Green Biosynthesis of Zinc Oxide Nanoparticles Utilizing Pomegranate Peel Extract for Grey Water Treatment

Article Preview

Abstract:

The Aim of this Study is the Green Biosynthesis of Zinc Oxide Nanoparticles (ZnO NPS) Using Pomegranate Peel Extract Utilized from Fruit Waste. Zno Nps were Characterized by X-Ray Powder Diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive X-Ray (EDX), Fourier Transform Infrared (FT-IR) Spectrum and UV–Vis Spectrophotometry. Also, Evaluation of the Efficiency of the Prepared Zno Nps Using the Jar Test Procedure was Employed after the Determination of the Optimum Dose of Zno Nps for the Removal of Pollutants from the Grey Water. Different Doses of Zno Nanoparticles (0.05, 0.1, 0.2, 0.3, 0.4, and 0.5 g/L) were Examined. the Results Obtained Confirmed that Zno Nps are Large Particles in Size Ranging from 54.2 to 86.4 Nm, Exist in a Pure and Crystalline Phase. the Results Obtained Showed that the Efficiency of Zno Nps for Pollutant Removal from Grey Water was Increased with the Increase of the Adsorbent Dose. the Best Removal Efficiency of Zno Nps was Obtained at a Dose of 400 Mg/L. the Removal Efficiency of Zno NPS was 98.16 %, 88.68%, 100%, 94.40%, 97.88%, 91.18%, 89.13%, 90.93%, and 90.37% for Ammonia (NH3+), Phosphorous (PO43-), Nitrate (NO3-), Oil & Grease, Total Nitrogen (TN), Turbidity, Chemical Oxygen Demand (COD), Biological Oxygen Demand (BOD5), and Total Suspended Solids (TSS) Removal, Respectively. the Cost Required for the Production of 100 g of Zno Nps was Calculated and Estimated to Be 42.37 Egyptian Pounds. in Conclusion Zno Nps Synthesized from Pomegranate Waste is a Sustainable, Eco-Friendly and Cost-Effective Approach with Potent Efficiency for Pollutants Removal from Grey Water.

You might also be interested in these eBooks

Info:

Periodical:

Solid State Phenomena (Volume 342)

Pages:

27-36

Citation:

Online since:

May 2023

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2023 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] N. Bellahsen, G. Varga, N. Halyag, S. Kertész, E. Tombácz, and C. Hodúr, "Pomegranate peel as a new low-cost adsorbent for ammonium removal," International Journal of Environmental Science and Technology, vol. 18, no. 3, p.711–722, 2021.

DOI: 10.1007/s13762-020-02863-1

Google Scholar

[2] I. R. Abubakar et al., "Environmental Sustainability Impacts of Solid Waste Management Practices in the Global South," International Journal of Environmental Research and Public Health, vol. 19, no. 19, 2022.

DOI: 10.3390/ijerph191912717

Google Scholar

[3] M. Samy, A. Gyamfi, E. Salama, M. Elkady, K. Mensah, and H. Shokry, "Heterogeneous activation of persulfate by a novel nano-magnetite / ZnO / activated carbon nanohybrid for carbofuran degradation : Toxicity assessment , water matrices , degradation mechanism and radical and non-radical pathways," Process Safety and Environmental Protection, vol. 169, no. November 2022, p.337–351, 2023.

DOI: 10.1016/j.psep.2022.11.038

Google Scholar

[4] C. O. Nnaji, J. Jeevanandam, Y. S. Chan, M. K. Danquah, S. Pan, and Barhoum, "Engineered nanomaterials for wastewater treatment: current and future trends," in Fundamentals of Nanoparticles, Elsevier, 2018, p.129–168.

DOI: 10.1016/b978-0-323-51255-8.00006-9

Google Scholar

[5] M. P. I. and Priyanka Jangid, "Applications of nanomaterials in wastewater treatment," Materials Today: Proceedings journal, p.1–5, 2021.

Google Scholar

[6] Q. L. Xiaolei Qu, and Pedro J.J. Alvarez, "Applications of nanotechnology in water and wastewater treatment," water r esearch, vol. 47, p.3931–3946, 2013.

DOI: 10.1016/j.watres.2012.09.058

Google Scholar

[7] M. S. M. M. and Hussein I. Abdel-Shafy1, "Green synthesis of metallic nanoparticles from natural resources and food waste and their environmental application," in Green Metal Nanoparticles, 2018, p.321–386.

DOI: 10.1002/9781119418900.ch11

Google Scholar

[8] M. S. M. M. Saad S.M. Hassan, and Hussein I. Abdel-Shafy, "Removal of pharmaceutical compounds from urine via chemical coagulation by green synthesized ZnO- nanoparticles followed by microfiltration for safe reuse," Arabian Journal of Chemistry, vol. 12, p.4074–4083, 2019.

DOI: 10.1016/j.arabjc.2016.04.009

Google Scholar

[9] E. K. Droepenu, B. S. Wee, S. F. Chin, K. Y. Kok, and M. F. Maligan, "Zinc oxide nanoparticles synthesis methods and its effect on morphology: A review," Biointerface Research in Applied Chemistry, vol. 12, no. 3, p.4261–4292, 2022.

DOI: 10.33263/BRIAC123.42614292

Google Scholar

[10] A. M. Saad et al., "Impact of Green Chitosan Nanoparticles Fabricated from Shrimp Processing Waste as a Source of Nano Nitrogen Fertilizers on the Yield Quantity and Quality of Wheat (Triticum aestivum L.) Cultivars," Molecules, vol. 27, no. 17, p.1–19, 2022.

DOI: 10.3390/molecules27175640

Google Scholar

[11] S. Haque et al., "Green Synthesis of Zn(OH)2/ZnO-Based Bionanocomposite using Pomegranate Peels and Its Application in the Degradation of Bacterial Biofilm," Nanomaterials, vol. 12, no. 19, p.1–14, 2022.

DOI: 10.3390/nano12193458

Google Scholar

[12] A. R. and A. S. P. Ramesh, "Synthesis of zinc oxide nanoparticle from fruits of citrus aurantifolia by chemical and green method," Asian J Phytomedicine Clin Res, vol. 2, no. 4, p.189–195, 2019.

Google Scholar

[13] J. K. P. Gitishree Das, Han-Seung Shin, Anuj Kumar, and Chethala N. Vishnuprasad, "Photo-mediated optimized synthesis of silver nanoparticles using the extracts of outer shell fibre of cocos nucifera L. fruit and detection of its antioxidant, cytotoxicity and antibacterial potential," Saudi Journal of Biological Sciences, vol. 28, p.980–987, 2021.

DOI: 10.1016/j.sjbs.2020.11.022

Google Scholar

[14] S. Sinsinwar, M. K. Sarkar, K. R. Suriya, P. Nithyanand, and V. Vadivel, "Use of agricultural waste (Coconut shell) for the synthesis of silver nanoparticles and evaluation of their antibacterial activity against selected human pathogens," Microbial Pathogenesis, p.1–13, 2018.

DOI: 10.1016/j.micpath.2018.08.025

Google Scholar

[15] Dalia Abdul Elah Mohammad and Eman Mohammad Taher, "Antimicrobial activity of silver nanoparticles fabricated from some vegetable plants," Journal of Physics, p.1–13, 2019.

DOI: 10.1088/1742-6596/1294/6/062048

Google Scholar

[16] S. Bhattacharya, P., Swarnakar, S., Ghosh, S., Majumdar, S., & Banerjee, "Disinfection of drinking water via algae mediated green synthesized copper oxide nanoparticles and its toxicity evaluation," Journal of Environmental Chemical Engineering, vol. 7, no. 1, 2019.

DOI: 10.1016/j.jece.2018.102867

Google Scholar

[17] E. Moghadam, M. R., Nasirizadeh, N., Dashti, Z., & Babanezhad, "Removal of Fe (II) from aqueous solution using pomegranate peel carbon: equilibrium and kinetic studies," International Journal of Industrial Chemistry, vol. 4, no. 1, p.1–6, 2013.

DOI: 10.1186/2228-5547-4-19

Google Scholar

[18] F. Rao, R. A., & Rehman, "Adsorption of heavy metal ions on pomegranate (punica granatum) peel: removal and recovery of Cr (VI) ions from a multi-metal ion system," Adsorption Science & Technolog, vol. 28, no. 3, p.195–211, 2010.

DOI: 10.1260/0263-6174.28.3.195

Google Scholar

[19] A. Verbič, M. Šala, I. Jerman, and M. Gorjanc, "Novel green in situ synthesis of zno nanoparticles on cotton using pomegranate peel extract," Materials, vol. 14, no. 16, 2021.

DOI: 10.3390/ma14164472

Google Scholar

[20] V.K.G. Alexander E. Burakov, Evgeny V. Galunin, Irina V. Burakova, Anastassia E. Kucherovaa, Shilpi Agarwalb, and Alexey G. Tkacheva, "Adsorption of heavy metals on conventional and nanostructured materials for wastewater treatment purposes: A review," Ecotoxicology and Environmental Safety, vol. 148, p.702–712, 2018.

DOI: 10.1016/j.ecoenv.2017.11.034

Google Scholar

[21] S. H. Baloch, M. Y. J., & Mangi, "Treatment of synthetic greywater by using banana, orange and sapodilla peels as a low cost activated carbon," J Mater Environmental Sci, vol. 10, no. 10, p.966–986, 2019.

Google Scholar

[22] N.A.S.M. A. El-Khateeb, and Hussein M. Ahmed, "Effective granular activated carbon for greywater treatment prepared from corncobs," Egyptian Journal of Chemistry, 2022.

DOI: 10.21608/ejchem.2022.117621.5302

Google Scholar

[23] M.A. El-Khateeb and N. A. S. , Hussein M. Ahmed, "Recycling of waste chicken bones for greywater pollutants removal," Desalination and Water Treatment, 2022.

DOI: 10.5004/dwt.2022.28609

Google Scholar

[24] S.S.M. Hassan, H. I. Abdel-Shafy, and M. S. M. Mansour, "Removal of pharmaceutical compounds from urine via chemical coagulation by green synthesized ZnO-nanoparticles followed by microfiltration for safe reuse," Arabian Journal of Chemistry, vol. 12, no. 8, p.4074–4083, 2019.

DOI: 10.1016/j.arabjc.2016.04.009

Google Scholar

[25] APHA., "Standard methods for the examination of water and wastewater," American Water Work, Public Work, Association, Environmental, Fed, 2017.

Google Scholar

[26] "Egyptian environmental association affair (EEAA), law 48, 1982, permissible values for wastes in river nile and Law 44, Law of the environmental protection 1994, updating 2000."

Google Scholar

[27] S. I. Abou-Elela, M. E. Fawzy, and S. A. El-Shafai, "Treatment of hazardous wastewater generated from metal finishing and electro-coating industry via self-coagulation: Case study," Water Environment Research, vol. 93, no. 9, p.1476–1486, Sep. 2021.

DOI: 10.1002/wer.1552

Google Scholar

[28] S.I. Abou-Elela, S.A. El-Shafai, M.E. Fawzy, M.S. Hellal, and O. Kamal, "Management of shock loads wastewater produced from water heaters industry," International Journal of Environmental Science and Technology, vol.15, no. 4, 2018.

DOI: 10.1007/s13762-017-1433-9

Google Scholar

[29] A. Alnehia, A. B. Al-Odayni, A. Al-Sharabi, A. H. Al-Hammadi, and W. S. Saeed, "Pomegranate Peel Extract-Mediated Green Synthesis of ZnO-NPs: Extract Concentration-Dependent Structure, Optical, and Antibacterial Activity," Journal of Chemistry, vol. 2022, 2022.

DOI: 10.1155/2022/9647793

Google Scholar

[30] G. A. Rather, S. Hamid, M. Riyaz, and M. Hassan, "The role of green synthesised zinc oxide nanoparticles in agriculture chapter 7 The role of green synthesised zinc oxide nanoparticles in agriculture," Nature Switzerland, vol. 119–142, no. October, p.1–25, 2021.

DOI: 10.1007/978-3-030-83066-3

Google Scholar

[31] H. S. Hassan, D. Abol-Fotouh, E. Salama, and M. F. Elkady, "Assessment of antimicrobial, cytotoxicity, and antiviral impact of a green zinc oxide/activated carbon nanocomposite," Scientific Reports, vol. 12, no. 1, p.1–12, 2022.

DOI: 10.1038/s41598-022-12648-w

Google Scholar

[32] O. Hamed, "Fabrication of zinc oxide nanoparticles and films by banana peel Fabrication of zinc oxide nanoparticles and films by banana peel extract food waste and investigation on their antioxidant and extract food waste and investigation on their antioxidant and a," 2018, [Online]. Available: https://fount.aucegypt.edu/etds.

DOI: 10.4028/www.scientific.net/kem.797.271

Google Scholar

[33] A.T.E. A. and, Enshirah Da'na, "Green synthesis of iron nanoparticles by acacia nilotica pods extract and its catalytic, adsorption, and antibacterial activities," Applied Science, vol. 8, no. 1922, p.1–17, 2018.

DOI: 10.3390/app8101922

Google Scholar

[34] L.M. Mahlaule-Glory and N. C. Hintsho-Mbita, "Green Derived Zinc Oxide (ZnO) for the Degradation of Dyes from Wastewater and Their Antimicrobial Activity: A Review," Catalysts, vol. 12, no. 8, 2022.

DOI: 10.3390/catal12080833

Google Scholar

[35] F.M. A.-H. Hussein M. Ahmed, Hussein I. Abdel-Shafy, Mohamed El-Khateeb, and Mohamed M. Hefny, "Greywater treatment for safe recycling via hybrid constructed wetlands and sludge evaluation," Egyptian Journal of Chemistry, p.1–15, 2022.

DOI: 10.21608/ejchem.2022.136764.6028

Google Scholar

[36] M. E. Fawzy, I. Abdelfattah, M. E. Abuarab, E. Mostafa, K. M. Aboelghait, and M. H. El-Awady, "Sustainable approach for pharmaceutical wastewater treatment and reuse: Case study," Journal of Environmental Science and Technology, vol. 11, no. 4, p.209–219, 2018.

DOI: 10.3923/jest.2018.209.219

Google Scholar