Tribological Study of Xanthate-Containing Acetic Ester as Additives in Hydrogenated Oil

Article Preview

Abstract:

A novel ester derivative, dodecyl xanthate acetic dodecyl xanthate ester(DXAD) was synthesized and it’s tribological behaviors as additives in hydrogenated oil, were evaluated using a four-ball tester. Results show that the compound possesses good antiwear performance, extreme pressure capacity, and good friction-reducing property. The action mechanism was estimated through analysis of the worn surface with X-ray photoelectron spectroscopy (XPS) and Scanning Electron Microscope (SEM). The results of XPS and SEM analyses illustrate that the prepared compound as an additive in hydrogenated oil forms a protective film containing ferric sulfide and ferric sulfate compounds on the rubbed surface.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

123-127

Citation:

Online since:

November 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] He Zhongyi, Zhan Weiqiang, etal, Study of the synergistic effect of a triazine-dithiocarbamate derivative with TCP in vegetable oil, Journal of Synthesis Lubrication, 2005, 21(4), 287-297.

DOI: 10.1002/jsl.3000210403

Google Scholar

[2] Milner J L, Phillips R L, Ozbalik N, et al. Odor reduction of lubricant additives packages[P]. US 6133207, 2000, 10, 17.

Google Scholar

[3] Jianchang Li, Jing Li, Jincan Yan, etal, The Tribological Chemistry of Novel Triazine Derivatives as Additives in Synthetic Diester , Tribology Transactions, 2011, 54(5): 793-799.

DOI: 10.1080/10402004.2011.604760

Google Scholar

[4] Weijiu Huang, Junxiu Dong, Guangfeng Wu, etal, A study of S-[2-(acetamido) benzothiazol-1-yl] N, N -dibutyldithiocarbamate as an oil additive in liquid paraffin. Tribology International. 2004, 37: 71–76.

DOI: 10.1016/j.triboint.2003.07.001

Google Scholar

[5] Xiong Liping, He Zhongyi, Zhou Xiang, etal, Tribological Synergy Study of a Benzotrizole Derivative and Tricresyl Phosphate, Lubrication Engineering, 2009, 5: 13-17.

Google Scholar

[6] Moulder S F, Stickle W F, Sobol P E, et al. Physical Electronics Division: Handbook of X-ray Photoelectron Spectroscopy. Minnesota: Perkin-Elmer, (1992).

Google Scholar

[7] Wang, Yonggang; Li, Jiusheng; Ren, Tianhui, Tribological study of a novel borate ester containing dialkylthiophosphate group as multifunctional additive, Industrial Lubrication and Tribology, 2009, 61(1): 33-39.

DOI: 10.1108/00368790910929511

Google Scholar

[8] K. Komvopoulos, V. Chiaro, B. Pakter, et al, Antiwear tribofilm formation on steel surface lubricated with gear oil containing borate, phosphorus, and sulfur additives, Tribology Transactions. 2002, 45(4): 568-575.

DOI: 10.1080/10402000208982589

Google Scholar