead to various types of anions and cations into the (thin) layer (intermolecular forces had been largely ineffective), the sample had a certain adsorption capacity.
From the SEM photograph of the whole, this structure the "thinning" "peel" effect and wide distribution, degree of depth, in order to take over the adsorption experiments laid the structural basis, taking into account the pyrophyllite in aqueous samples.
Journal of Physics and Chemistry of Solids Vol. 68 (2007), p. 1225-1229 [4] Erdemo, S.
Online since: June 2011
Authors: Dan Dan Ma, Zengzhi ZHANG
The structure properties and surface morphology of carbon-pillared MMT are analyzed.
At high magnification, layer structure of MMT large particles is not obvious.
Chemistry absorption water between layers of organic carbon pillared MMT has been removed after being heated at 400 ℃ for 4h.
And the carbon pillared structure is mainly stable.
[5] X.R.Wang, S.N.Wu, W.S.Li .Environmental Chemistry, Vol. 16 (1997), P. 14 in Chinese
At high magnification, layer structure of MMT large particles is not obvious.
Chemistry absorption water between layers of organic carbon pillared MMT has been removed after being heated at 400 ℃ for 4h.
And the carbon pillared structure is mainly stable.
[5] X.R.Wang, S.N.Wu, W.S.Li .Environmental Chemistry, Vol. 16 (1997), P. 14 in Chinese
Online since: January 2013
Authors: Xin Min Min, Xuchao Wang
The relations between electronic structure, chemical bond and thermoelectric property are discussed.
DFT-DVM method can be used to calculate larger structure models of molecules, clusters and solids, so it has been widely used in chemistry, physics, material science and so on.
The character structure of CoO2 layer is edge-sharing [Co(1)O6] octahedron.
Ca2CoO3 layer is similar to structure of NaCl.
There is obvious difference of electronic structure and chemical bond between the two layers.
DFT-DVM method can be used to calculate larger structure models of molecules, clusters and solids, so it has been widely used in chemistry, physics, material science and so on.
The character structure of CoO2 layer is edge-sharing [Co(1)O6] octahedron.
Ca2CoO3 layer is similar to structure of NaCl.
There is obvious difference of electronic structure and chemical bond between the two layers.
Online since: March 2007
Authors: Gene E. Ice, Hidemi Kato, E.D. Specht, I. Inoue, E. Miura, J.W.L. Pang, K. Hisatsune
Second-phase crystal structures in the glassy phase matrix were probed with an intense synchrotron
microbeam.
Based on the chemical distribution the position of the precipitates with anomalous chemistry is precisely detected.
In order to determine the unknown crystal structure, monochromatic energy scans of Laue spot were carried out.
Fig. 9 is an indexed Laue pattern using the crystal structure obtained in this study.
Measurements are now underway to refine the crystal structure.
Based on the chemical distribution the position of the precipitates with anomalous chemistry is precisely detected.
In order to determine the unknown crystal structure, monochromatic energy scans of Laue spot were carried out.
Fig. 9 is an indexed Laue pattern using the crystal structure obtained in this study.
Measurements are now underway to refine the crystal structure.