Synthesis of Nano Machines Based on Catenanes and Rotaxanes

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Abstract:

A nanomachine is an assembly of a discrete number of supramolecular components designed to perform mechanical like movements as a consequence of appropriate external stimuli. In this research work we wish report synthesis of a part of nanomachines are based on interlocked macrocycle named rotaxanes, catenanes, pseudorataxane and knots, that Bis aza thiacrown compound (5) was synthesized by macrocyclic diamide (4) and 2, 6-dicarbonyldicholoride pyridine in dry CH2Cl2 and was refluxed in presence of Et3N in good yield. The structures of these compounds were confirmed by IR, 1H NMR, 13C NMR and elemental analysis.

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3807-3809

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October 2011

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] M. R. Sambrook, P. D. Beer, J. A. Wisner, R. L. Paul, and A. R. Cowley, Vo l. 126, JACS Comunications, 2004, PP. 15384-15385.

Google Scholar

[2] P. R. Ashton, R. A. Bartsch, S. J Cantrill, R. E. Hanes, S. K. Hickingbottom, J. N. Lowe, J. A. Preece, J. F. Stoddart, V. S. Talanov and Z. Wang, Vol. 40, Tetrahedron Letters, 1999, pp.3661-3664.

DOI: 10.1016/s0040-4039(99)00553-5

Google Scholar

[3] V. Balzani, M. Gomez-Lopez and J. F. Stoddart, Vol. 31, Acc. Chem. Res, 1998, pp.405-414.

Google Scholar

[4] A. Shockravi and S. Bavili Tabrizi, Vol. 52, phenomena macrocycle, 2003, pp.223-227.

Google Scholar

[5] Y. L. Huang, C. Lin, P. Cheng, C. Lai and S. Vol. 49, 2008 pp.1665-1669.

Google Scholar

[6] A. Shockravi and S. Bavili Tabrizi, Vol. 52, 2003, Phn Macrocyclet, pp.223-227.

Google Scholar