Influence of Complex Plasticizers Containing Urea and Triethanolamin on the Characteristics of SPI/PVA Films

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SPI/PVA films were successfully prepared with complex plasticizers containing urea and trethanolamin (TEA) by casting and characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM), ultraviolet (Uv-vis), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and tensile testing. The results indicated that SPI/PVA films with the content of 40% complex plasticizers possessed better optical transmittance. All of the films exhibited only one Tg in DSC curves. Moreover, the SPI/PVA films with complex plasticizers had higher thermal stability and mechanical properties, as a result of the strong interaction between complex plasticizers and SPI/PVA. The SPI/PVA materials will be promising for the application in the field of package and container, substituting for the nongreen polymers.

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809-814

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January 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] J. Zhang, L. Jiang, L. Zhu, J. Jane and P. Mungare: Biomacromolecules Vol. 7 (2006), p.1551.

Google Scholar

[2] V. Micard, R. Belamri, M.H. Morel and S. Guillbert: Journal of Agricultural and Food Chemistry Vol. 48 (2000), p.2948.

Google Scholar

[3] P. Chen, L. Zhang and F. Cao: Macromolecular Bioscience Vol. 5 (2005), p.872.

Google Scholar

[4] P. Chen and L. Zhang: Biomacromolecules Vol. 7 (2006), p.1700.

Google Scholar

[5] Y. Hishikawa, E. Togawa, Y. Kataoka and T. Kondo: Polymer Vol. 40 (1999), p.7117.

Google Scholar

[6] Y. Lu and R.C. Larock: Biomacromolecules Vol. 8 (2007), p.3108.

Google Scholar

[7] H.J. Sue, S. Wang and J.L. Jane: Polymer Vol. 38 (1997), p.5035.

Google Scholar

[8] W. Amass, A. Amass, and B. Tighe: Polymer International Vol 47 (1998), p.89.

Google Scholar

[9] R. Kumar, V. Choudhary, S. Mishra, I. K. Varma, and B. Mattiason: Industrial Crops and Products Vol. 16 (2002), p.155.

DOI: 10.1016/s0926-6690(02)00007-9

Google Scholar

[10] J. Zhang and P. Mungara: Polymer Vol. 42 (2001), p.2569.

Google Scholar

[11] X. Sue, H.R. Kim and X.J. Mo: Journal of American Oil Chemists' Society Vol. 76 (1999), p.117.

Google Scholar

[12] B.E. Ralston and T.A. Osswald: Plastic Engineering Vol. 64 (2008), p.36.

Google Scholar

[13] J.F. Su, Z. Huang, K. Liu, L.L. Fu and H.R. Liu: Polymer bulletin Vol. 58 (2007), p.913.

Google Scholar

[14] D.C. Ren, P. Lin, L. Qian, P.F. He, Y.H. Du and R. Xue: Journal of Materials Engineering (2012), p.86.

Google Scholar

[15] H.F. Tian, D.G. Liu and L.N. Zhang: Journal of Applied Polymer Science Vol. 111 (2009), p.1549.

Google Scholar

[16] P. Lodha: Industrial Crops and Products Vol. 21 (2005), p.49.

Google Scholar

[17] G.M. MacDonald and B.A. Barry: Biochemistry Vol. 31 (1992), p.9848.

Google Scholar

[18] M.N. Gontard and A. Dufresne: Macromolecules Vol. 33 (2000), p.8344.

Google Scholar

[19] Q. Wu and L. Zhang: Industrial and Engineering Chemistry Research Vol. 40 (2001), p.558.

Google Scholar

[20] E. Fekete, E. Foldes and M. Pukanszky: European Polymer Material Vol. 41 (2005), p.727.

Google Scholar