Functionalized Ionic Liquids as Lubricants for Steel-Steel Contact

Article Preview

Abstract:

A new series of functionalized ionic liquids containing ester-group were synthesized through a typical two-step way. The physicochemical properties of the functionalized ionic liquids were studied and the tribological properties of them as lubricants for steel-steel contact were evaluated on an SRV friction and wear tester and compared with the perfluoroalkylpolyether (PFPE), a low-volatility and fluorine containing lubricant, and a conventional ionic liquid, 1-butyl-3-methy imidazolium tetrafluoroborate (LB104), which is nonfunctionalized. Results showed that all the ionic liquids studied in this paper have better lubricities than PFPE as lubricants for steel-steel friction pairs. Functionalized ionic liquids show worse friction reducing abilities at relatively lower loads, which could be ascribed to their higher viscosities, but they always exhibit better anti-wear abilities than LB104. The possible friction mechanisms were discussed.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

630-634

Citation:

Online since:

November 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Ichiro Minami. Ionic liquids in tribology[J]. Molecules. 2009, 14(6): 2286-2305.

DOI: 10.3390/molecules14062286

Google Scholar

[2] Bermudez M D, Jimenez A E, Sanes J, etal. Ionic liquid as advanced lubricant fluids[J]. Molecules. 2009, 14(8): 2888-2908.

DOI: 10.3390/molecules14082888

Google Scholar

[3] WANG H Z, LU Q M, YE C F, etal. Friction and wear behaviors of ionic liquid of alkylimidazolium hexafluorophosphates as lubricants for steel/steel contact[J]. Wear. 2004, 256(1-2): 44-48.

DOI: 10.1016/s0043-1648(03)00255-2

Google Scholar

[4] LU Q M, WANG H Z, YE C F, etal. Room temperature ionic liquid 1-ethyl-3-hexylimidazolium-bis(trifluoromethylsulfonyl)-imide as lubricant for steel–steel contact[J]. Tribology International. 2004, 37(7): 547-552.

DOI: 10.1016/j.triboint.2003.12.003

Google Scholar

[5] MU Z G, ZHOU F, ZHANG S X, etal. Effect of the functional groups in ionic liquid molecules on the friction and wear behavior of aluminum alloy in lubricated aluminum-on-steel contact[J]. Tribology International. 2005, 38(8): 725-731.

DOI: 10.1016/j.triboint.2004.10.003

Google Scholar

[6] ZHU L Y, CHEN L G, WANG B, etal. Tribological behaviour of an ester-group functionalized ionic liquid as a lubricant[J]. Acta Petrolei sinica (Petroleum Processing Section). 2011, 27(2): 292-297.

Google Scholar

[7] ZHU L Y, CHEN L G, ZHOU X, etal. Synthesis and characterization of the functionalized ionic liquid containing ester-group and its physicochemical properties[J]. Acta Petrolei sinica (Petroleum Processing Section). 2009, 25(suppl. ): 10-14.

Google Scholar

[8] Fredlake C P, Crosthwaite J M, Hert D G, etal. Thermophysical prooerties of imidazolium-based ionic liquids[J]. Journal of Chemical and Engineering Data. 2004, 49(4): 945-964.

DOI: 10.1021/je034261a

Google Scholar