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Online since: June 2014
Authors: Ping Yang, Lai Jun Lu
The establishment of spectrum function involves comprehensive analysis problems of interdisciplinary mass geological data, for example, the earth science data, physics data, chemistry data, remote sensing data, and so on [2,3].
This article studies this issue, and puts forward an encoding method of geological spatial objects based on α tree structure.
In Figure1, In order to make a level of "project - category - reaction" expansion and extension, we use a multi-level, multi node of tree structure, so we call it “α tree structure” that is, The depth of the tree is α.
The encoding method based on α tree structure is applied to the gold mineral unit and element variable, Statistical models are built by using the quantification theory IV.
The scale chart of 21 mineral unit Conclusions 1 Encoding the multi hierarchy geological qualitative variables with α tree structure, it is a good quantitative method. 2 α tree structure and the quantification theory IV combined to predict mineral resources, have a higher success rate.
This article studies this issue, and puts forward an encoding method of geological spatial objects based on α tree structure.
In Figure1, In order to make a level of "project - category - reaction" expansion and extension, we use a multi-level, multi node of tree structure, so we call it “α tree structure” that is, The depth of the tree is α.
The encoding method based on α tree structure is applied to the gold mineral unit and element variable, Statistical models are built by using the quantification theory IV.
The scale chart of 21 mineral unit Conclusions 1 Encoding the multi hierarchy geological qualitative variables with α tree structure, it is a good quantitative method. 2 α tree structure and the quantification theory IV combined to predict mineral resources, have a higher success rate.
Online since: September 2008
Authors: Wolfgang J. Choyke, Leif I. Johansson, Charíya Virojanadara, Ulrich Starke, M. Hetzel
Atomic and Electronic Structure of the (2×1) and c(2×2) 4H-SiC(1 102)
Surfaces
C.
Starke1) 1) Max- Planck-Institut für Festkörperforschung, Heisenbergstr. 1, D-70569 Stuttgart, Germany: chariya@fkf.mpg.de 2) Department of Physics, Chemistry and Biology, Linköping University, S-58183, Linköping, Sweden 3) Department of Physics and Astronomy, University of Pittsburgh, Pittsburgh, PA 15260, USA Keywords: atomic structure, electronic structure, 4H-SiC(1 1 02), photoemission, STM, LEED, one dimension.
The atomic and electronic structure of 4H-SiC(1 1 02) surfaces were investigated using scanning tunneling microscopy (STM), low-energy electron diffraction (LEED) and photoemission (PES).
It should be emphasized that the model proposed here should be only viewed as a plausible starting point for a quantitative structure determination by crystallography or total energy calculations.
The electronic structure of this SiC(1 1 02)-c(2×2) phase is experimentally determined by angle resolved PES studies of the valence band revealing four surface states.
Starke1) 1) Max- Planck-Institut für Festkörperforschung, Heisenbergstr. 1, D-70569 Stuttgart, Germany: chariya@fkf.mpg.de 2) Department of Physics, Chemistry and Biology, Linköping University, S-58183, Linköping, Sweden 3) Department of Physics and Astronomy, University of Pittsburgh, Pittsburgh, PA 15260, USA Keywords: atomic structure, electronic structure, 4H-SiC(1 1 02), photoemission, STM, LEED, one dimension.
The atomic and electronic structure of 4H-SiC(1 1 02) surfaces were investigated using scanning tunneling microscopy (STM), low-energy electron diffraction (LEED) and photoemission (PES).
It should be emphasized that the model proposed here should be only viewed as a plausible starting point for a quantitative structure determination by crystallography or total energy calculations.
The electronic structure of this SiC(1 1 02)-c(2×2) phase is experimentally determined by angle resolved PES studies of the valence band revealing four surface states.
Online since: September 2008
Authors: Jun Suda, Tsunenobu Kimoto, Toru Hiyoshi, Tsutomu Hori
Schematic of various mesa structures.
Fabrication process of improved bevel mesa structure Figs. 2 (a) and 2 (b) show the typical mesa structure employed for high-voltage SiC devices (The JTE region is not indicated.).
Fig. 3 shows the fabrication process of improved bevel mesa structure.
The photo-resist was removed, and the SiC epilayer was etched by RIE with a CF4-O2 chemistry
SiO2 was removed by BHF, and the improved bevel mesa structure was formed.
Fabrication process of improved bevel mesa structure Figs. 2 (a) and 2 (b) show the typical mesa structure employed for high-voltage SiC devices (The JTE region is not indicated.).
Fig. 3 shows the fabrication process of improved bevel mesa structure.
The photo-resist was removed, and the SiC epilayer was etched by RIE with a CF4-O2 chemistry
SiO2 was removed by BHF, and the improved bevel mesa structure was formed.
Online since: January 2012
Authors: Lai Fei Cheng, Li Tong Zhang, Ke He Su, Xin Wang, Yan Li Wang, Yan Liu, Qing Feng Zeng
A Study of Predominated Pathway of Initial Processes in Chemical Vapor Deposition of Silicon-Carbide from Methyltrichlorosilane and Hydrogen System1
Xin Wang1, Yanli Wang1, Yan Liu1, Kehe Su1, Qingfeng Zeng2, Laifei Cheng2
and Litong Zhang2
1Key Laboratory of Space Applied Physics and Chemistry,
Ministry of Education, School of Natural and Applied Sciences,
Northwestern Polytechnical University, Xi’an, Shaanxi Province, China
xinwang@nwpu.edu.cn
2National Key Laboratory of Thermostructure Composite Materials
Northwestern Polytechnical University, Xi’an, Shaanxi Province, China
xxw3721@hotmail.com
Keywords: pyrolysis mechanism methyltrichlorosilane
Abstract.
The energy barriers and the reaction energies were evaluated with the accurate model chemistry method at G3(MP2) level after a non-dynamical electronic correlation detection.
Frequency analyses at the same level of theory were proceeded with the optimized geometries to determine the harmonic vibrational frequencies, the zero-point energies (ZPE) (scaled by 0.9631) and to confirm the structure being a stationary species or a transition state.
TS1(Cs,1A’ ) TS2(C1, 1A) TS3(C1, 1A) TS4(C1, 1A) TS5(C1, 1A) TS6(Cs, 1A’ ) TS7(Cs, 2A’ ) TS8(Cs, 2A’ ) TS9(C1, 2A) TS10(C1, 2A) TS11(C1, 2A) TS12(C1, 2A) TS13(C1, 2A) TS14(C1, 2A) TS15(C1, 2A) TS16(C1, 2A) TS17(C1, 2A) TS18(C1, 2A) TS19(C1, 2A) TS20(C1, 2A) TS21(C1, 2A) Fig. 1 Structure, symmetry and electronic state of transition states in MTS pyrolysis obtained at B3PW91/6-311G(d,p).
This mainly because a tight transition state structure is not favored by entropic effects at high temperatures.
The energy barriers and the reaction energies were evaluated with the accurate model chemistry method at G3(MP2) level after a non-dynamical electronic correlation detection.
Frequency analyses at the same level of theory were proceeded with the optimized geometries to determine the harmonic vibrational frequencies, the zero-point energies (ZPE) (scaled by 0.9631) and to confirm the structure being a stationary species or a transition state.
TS1(Cs,1A’ ) TS2(C1, 1A) TS3(C1, 1A) TS4(C1, 1A) TS5(C1, 1A) TS6(Cs, 1A’ ) TS7(Cs, 2A’ ) TS8(Cs, 2A’ ) TS9(C1, 2A) TS10(C1, 2A) TS11(C1, 2A) TS12(C1, 2A) TS13(C1, 2A) TS14(C1, 2A) TS15(C1, 2A) TS16(C1, 2A) TS17(C1, 2A) TS18(C1, 2A) TS19(C1, 2A) TS20(C1, 2A) TS21(C1, 2A) Fig. 1 Structure, symmetry and electronic state of transition states in MTS pyrolysis obtained at B3PW91/6-311G(d,p).
This mainly because a tight transition state structure is not favored by entropic effects at high temperatures.
Online since: June 2011
Authors: Hao Long Chen, Zin Ching Liou, Shian Jang Lin
The nano-scaled ZnO and CuO formation and its structure were characterized by means of grazing-incidence X-ray diffraction, Scanning Electron Microscopy (SEM) and Energy Dispersive Spectroscopy (EDS).
The possible growth mechanisms and structure of nano-scaled CuO and ZnO are discussed in this paper.
The possible growth mechanisms and structure of nano-scaled CuO and ZnO are discussed in this paper.
Yang: Materials Chemistry and Physics Vol. 93 (2005), p. 35 [5] L.B.
Gómez Pineda: Materials Chemistry and Physics Vol. 115 (2009), p. 110 [9] B.
The possible growth mechanisms and structure of nano-scaled CuO and ZnO are discussed in this paper.
The possible growth mechanisms and structure of nano-scaled CuO and ZnO are discussed in this paper.
Yang: Materials Chemistry and Physics Vol. 93 (2005), p. 35 [5] L.B.
Gómez Pineda: Materials Chemistry and Physics Vol. 115 (2009), p. 110 [9] B.
Online since: July 2015
Authors: Sureeporn Uttiya, Ornella Cavalleri, Michele Biasotti, Marcella Pani, Daniele Caviglia, Lorenzo Mattera, Maria Maddalena Carnasciali, Maurizio Canepa
Mesoporous Titanium Dioxide Thin Films on Quartz via Electrochemical Anodisation Process
Sureeporn Uttiya1, a, Ornella Cavalleri1, b, Michele Biasotti2, c, Marcella Pani3, d, Maria Maddalena Carnasciali3, 4, e, Daniele Caviglia5, f , Lorenzo Mattera1, g and Maurizio Canepa1, h
1Department of Physics (DIFI), University of Genoa, Italy
2National Institute of Nuclear Physics (INFN), University of Genoa, Italy
3Department of Chemistry and Industrial Chemistry (DCCI), University of Genoa, Italy
4 National Interuniversity Consortium of Materials Science and Technology (INSTM), Italy
5Department of Electrical, Electronic, and Telecommunications Engineering, and Naval Architecture (DITEN), University of Genoa, Italy
asureeporn.uttiya@spin.cnr.it, bcavalleri@fisica.unige.it, cmichele.biasotti@ge.infn.it, dmarcella@chimica.unige.it, ecarnasciali.unige@gmail.com, fdaniele.caviglia@gmail.com, gmattera@fisica.unige.it, hcanepa@fisica.unige.it
Keywords: Titanium Dioxide, Mesoporous
Anodised mesoporous TiO2 films have been characterized by Raman spectroscopy, which indicates the presence of well-defined peaks related to anatase structure.
After anodisation, mesoporous TiO2 films were heated up in an oven in order to investigate the relationship between heating temperature and TiO2 phase structures.
Anodised mesoporous TiO2 films have been characterized by Raman spectroscopy, which indicates the presence of well-defined peaks related to anatase structure.
After anodisation, mesoporous TiO2 films were heated up in an oven in order to investigate the relationship between heating temperature and TiO2 phase structures.
Online since: October 2012
Authors: A. Sheela, S. Ershadul Haque, B. Ramdas
Preparation and photocatalytic study of nano Cadmium sulphide
Sk Ershadul Haque a, B.Ramdas a and A.Sheela* a
aCentre for Excellence in Nano materials, Materials Chemistry Division,
School of Advanced Sciences, VIT University, Vellore-632 014, Tamil Nadu, India.
It shows cubic structure with the particle size ranging about 20nm.
Ohtani, Size and structure-dependent photocatalytic activity of jingle-bell-shaped silica-coated cadmium sulfide nanoparticles for methanol dehydrogenation, The Journal of Physical Chemistry.
It shows cubic structure with the particle size ranging about 20nm.
Ohtani, Size and structure-dependent photocatalytic activity of jingle-bell-shaped silica-coated cadmium sulfide nanoparticles for methanol dehydrogenation, The Journal of Physical Chemistry.
Online since: February 2014
Authors: Ihsan Budi Rachman, Deana Wahyuningrum
Ganesha 10 Bandung, Indonesia
2Organic Chemistry Research Division, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jl.
Figure. 1 The reaction scheme in synthesizing of compound (2) from compound (1) Comparing to other methods described, the solvent-less reaction and the use of atmospheric oxygen in this study to synthesis bibenzoyl showed more advantages than others, because this method would support the green chemistry aspects and more environmentally benign.
The structure of compound (3) has confirmed by spectroscopy analysis (FTIR, NMR and ESI-MS).
Crouch, Fundamentals of Analytical Chemistry, eight ed., Thomson, Canada, 2004, pp. 784-792
Figure. 1 The reaction scheme in synthesizing of compound (2) from compound (1) Comparing to other methods described, the solvent-less reaction and the use of atmospheric oxygen in this study to synthesis bibenzoyl showed more advantages than others, because this method would support the green chemistry aspects and more environmentally benign.
The structure of compound (3) has confirmed by spectroscopy analysis (FTIR, NMR and ESI-MS).
Crouch, Fundamentals of Analytical Chemistry, eight ed., Thomson, Canada, 2004, pp. 784-792
Online since: September 2013
Authors: Li Ping Ma, Wen Juan Xu
The approach of using CO2 as “reagent” to produce various kinds of chemicals fuels in organic chemistry areas appears to be particularly attractive[4], which are potential substitutes for traditional oil-based fuels.
Automatic thermometer 15.cooler 16.gas-liquid separator 17.precision pressure meter 18.back pressure value 19.six-way value 20.GC 2.4 Catalyst characterization analysis The pore structure and surface areas of catalysts were analyzed on an Autosorb-1-C(BET analyses ), Nitrogen adsorption isotherms were recorded at the temperature of liquid nitrogen(77 K).The samples were degassed at 413 K for 12hr firstly.
Zheng, Chemistry world,Vol.4(2002),p. 214 [2] E.
Sloczynski, R, Grabowski, A, Kozlowska, POLISH JOURNAL OF CHEMISTRY, Vol.75(2001) ,p.733 [7] L.
Automatic thermometer 15.cooler 16.gas-liquid separator 17.precision pressure meter 18.back pressure value 19.six-way value 20.GC 2.4 Catalyst characterization analysis The pore structure and surface areas of catalysts were analyzed on an Autosorb-1-C(BET analyses ), Nitrogen adsorption isotherms were recorded at the temperature of liquid nitrogen(77 K).The samples were degassed at 413 K for 12hr firstly.
Zheng, Chemistry world,Vol.4(2002),p. 214 [2] E.
Sloczynski, R, Grabowski, A, Kozlowska, POLISH JOURNAL OF CHEMISTRY, Vol.75(2001) ,p.733 [7] L.
Online since: January 2013
Authors: Na Lu, Shubhashini Oza
The analysis was conducted with a heating rate of 10°C/minute, from 25-500 °C in a nitrogen atmosphere
Results and Discussion
Fiber Surface Chemistry Change: The FTIR spectra of untreated and treated fibers have revealed the surface chemistry change of hemp fiber prior and post-treatment, as shown in Figure 1.
FTIR was used to understand the change in surface chemistry brought about by hemp surface treatment.
Ferguson, Composition, structure, and mechanical properties of hemp fiber reinforced composite with recycled high-density polyethylene matrix.
FTIR was used to understand the change in surface chemistry brought about by hemp surface treatment.
Ferguson, Composition, structure, and mechanical properties of hemp fiber reinforced composite with recycled high-density polyethylene matrix.