Structure and Properties of A Dimer Complex: [Co2(Hdmg)2(dien)2](ClO4)24.5(H2O)

Xuan Wen Liu; Bing Wen Zhong; Yue Hong Zhang; Rui Guo

doi:10.4028/www.scientific.net/AMM.372.80

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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 372Structure and Properties of A Dimer Complex:...

Structure and Properties of A Dimer Complex: [Co₂(Hdmg)₂(dien)₂](ClO4)₂4.5(H₂O)

Abstract:

A new complex crystal [Co₂(Hdmg)₂(dien)₂](ClO₄)₂4.5(H₂O) (H₂dmg= dimethylglyoxime, dien = diethylenetriamine) had been synthesised in aqueous solution and was characterized by X-ray diffraction and IR spectrum. The complex crystallizes in monoclinic space group C₂/c with cell constants =20.868(7)Å, =11.408(4)Å, =15.816(4)Å, =90.00°, =116.97(2)°, =90.00°, =3355.8(17)Å³, =4, (000)=1732. The cobalt atom lies in a distorted octahedron environment and coordinates with one oxygen atom from neighbour Hdmg and five nitrogen atoms from bidentate chelate Hdmg and tridentate chelate dien. The two Hdmgs bridge two cobalt atoms to form a six-number Co₂O₂N₂ ring.

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Applied Mechanics and Materials (Volume 372)

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80-83

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https://doi.org/10.4028/www.scientific.net/AMM.372.80

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August 2013

Authors:

Xuan Wen Liu, Bing Wen Zhong, Yue Hong Zhang, Rui Guo

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Binuclear Complex, Cobalt, Diethylenetriamine, Dimethylglyoxime

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References

[1] Wei Y H, Tan A Z, Chen Z L, et al. Chinese J. Inorg. Chem. 2006, 22: 275-280.

Google Scholar

[2] XW Liu, Wang XQ, Zhang Y, et al. Crystal structure and spectroscopy of a new dmg2-bridged dinuclear cobalt(III) compound, J CHEM CRYSTALLOGR 2003, 33(3) : 169-173 MAR (2003).

Google Scholar

[3] Dong ZY, XW Liu, Wang XQ, et al., Acta. Cryst., 2003, 59(2): 260-262.

Google Scholar

[4] XW Liu, Chu S, Wang XQ, et al., Inorg. Chem. Commun., 2002, 5(6) : 1086-1089.

Google Scholar

[5] Chaudhuri P., Winter M., Della Vedova B.P.C., Bill E., Trautwein A., Gehring S., Fleischauer P., Nuber B., Weiss J. Inorg. Chem., 1991, 30, 2148-2154.

Google Scholar

[6] Krebs C., Winter M., Weyheremuller T., Wieghardt K., Chaudhurei P.J. Chem. Commun. 1995, 1913-(1919).

Google Scholar

[7] R. L. Lintvedt, M. D. Glick, B. K. Tomlonovic, D. P. Gavel, J. M. Kuszaj, Inorg. Chem. 1976, 15, 1633.

Google Scholar

[8] M. Rodriguez, A. Liobet, M. Corbella, Polyhedron 2000, 19, 2483.

Google Scholar

[9] Liu C M, Gao S, Zhang D Q, et al. Cryst, Crowth Des. 2007, 7, 1317.

Google Scholar

[10] XW Liu, Poly[diaqua(mu(3)-succinato)cadmium(II)], ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 65: M574-U985 Part 5 MAY (2009).

DOI: 10.1107/s1600536809011593

Google Scholar

[11] Chen H J, Chinese J. Struct. Chem. 2500, 24(2): 236-240.

Google Scholar