The Preparation and the Properties of CS/PVP Composite Hydrogel Microspheres

Article Preview

Abstract:

According to the gelatification of sodium hydroxide ethanol solution, the chitosan (CS)/polyvinylpyrrolidone (PVP) composite hydrogel microspheres have been prepared in this paper. Meanwhile, the influence of PVP content and PH on the swelling property and the adsorption Cr(Ⅵ) effect of CS/PVP hydrogel microspheres has been also discussed. The results have shown that the introduction of PVP has significantly improved the swelling property of CS. When the CS content is 2.5% and the PVP content is 5%, the swelling rate of microspheres will be the maximum. The swelling property and the adsorption property of microspheres have shown certain pH sensitivity. And the SEM has also indicated that the inside of CS/ PVP composite hydrogel microspheres is the loose network structure, which is conducive to the swelling and the adsorption.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

393-398

Citation:

Online since:

January 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] B.S. Zhou, Technologies in Industrial Wastewater Treatment, Chemical Industry Press, Beijing, (2003).

Google Scholar

[2] R.T. Yang, Adsorbents Fundamentals and Applications (L.P. Ma, P. Ning, S.L. Tian, Trans. ), Higher Education Press, Beijing, (2010).

Google Scholar

[3] Hu Zhi-biao, Chen Jie-bin et al. Adsorption properties of the bamboo-charcoal for chromium (VI)[J]. Journal of Functional Materials, 2008, 39(3):523-525.

Google Scholar

[4] Sudipta Chatterjee, Tania Chatterjee, Seung H. Woo. A new type of chitosan hydrogel sorbent generated by anionic surfactant gelation[J]. Bioresource Technology 101 (2010) 3853–3858.

DOI: 10.1016/j.biortech.2009.12.089

Google Scholar

[5] Chen Xue-mei, Xiao Wen-sheng, Liu Xu-qing. Treatment of Chrome Wastewater with Cross-linked Chitosan Sorbent[J]. Environmental Science & Technology, 2006, 29(4): 74-75.

Google Scholar

[6] Jie Dai, Han Yana, et al. Simple method for preparation of chitosan/poly(acrylic acid) blending hydrogel beads and adsorption of copper(II) from aqueous solutions[J]. Chemical Engineering Journal . 2010, (165): 240–249.

DOI: 10.1016/j.cej.2010.09.024

Google Scholar

[7] Yi Guo-bin, Cui Ying-de et al. Synthesis and swelling behavior of NVP grafted chitosan hydrogel[J]. Journal of Chemical Industry and Engineering, 2005,56(9):1783-1788.

Google Scholar

[8] Xiao Ling, Ben Wei-wei. Preparation and Adsorption Properties of Chitosan Immobilized Tannin Microspheres[J]. Journal of Wuhan University (Science Edition), 2006, 52(2): 189-192.

Google Scholar

[9] Tang Lan-mo, Fu Mai-qun et al. Study on the Removel of Chromium (VI) in Solution by Chitosan and its Adsorption Mechanism[J]. Chemical World, 2001(2): 59-62.

Google Scholar

[10] Sun Sheng-ling, Wang Li et al. Process in the Research on Metal Complexation of Chitosan its Derivatives[J]. Polymer Bulletin, 2005(6): 32-35.

Google Scholar