Zn (O,S):Al Films Prepared by Radio Frequency Magnetron Sputtering for Transparent Electrode

Article Preview

Abstract:

Zn (O,S):Al (AZOS) has been proposed as a new type of transparent conductive oxide (TCO) with adjustable band gap energy (Eg) and conduction band position. The novel materials of AZOS with S/(S+O) ratio of 0.00~0.85 were prepared by radio frequency magnetron co-sputtering of ZnO:Al and ZnS targets. The optical properties of the films showed high transmittance of almost over 80% and Eg change with the S/(S+O) ratio. The suitable resistivity for TCO of around 10-3 Ωcm was obtained at the S/(S+O) ratio of 0.00~0.09, but as the S/(S+O) ratio exceeded 0.40, the resistance increased greatly.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

567-570

Citation:

Online since:

August 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] K. Ramanathan, G. Teeter, J. C. Keane, R. Noufi, Properties of high-efficiency CuInGaSe2 thin film solar cells, Thin Solid Films 480–481 (2005) 499-502.

DOI: 10.1016/j.tsf.2004.11.050

Google Scholar

[2] T. Minemoto, T. Matsui, H. Takakura ,Y. Hamakawa, T. Negami, Y. Hashimoto, T. Uenoyama, M. Kitagawa, Theoretical analysis of the effect of conduction band offset of window/CIS layers on performance of CIS solar cells using device simulation, Sol. Energy Mater. Sol. Cells, 67 (2001).

DOI: 10.1016/s0927-0248(00)00266-x

Google Scholar

[3] T. Minemoto, Y. Hashimoto, T. Satoh, T. Negami, H. Takakura, Y. Hamakawa, Cu(In, Ga)Se2 solar cells with controlled conduction band offset of window/Cu(In, Ga)Se2 layers, J. Appl. Phys. 89 (2001) 8327-8330.

DOI: 10.1063/1.1366655

Google Scholar

[4] T. Minemoto, A. Okamoto, H. Takakura, Sputtered ZnO-based buffer layer for band offset control in Cu(In, Ga)Se2 solar cells, Thin Solid Films 519 (2011) 7568-7571.

DOI: 10.1016/j.tsf.2010.12.117

Google Scholar

[5] T. Minemoto, J. Julayhi, Buffer-less Cu(In, Ga)Se2 solar cells by band offset control using novel transparent electrode, Current Applied Physics 13 (2013) 103-106.

DOI: 10.1016/j.cap.2012.06.019

Google Scholar

[6] J. Julayhi, T. Minemoto, Bufferless Cu(In, Ga)Se2 solar cells using Zn(O, S): Al transparent electrode, phys. status solidi (a) in press.

DOI: 10.1002/pssc.201200802

Google Scholar

[7] B. K. Meyer, A. Polity, B. Farangis, Y. He, D. Hasselkamp, Th. Kramer, C. Wang, Structural properties and bandgap bowing of ZnO1−xSx thin films deposited by reactive sputtering, Appl. Phys. Lett. 85 (2004) 4929-4931.

DOI: 10.1063/1.1825053

Google Scholar

[8] E. Burstein, Anomalous optical absorption limit in InSb, Phys. Rev. 93 (1954) 632-633.

DOI: 10.1103/physrev.93.632

Google Scholar