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Online since: March 2011
Authors: Li Ping Feng, Zheng Tang Liu, Qi Jun Liu
Results and discussion
Structure optimization.
Electronic structure.
Fig. 3 shows the molecular-orbital bonding structure for monoclinic HfO2.
Chen: Advanced Inorganic Chemistry (Advanced Education Press, Beijing 2005) [28] D.K.
Zheng: Structure of Matter (Advanced Education Press, Beijing 1989)
Electronic structure.
Fig. 3 shows the molecular-orbital bonding structure for monoclinic HfO2.
Chen: Advanced Inorganic Chemistry (Advanced Education Press, Beijing 2005) [28] D.K.
Zheng: Structure of Matter (Advanced Education Press, Beijing 1989)
Online since: February 2013
Authors: Vipinchandra A. Rana, A.D. Vyas, Deepak H. Gadani, Ashvin N. Prajapati
Because of its outstanding role in chemistry and biology, hydrogen bonding in liquid systems has been intensively studied for long and it is still subject to a lively scientific debate.
Fig. 4 Geometrically optimized hydrogen bonded structure of DMF and 1-PrOH.
Khatri, Study of static permittivity and hydrogen bonded structures in amide–alcohol mixed solvents, Thermochimica Acta. 506 (2010) 47-51
Saeriger, Hydrogen bonding in biological structures, Springer-verlag, New York, 1991
Lide, CRC Handbook of Chemistry and Physics, 84th Edition, CRC Press, 2004
Fig. 4 Geometrically optimized hydrogen bonded structure of DMF and 1-PrOH.
Khatri, Study of static permittivity and hydrogen bonded structures in amide–alcohol mixed solvents, Thermochimica Acta. 506 (2010) 47-51
Saeriger, Hydrogen bonding in biological structures, Springer-verlag, New York, 1991
Lide, CRC Handbook of Chemistry and Physics, 84th Edition, CRC Press, 2004
Online since: December 2010
Authors: Bao Min Wang, Wei Liu
Kaolin is in a layered silicate structure, with the layers binding with each other via the Van Der Weals bond, among which OH- is bound firmly.
Kaolin: Origin from Jilin Province, see Table 1 for chemistry.
Cement: P•42.5R type silicate cement from Dalian Onoda Cement Plant, refer to Table 2 for chemistry and to Table 3 for the physical mechanical properties of cement.
Kaolin chemistry (%) Material SiO2 Al2 O3 Fe2O3 CaO MgO Lo1(Lgnition loss) OPC 59.93 27.04 1.87 0.62 0.54 9.98 Table 2.
Cement chemistry Material CaO SiO2 Al2 O3 Fe2O3 MgO C3S C2S C3A C4AF OPC 64.14 21.07 4.61 2.98 1.42 59.5 15.5 7.2 9.1 Table 3.
Kaolin: Origin from Jilin Province, see Table 1 for chemistry.
Cement: P•42.5R type silicate cement from Dalian Onoda Cement Plant, refer to Table 2 for chemistry and to Table 3 for the physical mechanical properties of cement.
Kaolin chemistry (%) Material SiO2 Al2 O3 Fe2O3 CaO MgO Lo1(Lgnition loss) OPC 59.93 27.04 1.87 0.62 0.54 9.98 Table 2.
Cement chemistry Material CaO SiO2 Al2 O3 Fe2O3 MgO C3S C2S C3A C4AF OPC 64.14 21.07 4.61 2.98 1.42 59.5 15.5 7.2 9.1 Table 3.
Online since: July 2013
Authors: I.H. Kim, W.S. Kim, D.S. Rhee
It is generally refractory to any substantial biodegradation owing to its inherent chemical properties and complicated structure.
A: Chemistry 152(2002), p. 267 [6] J.
A: Chemistry 87(1995), p. 177 [16] M.
A: Chemistry 132(2000), p. 121 [17] U.
A: Chemistry 148(2002), p.137 [20] J.
A: Chemistry 152(2002), p. 267 [6] J.
A: Chemistry 87(1995), p. 177 [16] M.
A: Chemistry 132(2000), p. 121 [17] U.
A: Chemistry 148(2002), p.137 [20] J.
Online since: September 2012
Authors: Giuseppe Gallone, Fabia Galantini, Sabrina Bianchi, Irene Anguillesi, Valter Castelvetro
Piaggio”, University of Pisa, Largo Lucio Lazzarino 2, Pisa, Italy
2Department of Chemistry and Industrial Chemistry, University of Pisa, Via Risorgimento 35, Pisa, Italy
3Department of Chemical Engineering, Industrial Chemistry and Material Science, Largo Lucio Lazzarino 2, Pisa, Italy
afabia.galantini@ing.unipi.it, bsabrinab@ns.dcci.unipi.it, cvetro@dcci.unipi.it, direne.anguillesi@ing.unipi.it, eg.gallone@ing.unipi.it
Keywords: actuators, dielectric constant, dielectric elastomer, electro-mechanical response, functionalized carbon nanotubes, percolation, polyurethane.
Combination of CNTs with electro-active polymers (EAPs), has recently found application not only as reinforcing method to create structured materials with improved mechanical properties [1], but also as a means to enhance the electromechanical performance of dielectric elastomers actuators (DEAs) [2].
Most common CNTs functionalization methods include the use of diazonium, fluorination, radical chemistry, metal reduction and others.
Results and Discussion Graphs reported in Fig. 1 show a typical noisy IR spectrum for CNTs-RAFT, with a peak at 1560 cm1 relative to C=C bonds stretching of graphene structures and a peak at 1167 cm-1 due to the stretching vibrstion of C-S bonds of RAFT dithiobenzoate.
Combination of CNTs with electro-active polymers (EAPs), has recently found application not only as reinforcing method to create structured materials with improved mechanical properties [1], but also as a means to enhance the electromechanical performance of dielectric elastomers actuators (DEAs) [2].
Most common CNTs functionalization methods include the use of diazonium, fluorination, radical chemistry, metal reduction and others.
Results and Discussion Graphs reported in Fig. 1 show a typical noisy IR spectrum for CNTs-RAFT, with a peak at 1560 cm1 relative to C=C bonds stretching of graphene structures and a peak at 1167 cm-1 due to the stretching vibrstion of C-S bonds of RAFT dithiobenzoate.
Online since: December 2024
Authors: Muhammad Zaki, Aula Chairunnisak, Darmadi Darmadi, Adisalamun Adisalamun
Current investigations indicate a range of methods, including chemistry, biology, and physiological processes are employed for eliminating metallic substances from water as well as wastewater.
In contrast, zeolites are inorganic crystalline minerals with structured pores smaller than two nm.
The structured pores of natural clays exhibit excellent handling features when exposed to water, enhancing the removal of contaminants during adsorption processes [30].
The analyses were essential for understanding how changes in pressure affect the adsorbent structure.
Monolith pressure drop performance in a packed bed has a lower pressure drop because of its unique structure.
In contrast, zeolites are inorganic crystalline minerals with structured pores smaller than two nm.
The structured pores of natural clays exhibit excellent handling features when exposed to water, enhancing the removal of contaminants during adsorption processes [30].
The analyses were essential for understanding how changes in pressure affect the adsorbent structure.
Monolith pressure drop performance in a packed bed has a lower pressure drop because of its unique structure.
Online since: April 2009
Authors: Toshio Maruyama, Mitsutoshi Ueda, Kenichi Kawamura
Defect chemistry in scales is directly related to the sign of divergence and gives an
indication of the void formation behavior.
This paper described how well the divergence of ionic fluxes explaines void formation, the relation between the defect chemistry and the void formation in the scale. 2.
Relation between n t and the defect structure in metal oxides. [9] The sign of MOnt is identical to that of the last term in Eq. (31).
Table 1 summerizes the relation of defect structure and the microstructure development.
Defect chemistry in scales is directly related to the sign of divergence and gives an indication of the void formation behavior.
This paper described how well the divergence of ionic fluxes explaines void formation, the relation between the defect chemistry and the void formation in the scale. 2.
Relation between n t and the defect structure in metal oxides. [9] The sign of MOnt is identical to that of the last term in Eq. (31).
Table 1 summerizes the relation of defect structure and the microstructure development.
Defect chemistry in scales is directly related to the sign of divergence and gives an indication of the void formation behavior.
Online since: August 2009
Authors: Zhen Ni Du, Yong Cai Zhang
In air synthesis of Bi2S3 and PbS microcrystals by thermolysis of
single-source precursors
Zhen Ni Du, Yong Cai Zhang *
College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou city 225002,
China
Email: jane860605@yeah.net (Z.N.
Take Bi2S3 for example, the crystal structure of its precursor Bi-(DDTC)3 is shown in Scheme 1a [8], in which two ligands are omitted for clarity.
The crystal structure of Pb-(DDTC) is shown in Scheme.1b.
The PbS crystallites have the cubic structure.
Wells: Structural Inorganic Chemistry, fifth ed.
Take Bi2S3 for example, the crystal structure of its precursor Bi-(DDTC)3 is shown in Scheme 1a [8], in which two ligands are omitted for clarity.
The crystal structure of Pb-(DDTC) is shown in Scheme.1b.
The PbS crystallites have the cubic structure.
Wells: Structural Inorganic Chemistry, fifth ed.
Online since: August 2013
Authors: Zhong Yuan Zhang, Teng Teng Sa, Xiao Qiang Tie, Hong Lan, Wei Hua Zhang
Soil permeability, one of the important physical properties of soil, is closely related to water supply intensity, soil structure and soil moisture conditions.
At this moment, infiltration rate is affected not only by the level of soil properties, structure and profile, but also by the impact of soil moisture content.
Experimental methods Soil Agricultural Chemistry Analysis Handbook [2] by Lao Jiacheng described “the permeation tube method” and “the cutting ring method”, which are widely used to determine soil permeability coefficient.
In addition, if there are more organic matter, better soil aggregates and well-structured, the infiltration capacity is stronger.
Soil Agricultural Chemistry Analysis Handbook [M].Beijing: Agriculture Press, 1988: 220-288
At this moment, infiltration rate is affected not only by the level of soil properties, structure and profile, but also by the impact of soil moisture content.
Experimental methods Soil Agricultural Chemistry Analysis Handbook [2] by Lao Jiacheng described “the permeation tube method” and “the cutting ring method”, which are widely used to determine soil permeability coefficient.
In addition, if there are more organic matter, better soil aggregates and well-structured, the infiltration capacity is stronger.
Soil Agricultural Chemistry Analysis Handbook [M].Beijing: Agriculture Press, 1988: 220-288
Online since: June 2011
Authors: Xin Wang, Jun Wu Zhu, Wen Bin Zou
Therefore, GO can be considered as promising nanoscale building blocks for new materials due to its special surface properties and layered structure.
It is well known that graphene oxide is receiving increased attention due to its special surface properties, large specific surface area and layered structure for synthesis of GO-based nanocomposites [15, 16].
The powder X-ray diffraction (XRD) measurements of the samples were performed on a Bruker D8 Advance diffractometer with Cu Kα radiation at a slow scan rate of 0.03°/s to determine the structure.
Therefore, this structure of the composites of exfoliated GO and ZnO nanocrystals is consistent with the XRD results.
Materials Chemistry Vol. 17 (2007), p. 3678 [22] D.
It is well known that graphene oxide is receiving increased attention due to its special surface properties, large specific surface area and layered structure for synthesis of GO-based nanocomposites [15, 16].
The powder X-ray diffraction (XRD) measurements of the samples were performed on a Bruker D8 Advance diffractometer with Cu Kα radiation at a slow scan rate of 0.03°/s to determine the structure.
Therefore, this structure of the composites of exfoliated GO and ZnO nanocrystals is consistent with the XRD results.
Materials Chemistry Vol. 17 (2007), p. 3678 [22] D.