Influence of BaB2O4 Glass on the Synthesis of Ba2Ti9O20 Ceramics

Article Preview

Abstract:

The effects of BaB2O4 glass on the synthesis of Ba2Ti9O20 were studied. The doping amounts of BaB2O4 varied from 0 to 10wt% and the compositions were sintered in the temperature range of 1200~1280C for 2h. The benefit of BaB2O4 addition to the densification of the ceramics is apparently due to the liquid phase which accelerates the migration of reactant species, which results in the decreasing of the sintering temperature. With the amount of BaB2O4 increased, the microstructure and properties of the ceramics were also changed: BaTi4O9 became the major phase instead of Ba2Ti9O20, bulk density decreased, and dielectric constant decreased accordingly, while dielectric loss kept small.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

2257-2260

Citation:

Online since:

October 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] H.M. O'Bryan, A new BaO–TiO2 compound with temperature-stable high permittivity and low microwave loss, J. Am. Ceram. Soc., Vol. 57 (1974), p.450–453.

DOI: 10.1111/j.1151-2916.1974.tb11380.x

Google Scholar

[2] J.K. Plured, D.F. Linn, Ba2Ti9O20 as a microwave dielectric resonator, J. Am. Ceram. Soc., Vol. 59 (1975), p.418–420.

Google Scholar

[3] K.W. Kirby, B.A. Wechsler, Phase relations in the barium titanate–titanium oxide system, J. Am. Ceram. Soc., Vol. 74 (1991), p.1841–1847.

DOI: 10.1111/j.1151-2916.1991.tb07797.x

Google Scholar

[4] H.M. O'Bryan, J. Thomson, Temperature-dependent phase boundaries for BaTi4O9, Ba4Ti13O30, and Ba6Ti17O40, J. Am. Ceram. Soc., Vol. 68 (1985), p.70–72.

Google Scholar

[5] Cheng, C. M., Yang, C. F. and Lo, S. H., Sintering and dielectric properties of Ba2Ti9O20 microwave ceramics by glass addition. Jpn.J. Appl. Phys., Vol. 86(1997), p.1604–1607.

Google Scholar

[6] Kanai, H., Furukawa, O. and Nakamura, S. I., Effect of B2O3 and SiO2 on dielectric properties and reliability of a lead-based relaxor dielectric. J. Mater. Sci., Vol. 31(1996), p.1609–1614.

DOI: 10.1007/bf00357871

Google Scholar

[7] Hirata, A. and Yamaguchi, T., Interfacial reaction of BaTiO3 ceramics with PbO–B2O3 glasses. J. Am. Ceram. Soc., Vol, 80(1997), p.79–84.

DOI: 10.1111/j.1151-2916.1997.tb02793.x

Google Scholar

[8] Kuromitsu, Y., Wang, S. F., Yoshikawa, S. and Newnham, R. E., Evolution of interfacial microstructure between barium titanate and binary glasses. J. Am. Ceram. Soc., Vol, 77(1994), p.852–856.

DOI: 10.1111/j.1151-2916.1994.tb05379.x

Google Scholar

[9] Tillmanns, E., Hofmeister, W. and Baur, W. H., Crystal structure of the microwave dielectric resonator Ba2Ti9O20. J. Am. Ceram. Soc., Vol, 66(1983), p.268–271.

DOI: 10.1111/j.1151-2916.1983.tb15712.x

Google Scholar

[10] O'Bryan, H. M. Jr, Grodkiewicz, W. H. and Bernstein, J. L., J. Am. Ceram. Soc., Vol, 63(1980), pp.309-311.

Google Scholar