Environmental Friendship Synthesis of Ultra-Fine Silver Particles for Electromagnetic Shielding Materials

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A room-temperature ionic liquid, 1-n-butyl-3-methylimidazolium tetrafluoroborate([bmim]BF4), was synthesized with two-step method, and putting p-benzenediol and AgNO3 ethanol solution into [bmim]BF4, ultra-fine silver powder were prepared successfully in this paper. The effects of the temperature and material mol ratio of AgNO3 and p-benzenediol on the shape of products were studied. The products were characterized by XRD, SEM, IR and TEM. The results showed that the particle size of silver was much smaller and in the range of nanometers, and had narrowly, uniform distribution, which indicates that the synthesis method using ionic liquid, is the better “green” and “environment friendship” method to prepare ultra-fine silver powder for electromagnetic shielding.

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97-100

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July 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] M. Xie, Y.C. Yang, L.L. Chen, et al. The study on silver powder materials used for electromanetic shielding[J]. J. of Rare Metals(in Chinese), Vol. 30, No. 4(2009), pp.5-8.

Google Scholar

[2] Y.H. Song. Study on the preparartion ofsSpherical nano silver powder[J]. J. of Rare Metal Materials and Engineering(in Chinese), Vol. 36, No. 4 (2007) , pp.709-712.

Google Scholar

[3] J. Li, S.M. Zhang, Z.S. Wu, et al. The preparation and properties of nano silver powder in functional ionic liquid[J]. J. of Inorganic Chemistry(in Chinese), Vol. 22, No. 1(2006), pp.65-68.

Google Scholar

[4] M. Antonietti, D. Kuang, B. Smarsly. Ionic liquids for the convenient synthesis of functional inorganic nanoparticles[J]. Angew. Int. Ed, Vol. 43(2004), pp.4998-4999.

DOI: 10.1002/anie.200460091

Google Scholar

[5] Y.Q. Yang, Y.L. Zhou, H.Z. Ma, et al. The preparation and structure characterization of nano silver in room-temperature ionic liquid[J]. Yunnan Chemical Engineering, Vol. 35, No. 1(2008), pp.8-11.

Google Scholar

[6] S.M. Zhang, C.L. Zhang, H.X. Dang. The preparation and structure characterization of nano silver in room-temperature ionic liquid[J]. J. of Physical Chemistry, Vol. 20, No. 5(2004), pp.554-556.

Google Scholar