Synthesis and Properties of IPDI-TMP Waterborne Curing Agent

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Abstract:

The waterborne curing agent was prepared by reaction of isophorone diisocyanate (IPDI), polyethylene glycol single methyl ether(MPEG) and trimethylol propane (TMP). The synthesis process of curing agent were monitored by Fourier transform infrared (FTIR) spectroscopy, and initial tack, peel strength, heat aging resistance, shear strength, creep resistance of all samples with different curing agent content were measured. The results showed that the curing agent dispersed well as an incorporated state in the waterborne polyurethane. The water and ethanol absorption decreased with increasing curing agent content, the peel strength was significantly increased up to 6.7 N/mm.

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24-27

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February 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] Pion Florian, Kishore K. Jena, Shaik Allauddin, Ramanuj Narayan. Preparation and Characterization of Waterborne Hyperbranched Polyurethane-Urea and Their Hybrid Coatings, Ind. Eng. Chem. Res. 49 (2010) 4517-4527.

DOI: 10.1021/ie900840g

Google Scholar

[2] G.Q. LU, J.Z. Sun, Q.Y. Zhou. Synthesis and Characterization of Waterborne Epoxy Curing Agent Modified by Silane, Chinese Journal of Chemical Engineering. (15) 2007 899-905.

DOI: 10.1016/s1004-9541(08)60022-1

Google Scholar

[3] Jintao Wan, Zhiyang Bua, CunJin Xua, etal. Preparation, curing kinetics, and properties of a novel low-volatile starlike aliphatic-polyamine curing agent for epoxy resins, Chemical Engineering Journal. 171 (2011) 357-367.

DOI: 10.1016/j.cej.2011.04.004

Google Scholar

[4] Yeh J M, Yao C T , Hsieh C F. Preparation and properties of amino terminated anionic waterborne polyurethane silica hybrid materials through a solgel process in the absence of an external catalyst, European Polymer Journal. 44 (2008) 2777-2783.

DOI: 10.1016/j.eurpolymj.2008.06.040

Google Scholar

[5] Xiaojuan Lai, Xiaorui Li, Lei Wang. Synthesis and characterizations of waterborne polyurethane modified with 3-aminopropyltriethoxysilane, Polym. Bull. 65 (2010) 45-57

DOI: 10.1007/s00289-009-0233-x

Google Scholar