Effect of CO2 Flow Rate on the Synthesis Nanosized Precipitated Calcium Carbonate, PCC

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The precipitated of calcium carbonate has attractedmuch attention because of its numerous applications in various areas of plastics, textiles, rubbers, adhesives, paints and wastewater treatment. Nanosized of precipitated calcium carbonate,(PCC) will enhance the properties and give better performance. Its high purity and close controlled particle size and shape are making it the white filler of choice. Nanosized precipitated calcium carbonate particles were prepared using spraying method. The particles were prepared using three (3) different concentrations of Calcium Hydroxide,Ca (OH)2, three (3) CO2 flow rate and three (3) different calcinations temperature. The three (3) concentration of Calcium Hydroxide that been used are 25g/200ml, 25g/ 400ml and 25g/800ml and each of these initial solution sprayed at three (3) different CO2 flow rate, 5l/per-minute, 7l/per-minute and 10l/per-minute. Calcium Carbonate, CaCO3 powders were then calcined at three (3) different temperature, 1100°C,1200°C and 1300°C. Images from SEM showed morphology of the particles changed to spindle-like or prismatic when the ionic strength of the Calcium Hydroxide, Ca (OH)2 was increased.

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December 2013

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] Hochella, Jr. and Michael,F. Nanoscience and technology the next revolution in the earth science, Earth and planetary science letters 203, pp.593-605( 2002).

DOI: 10.1016/s0012-821x(02)00818-x

Google Scholar

[2] Ariffin, K.S. Effects of operating variables on precipitated calcium carbonate (PCC), RAMM conference (2001), pp.68-80.

Google Scholar

[3] Bates,L. P., Harrison, D. L.; Precipitated Calcium Carbonate Fillers in LowModulus Thixotropic Sealants; Adhesives, Sealants and Encapsulants Conference -Conference Proceedings. v 1. Materials, 131, (1985).

Google Scholar

[4] Chen, Le-Shang, Mai, Yiu-Wing, Cotterell, Brian, Impact fracture energy ofmineral-filled polypropylene, PolymEngSci v 29 n 8, ( 1989), pp.505-512.

DOI: 10.1002/pen.760290804

Google Scholar

[5] Kovacevic, V., Lucic, S., Leskovac, M., Morphology and failure in nanocomposites. Part I: Structural and mechanical properties, J AdhesSciTechnol v 16 n 10, (2002), pp.1343-1365.

Google Scholar

[6] Lee, I., Sang Woo Han, Hyouk Jin Choi, Kim, K., Nanoparticle-directed crystallization of calcium carbonate, Adv Mater v 21, (2001).

Google Scholar

[7] Wang,L. ZCharacterization of nanophase materials, Wiley-VCH, (200), pp.1-4, 13-17, 37-40.

Google Scholar

[8] Sun, Qunhui, Deng, Yulin, Synthesis of micrometer to nanometer CaCO3 particles via mass restriction method in an emulsion liquid membrane process, Journal of colloid and interface science, (2004), pp.376-382.

DOI: 10.1016/j.jcis.2004.06.013

Google Scholar

[9] Pokrovsky, S. O, Precipitation of calcium and magnesium carbonates from homogeneous supersaturated solutions, (1998), pp.233-239.

DOI: 10.1016/s0022-0248(97)00462-4

Google Scholar

[10] Buchmeiser, R. Michael, Polymeric materials in organic synthesis and catalysis, Wiley-VCH, (2003), pp.245-247.

Google Scholar

[11] Andreassen, Petter-jens, Formation mechanism and morphology in precipitation of vateritenano aggregation or crystal growth?, submitted to Journal of crystal growth, (2004).

Google Scholar

[12] Edelsten, A. S and cammarata, R. C, Nnaomaterials: synthesis, properties and applications, The institute of physics, (1996), pp.13-16, 55-59.

Google Scholar

[13] Hartwig,W., Hanko,R. and Nicolaou K. C, Handbook of combination chemistry, Wiley-VCH, (2003), pp.44-45.

Google Scholar

[14] Poharb, C., Kneza,S. The magnetic field influence on the polymorph composition of CaCO3 precipitated from carbonized aqueous solutions, submitted to Journal of colloid and interface science, (2004).

DOI: 10.1016/j.jcis.2004.08.099

Google Scholar

[15] Szczes, A., Chibowski, E and Holysz, L, Influence of impurity ions and magnetic field on the properties of freshly precipitated calcium carbonate, Water research, (2003), pp.3351-3360.

DOI: 10.1016/s0043-1354(03)00159-3

Google Scholar

[16] O. Nooririnah, A.R., Jeefferie, M.Y. Yuhazri, M.M. Haidir, A.R. Toibah,H. Sihombing, A. Azizan, Proceeding Effect of CO2 Flow Rate and Calcination Temperature on the Synthesis Nanosized Precipitated Calcium Carbonate, submitted to Workshop on advanced material science and nanotechnology, (2010).

Google Scholar