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Online since: February 2009
Authors: J.A. Juarez-Islas, M.A. Alvarez-Pérez, M. García-Hipolito, J. de La Fuente Hernández, H. Arzate, B. Carmona-Rodriguez, L.A. Ximenez-Fyvie, O. Alvarez-Fregoso
Zinc aluminate is a well-known wide bandgap semiconductor with a spinel structure and also with unique catalytic, mechanical and surface properties in the range of nanometers [14, 15].
The crystalline structured features of the deposited films were analyzed by X-ray diffractions (XRD) using a Siemens D-500 diffractometer with wavelength radiation of 1.5406 Å (Cu Kα).
Control at 5 and 14 days, revealed a smaller globular or spherules mineral formed by agglomerate structures (Figs. 4A and 4C for 5 and 14 days of culture respectively).
The inset magnification of the nanospherical globular-like structures of the mineral-like tissue onto ZnAl2O4 nanostructured material is showed by the arrow.
Joubert, in: Chemistry of Advanced Materials, edited by C.N.R.
Online since: March 2018
Authors: Akindele Okewale, Felix Omoruwuo
Introduction Corrosion of engineering structures and components in service has continued to be a huge source of concern to corrosion experts in the academia and industries.
The surface of metallic structure is attacked through the migration of ions away from the surface, resulting in material loss over time.
The adsorption process is affected by the chemical structures, allocation of charge in molecule, the nature and apparent charge of metal, and the type of aggressive media [25].
P., (2012), Synergistic inhibition effects between leaves and stem extracts of sida acuta and iodide ion for mild steel corrosion in 1 M H2SO4 solutions, Arabian Journal of Chemistry, 5 (3), 325 – 337
P., (2014), Gmelina Arborea Bark Extracts as a Corrosion Inhibitor for mild steel in an acidic environment, International Journal of Materials and Chemistry, 4(2):34 – 39
Online since: January 2016
Authors: Juha Larismaa, Simo Pekka Hannula, Qian Chen, Harri Lipiäinen
Combustion of polymeric materials is a complex process involving combinations of heat and mass transfer/diffusion, fluid dynamics and degradation chemistry.
The release of NH3 induces the formation of a foam structure in the polymer mixture.
Sample 4 presented the smallest expansion factor with a relatively dense structure (Figure 3 (e)).
Its structure after fire test (Figure 3 (f)) was similar to sample 1.
Hamerton, Recent developments in the chemistry of halogen-free flame retardant polymers, Prog.
Online since: June 2005
Authors: Dong Pyo Kim, Lan Young Hong
We reported on the synthesis and characterization of novel polymeric precursors for SiCBN and BCN ceramics via hydroboration of organosilazane and triethynylborazine with borazine, including the pyrolytic chemistry.[5-7] The liquid type of polymers were advantageous with higher processibility and stability in air than the previously reported products.
Results and discussion Fig. 1 shows representative SEM photographs of various porous SiCBN and BCN ceramics with flat plane or deep-seated structures.
It is obvious that the achieved porous SiCBN and BCN ceramic contain 3 dimensionally ordered structures with excellent regularity at least in short range.
In addition, the highly ordered porous ceramic structure was reproducibly obtained as the slower heating rates gently released the gaseous products during pyroysis.
In particular, below 600� it should be gently annealed to consolidate the infiltrated polymeric structure because major thermal decomposition with high mass loss was occurred at the range.
Online since: May 2020
Authors: Xiao Li Xi, Lin Yan Zhao, Zuo-Ren Nie, Yang Si Liu, You Shu Fan
The crystal structure of WO3 nanostructure was triclinic phase and their morphology was mainly one dimensional nanorods.
In modern synthesis and preparative chemistry, more and more hydrothermal methods are used to carry out the reactions which cannot happen under usual conditions, and various new compounds and new phases are synthesized.
Results and Discussion Effect of Hydrothermal Temperature and Time on the Crystal Structure of WO3 Nanostructures.
Wei, NO2 sensing properties of WO3 porous films with honeycomb structure, J.
Gao, Hierarchical structures of coated TiO2 nanoribbons with photodegradation and sedimentation properties, Int.
Online since: March 2013
Authors: Xu Duo Bai, Chen Wang, Li Guo Sun, Wen Hao Geng, Zhuo Ying Xie, Yuan Jin Zhao, Yuan Guan, Li Li Lv
Pereparation of hollow silica core/mesoporous silica shell monodisperse uniform spheres Lili Lv1,2, Wenhao Geng2, Cheng Wang1,a*, Zhuoying Xie3,Yuanjin Zhao3, Yuan Guan2, Xuduo Bai1, Liguo Sun2,3b* 1 Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education of the People’s Republic of China, Heilongjiang University, Harbin, 150080, P.R.
The hollow core and mesoporous structure were formed by calcination which acts as the removable templates.
In this paper, we reported a method to synthesize monodisperse hollow mesoporous silica of well-defined core/shell structure.
By comparing the PS/silica/CTAB composite spheres calcined before (Fig.1c) and after (Fig.1d), no obvious shrinkage was observed, indicating the structure of the spheres are stable.
The well-defined step between 0.4 and 0.6 of P/P0 indicates a highly narrow mesoporous structure.
Online since: January 2014
Authors: Yu Ming Li, Tao Yuan
Beginning from the manufacture process of metal rubber material, the structure and electromagnetic shielding mechanic were studied.
Using the microscope we can see that its internal frame is connected disorderly by a considerable volume of metal silk, and it is just like the net structure of rubber’s microscopic view.
It is because that the structure of metal rubber material is irregular and special.
Shielding Efficiency fitting curve Summary Researching from the manufacture process of metal rubber material, the structure and electromagnetic shielding mechanics were analyzed, and the mathematic model of electromagnetic shielding efficiency was deduced.
References [1] Shiyuan Yang, Theory and practice of electromagnetic shielding[M], Defence Industry Publishing, 2006. 12-16 [2] Jujun Shen, Research on shielding efficient of conducting material[J], Electron Mechanical Engineering, 2006 (5) 10-12 [3] Yuming Li, Hongbai Bai, Zheng jian, Deformation behavior of metal rubber material, Progresses in fracture and strength of materials and structures[J], Key Engineering Materials, part 1, 2006. 571-574 [4] Ming Wei, Defending technique of static and electromagnetic[M], Ordnance Engineering University,2011. 39-42 [5] Lee Y M, Comparison of SE measurements between MIL-STD-285 and the ASTM Standard E1851A[J], IEEE International Symposium on Electromagnetic Compatibility,1998 (2). 1053-1058 [6] Shunhua Liu, Electromagnetic shielding and wave absorbing material[M], Chemistry Industry Publishing, 2007. 67-69 [7] Yu Chen, Junming Liu, Electromagnetic shielding material used at launching box[J], Packing Engineering, 2008(12).270-271
Online since: July 2011
Authors: Li Liu, Li Wei Xu, Yu Dong Huang
However, ageing of coating was dependent on its structure.
These may include the enhancement of mechanical properties, visual appearance or corrosion resistance or may provide special magnetic of optical properties[1-3].The degree of environmental degradation that occurs in a fiber reinforced polymer composite structure is linked directly with the amount of moisture that is absorbed.
Experiments Materials The epoxy resin (E-51) used in this study was supplied by Nantong Xingchen Synthesized Resin Institution, which structure was shown as following: The E-type glass fibers investigated in current studies were commercial.
Moisture can potentially cause debonding at the fiber/matrix interface not only through chemical attack and reaction, but also through mechanochemical effects such as osmotic pressure [8].The mechanism of attack at the interface is decisively governed by the chemistry, structure, morphology, and modes of failure at that interface[9].
Collings, Composite Structures, Vol. 5(1989), p. 213
Online since: April 2012
Authors: Zhao Ping Chen, Hang Yu Gu, Ying Wang
Different pretreatment methods have led to various surface structures, which resulted in various effects on removal heavy metals.
Introduction Sepiolite is a Mg-silicate with fibrous morphology, whose structure consists of talc-like ribbons parallel to the fiber axis.
This special structure brings about a high adsorption capacity.
Effect of Modification Degree on the Structure of Sepiolite When sepiolite was modified by 15% hydrochloric acid, the various RMR was obtained under different modification time.
XRD shows that during the modification, if the RMR is too high, the octahedral part in sepiolite structure transforms into tetrahedron.
Online since: October 2010
Authors: Zhou Cheng Wang, Zheng Bing Qi, Xuan Wang, Kui Zhang, Guang Hui Yue, Dong Liang Peng
Investigation on the Structure and Properties of TiAlN Coatings Deposited by DC Reactive Magnetron Sputtering Xuan Wang1,a, Kui Zhang1,b, Guanghui Yue1,c, Dongliang Peng1,d*, Zhengbing Qi2,e, Zhoucheng Wang2,f* 1 College of Materials, Xiamen University, Xiamen, China 2 College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, China ayuyuan@xmu.edu.cn, bkzhang@xmu.edu.cn, cyuegh@xmu.edu.cn, d*dlpeng@xmu.edu.cn, ezbqi_xmu@126.com, f*zcwang@xmu.edu.cn Keywords: TiAlN; coatings; vapor deposition; microstructure; hardness.
The TiAlN coating shows the highest hardness at a certain N2 flow rate when it has the most compact structure.
Increasing R (N2) further, TiAlN coatings turn a single B1-NaCl type cubic structure.
Additionally, the cross-section morphologies of TiAlN coatings turn from a dense fibrous structure to a bulky columnar structure with increasing R (N2),as shown in the cross-section images (Fig. 3b-d).The TiAlN coatings show different microstructural morphology as R (N2) increased, and we acquired the most compact coatings at R (N2) =10%.
Additionally, the cross-section morphologies of TiAlN coatings turn from a dense fibrous structure to a bulky columnar structure with increasing R (N2),as shown in the cross-section images (Fig. 3b-d).The TiAlN coatings show different microstructural morphology as R (N2) increased, and we acquired the most compact coatings at R (N2) =10%.