Synthesis of Core-Shell Particles Consisted of Polysiloxane and Poly(butyl methacrylate-stryrene-acrylonitrile) by Microemulsion Polymerization

Abstract:

Latexes with poly(butyl methacrylate-stryrene-acrylonitrile) rich in the shell and PDMS rich in the core were prepared based on microemulsion polymerization. Vinyl monomers were introduced to generate slightly crosslinked particles, then, etamethyltetraeyelosiloxane（D4）was added slowly to form the core. In the process, internal resistance must be overcome when the D4 entered into the polymer to form the core. The compatibility between the two polymer phases was changed by introducing acrylonitrile and the effect of different methods on forming latex particles was discussed.

• Periodical: Applied Mechanics and Materials (Volume 319)
• Pages: 203-208
• DOI: https://doi.org/10.4028/www.scientific.net/AMM.319.203
• Online since: May 2013
• Authors: Shao Jin Jia, Zhen Gang Ding, Ping Kai Jiang
• Keywords: Core-Shell, Microemulsion Polymerization, Polysiloxane, Vinyl Monomers

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