Paper Titles
Thermodynamic Analysis of Ethanol Diesel-Oil Alternative Fuel
p.1005
Abnormal Heat Triggered by Pressure Change in a D/Pd Gas-Loading System
p.1011
Analysis of Chinese Natural Gas Interchangeability Predicted by Weaver Indices
p.1017
Crystallitic Structure and Thermodynamics of Magnesium-Based Hydrogen Storage Materials from Reactive Milling under Hydrogen Atmosphere
p.1021
Effects of FEC Additive on the Low Temperature Performance of LiODFB-Based Lithium-Ion Batteries
p.1025
Influence of Eu Substitution for Y on the High Temperature Electric Transport Properties of YBaCo4O7+δ
p.1029
Magnesium Hydride of Orthorhombic Crystal from High-Energy Ball Milling under Hydrogen Atmosphere
p.1033
One-Pot Synthesis of Carbon-Coated ZnFe2O4 with Excellent Electrochemical Performance as an Anode in Lithium Ion Battery
p.1037
Pyrolysis Characteristics of Long Flame Coal
p.1042

Effects of FEC Additive on the Low Temperature Performance of LiODFB-Based Lithium-Ion Batteries

Article Preview

Abstract:

The low temperature performance of LiFePO4/Li cells based on lithium oxalyldifluoroborate (LiODFB) with fluoroethylene carbonate (FEC) as addictive have been investigated. The result of ionic conductivity test shows that the use of 5% FEC can improve the conductivity of both LiPF6 and LiODFB electrolytes at low temperature. The electrochemical measurements of the cells show that the use of FEC can effectively improve the discharge capacity and has better kinetics characteristics and low temperature performance. The LiODFB cell with FEC also exhibits excellent cycling retention of 88.8% after 50 cycles at-20°C.

You might also be interested in these eBooks
Applied Energy Technology View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 724-725)

Pages:

1025-1028

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.724-725.1025

Citation:

Cite this paper

Online since:

August 2013

Authors:

Rong Xiang, Fa Qiang Li, Guo Feng Jia, Zheng Jun Peng, Qin Zhuge

Keywords:

FEC, LiODFB, Lithium-Ion Battery, Low Temperature Performance

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

References

[1] K. Xu, U. Lee, S.S. Zhang, J.L. Allen, T.R. Jow, Electrochem. Solid-State Lett. 7(2004)A273.

Google Scholar

[2] K. Xu, U. Lee, S.S. Zhang, T.R. Jow, in: 208th ECS Meeting Abstracts, Los Angeles, CA, 16-21, 2005, 219.

Google Scholar

[3] S.S. Zhang, K. Xu, T.R. Jow, Electrochem. Commun4(2002)928.

Google Scholar

[4] J. Liu, Z.H. Chen, S. Busking, K. Amine, Electrochem. Commun 9(2007)475.

Google Scholar

[5] S.S. Zhang, Electrochem. Commun8(2006)1423.

Google Scholar

[6] J.L. Shen, X.L. Zhang and Z.Y. Yang, C.N. Patent 101, 717, 389. (2009).

Google Scholar

[7] C.W. Yng, F. Wu, B.R. Wu, Y.H. Ren and J.W. Yao, Electrochemistry 01(2011)63.

Google Scholar

[8] J. Xu, W.H. Yao and Y.W. Yao, Acta Phys-Chim Sin 25(2009)201.

Google Scholar

[9] A. Yamada, M. Hosoya, S.C. Chuang, Y. Kudo, K. Hinokuma, K.Y. Liu, Y. Nishi, J PowerSources 119-121(2003)232.

Google Scholar

[10] J. Li, K.Y. Xie, Y.Q. Lai, Z.A. Zhang, F.Q. Li, X. Hao, X.J. Chen, Y.X. Liu, J. PowerSources 195(2010) 5344.

Google Scholar

[11] M.S. Ding, J. Chem. Eng. Data 49(2004)1102.

Google Scholar

[12] M.S. Ding, T.R. Jow, J. Electrochem. Soc. 151(2004)A2007.

Google Scholar

[13] Z.A. Zhang, X.J. Chen, F.Q. Li, Y.Q. Lai, J. Li, P. Liu, X.Y. Wang, J. PowerSources195(2010) 7397.

Google Scholar

[14] K. Xu, Chem Rev 104(2004)4303.

Google Scholar

[15] S.S. Zhang, K, Xu, T.R. Jow, J. PowerSources160(2006) 1439.

Google Scholar

[16] L. X Hu, C. Wang, X.Q. Chen, Y.L. Zhang, New chemical materials 7(2011)62.

Google Scholar