A Study of Fabrication Nanopowders of Cu2ZnSnS4 for Solar Cells Absorbers

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Abstract:

In this study, fixed mole number proportion of CuCl, ZnCl2, SnCl2‧2H2O and sulfide compounds and the reacted solution are added to the autoclave, then the CZTS powders are prepared by changing the heating temperature and time. It is found from the experimental results that better result with less secondary phase can be obtained at the heating temperature 250°C and heated time of 36 hours.

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261-264

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January 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] T. K. Todorov, K. B. Reuter, and D. B. Mitzi, Adv. Mater. 22, E156 (2010).

Google Scholar

[2] Moriya, K., Tanaka, K., Uchiki, H., Fabrication of Cu2ZnSnS4 thin film solar cell prepared by pulsed laser deposition. Jpn. J. Appl. Phys. 46, 5780–5781(2007).

DOI: 10.1143/jjap.46.5780

Google Scholar

[3] Seol, J.S., Lee, S.Y., Lee, J.C., Nam, H.D., Kim, K.H., Electrical and optical properties of Cu2ZnSnS4 thin films prepared by rf magnetron sputtering process. Sol. Energy Mater. Sol. Cells 75, 155–162(2003).

DOI: 10.1016/s0927-0248(02)00127-7

Google Scholar

[4] R.B.V. Chalapathy, Gwang Sun Jung, Byung Tae Ahn, Fabrication of Cu2ZnSnS4 films by sulfurization of Cu/ZnSn/Cu precursor layers in sulfur atmosphere for solar cells, Solar Energy Materials & Solar Cells 95 3216–3221, (2011).

DOI: 10.1016/j.solmat.2011.07.017

Google Scholar

[5] F. Liu, Y. Li, K. Zhang, B. Wang, C. Yan, Y. Lai, Z. Zhnag, J. Lie, Y. Lu, Insitu growth of Cu2ZnSnS4 thin films by reactive magnetron co-sputtering, Sol. Energy Mater. Sol. Cells 94–12, 2431–2434(2010).

DOI: 10.1016/j.solmat.2010.08.003

Google Scholar

[6] Fahrettin Yakuphanoglu, Nanostructure Cu2ZnSnS4 thin film prepared by sol–gel for optoelectronic applications, Solar Energy 85, 2518–2523(2011).

DOI: 10.1016/j.solener.2011.07.012

Google Scholar

[7] N. Kamoun, H. Bouzouita, B. Rezig, Fabrication and characterization of Cu2ZnSnS4 thin films deposited by spray pyrolysis technique, Thin Solid Films 515, 5949–5952(2007).

DOI: 10.1016/j.tsf.2006.12.144

Google Scholar

[8] Doyoung Park, Dahyun Nam, Sunghun Jung, SeJin An, Jihye Gwak, Kyunghoon Yoon, Jae Ho Yun, Hyeonsik Cheong, Optical characterization of Cu2ZnSnSe4 grown by thermal co-evaporation, Thin Solid Films 519, 7386–7389(2011).

DOI: 10.1016/j.tsf.2011.01.142

Google Scholar

[9] Minsung Jeon, Tomohiro Shimizu, Shoso Shingubara, Cu2ZnSnS4 thin films and nanowires prepared by different single-step electrodeposition method in quaternary electrolyte, Materials Letters 65, 2364–2367(2011).

DOI: 10.1016/j.matlet.2011.05.003

Google Scholar

[10] A.V. Moholkar, S.S. Shinde, A.R. Babar, Kyu-Ung Sim, Hyun Kee Lee, K.Y. Rajpure, P.S. Patil, C.H. Bhosale, J.H. Kim, Synthesis and characterization of Cu2ZnSnS4 thin films grown by PLD: Solar cells, Journal of Alloys and Compounds 509, 7439–7446(2011).

DOI: 10.1016/j.jallcom.2011.04.074

Google Scholar

[11] Q. Guo, H.W. Hillhouse, R. Agrawal, Synthesis of Cu2ZnSnS4 nano crystal ink and its use for solar cells, J. Am. Chem. Soc. 131, 11672–11673(2009).

DOI: 10.1021/ja904981r

Google Scholar

[12] Cui Y, Zuo S, Jiang J, Yuan S, Chu J. Sol Energy Mater Sol Cells(2011).

Google Scholar